A Concise Approach to a Gelsemine Core Structure using an Oxygen to Carbon Bridge Swapping Strategy


Autoria(s): Tchabanenko, Kirill; Simpkins, Nigel S.; Male, Louise
Data(s)

06/11/2008

Resumo

A tricyclic core structure related to gelsemine was synthesized from an oxabicyclo[3.2.1]octanone by a three-step bridge swapping strategy involving elimination of the bridging ether oxygen and intramolecular Michael addition of a tethered cyanoacetamide unit.

Identificador

http://pure.qub.ac.uk/portal/en/publications/a-concise-approach-to-a-gelsemine-core-structure-using-an-oxygen-to-carbon-bridge-swapping-strategy(5f4702fb-bf31-44af-b1c8-6d0410d75d35).html

http://dx.doi.org/ 10.1021/ol801835q

http://www.scopus.com/inward/record.url?scp=58149163163&partnerID=8YFLogxK

Idioma(s)

eng

Direitos

info:eu-repo/semantics/restrictedAccess

Fonte

Tchabanenko , K , Simpkins , N S & Male , L 2008 , ' A Concise Approach to a Gelsemine Core Structure using an Oxygen to Carbon Bridge Swapping Strategy ' Organic Letters , vol 10 , no. 21 , pp. 4747-4750 . DOI: 10.1021/ol801835q

Palavras-Chave #/dk/atira/pure/subjectarea/asjc/1300/1303 #Biochemistry #/dk/atira/pure/subjectarea/asjc/1600/1605 #Organic Chemistry #/dk/atira/pure/subjectarea/asjc/1600/1606 #Physical and Theoretical Chemistry
Tipo

article