Sucessão estratigráfica e paleoambientes dos microbialitos proterozóicos do membro sumidouro, formação lagamar, grupo Vazante, na fazenda Sumaré, em Lagamar - MG

Microbialites (irregular agglutinated grains, laterally continuous mats and stromatolites) occur in small, nearly continuous outcrops over a ~60 m-thick carbonate interval of the Sumidouro Member, Lagamar Formation, Vazante Group, Meso-Neoproterozoic, on the Sumaré Farm, in Lagamar (MG, Southeastern Brazil). Diversified stromatolites formed under shallow, high energy conditions predominate and exhibit frequent lateral and vertical changes, including probable bioherm borders. In the lower part of the interval, coniform columnar stromatolites (Conophyton), representative of the deepest and/or calmest settings, are common. Higher up, narrow subcylindrical unbranched forms become abundant and may grade to forms with subparallel dichotomous or multiple divergent branches. The microbialites are apparently organized in shallowing upward cycles

Construction of a chamber for in situ monitoring of the drying process of gels and porous solids

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Characterization of aluminum hydroxide (Al(OH)(3)) for use as a porogenic agent in castable ceramics

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Chromosomal evolution in Pleurothallidinae (Orchidaceae: Epidendroideae) with an emphasis on the genus Acianthera: chromosome numbers and heterochromatin

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Cytotoxic and genotoxic effects of ethanolic extract of Euphorbia hyssoptfolia L. on HepG2 cells

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Aluminas macro-mesoporosas produzidas pelo método sol-gel para aplicação em catálise heterogênea

Pós-graduação em Química - IQ

Efeito do percentual de habitat e de diferentes tipos de matrizes sobre a dieta de Jaguatirica (Leopardus Pardalis)

A fragmentação e a perda de habitat promovem a perda de biodiversidade, sendo que esses efeitos podem interferir nas comunidades presentes em paisagens antropizadas. Dentre as conseqüências destacamos processos ecológicos chave, como a herbivoria, dispersão de sementes, fluxo gênico e predação/consumo de recursos alimentares. Entender como as espécies respondem às alterações na paisagem é essencial para promover medidas eficazes de conservação e manejo da paisagem e, consequentemente, manutenção da biodiversidade e serviços ecossistêmicos associados. Sabe-se que predadores de topo e meso predadores exercem papel fundamental sobre diversos aspectos relacionados à cascata trófica. Considerando que a paisagem pode alterar a persistência e manutenção de populações de predadores, entender com se dá o efeito da fragmentação sobre tais organismos pode aumentar o entendimento de como se dá o uso e distribuição de recursos nos níveis imediatamente abaixo dos predadores. Todavia, pouca informação temos disponíveis sobre as consequências da alteração da paisagem sobre o consumo de recursos alimentares em geral. A jaguatirica (Leopardus pardalis) é um bom modelo para estudos dessa natureza uma vez que é carnívoro e pode interferir nas demais guildas da cadeia trófica, além da literatura apontar a espécie como sendo bastante sensível a alterações em seu habitat. O estudo tem como objetivo avaliar se a estrutura da paisagem em múltiplas escalas influencia o hábito alimentar da espécie. 43 Fezes de jaguatirica de oito fragmentos de Mata Atlântica Semidecidual foram coletadas na Região Metropolitana de Campinas, São Paulo. A dieta foi caracterizada segundo a porcentagem de fezes com o determinado item alimentar (pelos, penas, escamas, sementes, carrapatos etc). 93,02% das amostras continham pelos; 55,81% penas, 20,93% escamas de répteis Esperava-se que em fragmentos em paisagem mais degradados a dieta das...

Efeito do percentual de habitat e de diferentes tipos de matrizes sobre a dieta de Jaguatirica (Leopardus Pardalis)

A fragmentação e a perda de habitat promovem a perda de biodiversidade, sendo que esses efeitos podem interferir nas comunidades presentes em paisagens antropizadas. Dentre as conseqüências destacamos processos ecológicos chave, como a herbivoria, dispersão de sementes, fluxo gênico e predação/consumo de recursos alimentares. Entender como as espécies respondem às alterações na paisagem é essencial para promover medidas eficazes de conservação e manejo da paisagem e, consequentemente, manutenção da biodiversidade e serviços ecossistêmicos associados. Sabe-se que predadores de topo e meso predadores exercem papel fundamental sobre diversos aspectos relacionados à cascata trófica. Considerando que a paisagem pode alterar a persistência e manutenção de populações de predadores, entender com se dá o efeito da fragmentação sobre tais organismos pode aumentar o entendimento de como se dá o uso e distribuição de recursos nos níveis imediatamente abaixo dos predadores. Todavia, pouca informação temos disponíveis sobre as consequências da alteração da paisagem sobre o consumo de recursos alimentares em geral. A jaguatirica (Leopardus pardalis) é um bom modelo para estudos dessa natureza uma vez que é carnívoro e pode interferir nas demais guildas da cadeia trófica, além da literatura apontar a espécie como sendo bastante sensível a alterações em seu habitat. O estudo tem como objetivo avaliar se a estrutura da paisagem em múltiplas escalas influencia o hábito alimentar da espécie. 43 Fezes de jaguatirica de oito fragmentos de Mata Atlântica Semidecidual foram coletadas na Região Metropolitana de Campinas, São Paulo. A dieta foi caracterizada segundo a porcentagem de fezes com o determinado item alimentar (pelos, penas, escamas, sementes, carrapatos etc). 93,02% das amostras continham pelos; 55,81% penas, 20,93% escamas de répteis Esperava-se que em fragmentos em paisagem mais degradados a dieta das...

Vertical distribution of benthic invertebrate larvae during an upwelling event along a transect off the tropical Brazilian continental margin

Abundance and composition of marine benthic communities have been relatively well studied in the SE Brazilian coast, but little is known on patterns controlling the distribution of their planktonic larval stages. A survey of larval abundance in the continental margin, using a Multi-Plankton Sampler, was conducted in a cross-shelf transect off Cabo Frio (23 degrees S and 42 degrees W) during a costal upwelling event. Hydrographic conditions were monitored through discrete CDT casts. Chlorophyll-a in the top 100 m of the water column was determined and changes in surface chlorophyll-a was estimated using SeaWiFS images. Based on the larval abundances and the meso-scale hydrodynamics scenario, our results suggest two different processes affecting larval distributions. High larval densities were found nearshore due to the upwelling event associated with high chlorophyll a and strong along shore current. On the continental slope, high larval abundance was associated with a clockwise rotating meander, which may have entrapped larvae from a region located further north (Cabo de Sao Tome, 22 degrees S and 41 degrees W). In mid-shelf areas, our data suggests that vertical migration may likely occur as a response to avoid offshore transport by upwelling plumes and/or cyclonic meanders. The hydrodynamic scenario observed in the study area has two distinct yet extremely important consequences: larval retention on food-rich upwelling areas and the broadening of the tropical domain to southernmost subtropical areas. (C) 2009 Elsevier B.V. All rights reserved.

Height variability from the MIROC - IPCC model for the 20th century compared to that of the TOPEX/POSEIDON altimeter

Planetary waves are key to large-scale dynamical adjustment in the global ocean as they transfer energy from the east to the west side of oceanic basins; they connect the forcing in the ocean interior with the variability at its boundaries: and they change the local heat content, thus coupling oceanic, atmospheric, and biological processes. Planetary waves, mostly of the first baroclinic mode, are observed as distinctive patterns in global time series of sea surface height anomaly (SSHA) and heat storage. The goal of this study is to compare and validate large-scale SSHA signals from coupled ocean-atmosphere general circulation Model for Interdisciplinary Research on Climate (MIROC) with TOPEX/POSEIDON satellite altimeter observations. The last decade of the models` time series is selected for comparison with the altimeter data. The wave patterns are separated from the meso- and large-scale SSHA signals by digital filters calibrated to select the same spectral bands in both model and altimeter data. The band-wise comparison allows for an assessment of the model skill to simulate the dynamical components of the observed wave field. Comparisons regarding both the seasonal cycle and the Rossby wave Held differ significantly among basins. When carried within the same basin, differences can occur between equal latitudes in opposite hemispheres. Furthermore, at some latitudes the MIROC reproduces biannual, annual and semiannual planetary waves with phase speeds and average amplitudes similar to those observed by the altimeter, but with significant differences in phase. (C) 2008 Elsevier Ltd. All rights reserved.

Coastal and shelf circulation in the vicinity of Camamu Bay (14 degrees S), Eastern Brazilian Shelf

The Camamu Bay (CMB) is located on the narrowest shelf along the South American coastline and close to the formation of two major Western Boundary Currents (WBC), the Brazil/North Brazil Current (BC/NBC). These WBC flow close to the shelf break/slope region and are expected to interact with the shelf currents due to the narrowness of the shelf. The shelf circulation is investigated in terms of current variability based on an original data set covering the 2002-2003 austral summer and the 2003 austral autumn. The Results show that the currents at the shelf are mainly wind driven, experiencing a complete reversal between seasons due to a similar change in the wind field. Currents at the inner-shelf have a polarized nature, with the alongshore velocity mostly driven by forcings at the sub-inertial frequency band and the cross-shore velocity mainly supra-inertially forced, with the tidal currents playing an important role at this direction. The contribution of the forcing mechanisms at the mid-shelf changes between seasons. During the summer, forcings in the two frequency bands are important to drive the currents with a similar contribution of the tidal currents. On the other hand, during the autumn season, the alongshore velocity is mostly driven by sub-inertial forcings and tidally driven currents still remain important in both directions. Moreover, during the autumn when the stratification is weaker, the response of the shelf currents to the wind forcing presents a barotropic signature. The meso-scale processes related to the WBC flowing at the shelf/slope region also affect the circulation within the shelf, which contribute to cause significant current reversals during the autumn season. Currents at the shelf-estuary connection are clearly supra-inertially forced with the tidal currents playing a key role in the generation of the along-channel velocities. The sub-inertial forcings at this location act mainly to drive the weak ebb currents which were highly correlated with both local and remote wind forcing during the summer season. (C) 2010 Elsevier Ltd. All rights reserved.

Correlation of photodynamic activity and singlet oxygen quantum yields in two series of hydrophobic monocationic porphyrins

The photodynamic properties of eight hydrophobic monocationic methyl and ruthenium polypyridine complex derivatives of free-base and zinc(II) meso-triphenyl-monopyridylporphyrin series were evaluated and compared using HeLa cells as model. The cream-like polymeric nanocapsule formulations of marine atelocollagen/xanthan gum, prepared by the coacervation method, exhibited high phototoxicity but negligible cytotoxicity in the dark. Interestingly, the formulations of a given series presented similar photodynamic activities but the methylated free-base derivatives were significantly more phototoxic than the respective ruthenated photosensitizers, reflecting the higher photoinduced singlet oxygen quantum yields of those monocationic porphyrin dyes.

Magmatism and fenitization in the Cretaceous potassium-alkaline-carbonatitic complex of Ipanema So Paulo State, Brazil

The Ipanema alkaline-carbonatitic complex is part of the Meso-Cenozoic alkaline magmatism located within the southeastern part of the Brazilian Platform. Drill-core and field sampling have indicated the occurrence of glimmerites, with subordinate shonkinites (mela-syenites), clinopyroxene-bearing glimmerites, diorites and syenites. The glimmerites are cross-cut by lamprophyric dykes and calciocarbonatites. Fenitization has deeply affected the country rocks, originating dioritic and syenitic rocks. The Ipanema rocks show a distinct potassic affinity. The initial Sr-Nd- isotopic composition of the Ipanema rocks ((87)Sr/(86)Sr = 0.70661-0.70754 and (143)Nd/(144)Nd = 0.51169-0.51181) is similar to that of tholeiitic and potassium-rich-alkaline rocks of the Eastern Paraguay. Stable isotope data for the Ipanema calciocarbonatite suggest interaction with fluids at temperatures typical of hydrothermal stages, as hypothesized for other carbonatite complexes from southeastern Brazil. The chemical differences between the lamprophyre, glimmerites, carbonatites, apatitites and magnetitites, and the absence of marked REE enrichment in the evolved lithologies, all indicate that fractional crystallization and accumulus of liquidus phases in a magma reservoir, likely coupled with liquid immiscibility processes, may have played an important role in the genesis of the Ipanema rocks.

Mechanism and Efficiency of Cell Death of Type II Photosensitizers: Effect of Zinc Chelation

A series of meso-substituted tetra-cationic porphyrins, which have methyl and octyl substituents, was studied in order to understand the effect of zinc chelation and photosensitizer subcellular localization in the mechanism of cell death. Zinc chelation does not change the photophysical properties of the photosensitizers (all molecules studied are type II photosensitizers) but affects considerably the interaction of the porphyrins with membranes, reducing mitochondrial accumulation. The total amount of intracellular reactive species induced by treating cells with photosensitizer and light is similar for zinc-chelated and free-base porphyrins that have the same alkyl substituent. Zinc-chelated porphyrins, which are poorly accumulated in mitochondria, show higher efficiency of cell death with features of apoptosis (higher MTT response compared with trypan blue staining, specific acridine orange/ethidium bromide staining, loss of mitochondrial transmembrane potential, stronger cytochrome c release and larger sub-G1 cell population), whereas nonchelated porphyrins, which are considerably more concentrated in mitochondria, triggered mainly necrotic cell death. We hypothesized that zinc-chelation protects the photoinduced properties of the porphyrins in the mitochondrial environment.

The influence of large-scale circulation, transient and local processes on the seasonal circulation of the Eastern Brazilian Shelf, 13 degrees S

The circulation at the Eastern Brazilian Shelf (EBS), near 13 degrees S, is discussed in terms of the currents and hydrography, associating large-scale circulation, transient and local processes to establish a regional picture of the EBS circulation. The results show that the circulation within the continental shelf and slope region is strongly affected by the seasonal changes in the wind field and mesa/large-scale circulation. Transient processes associated to the passage of Cold Front systems or meso-scale activity and the presence of a local canyon add more complexity to the system. During the austral spring and summer seasons, the prevailing upwelling favorable winds blowing from E-NE were responsible for driving southwestward shelf currents. The interaction with the Western Boundary Current (the Brazil Current), especially during summer, was significant and a considerable vertical shear in the velocity field was observed at the outer shelf. The passage of a Cold Front system during the springtime caused a complete reversal of the mean flow and contributed to the deepening of the Mixed Layer Depth (MLD). In addition, the presence of Salvador Canyon, subject to an upwelling favorable boundary current, enhanced the upwelling system, when compared to the upwelling observed at the adjacent shelf. During the austral autumn and winter seasons the prevailing downwelling favorable winds blowing from the SE acted to total reverse the shelf circulation, resulting in a northeastward flow. The passage of a strong Cold Front, during the autumn season, contributed not only to the strengthening of the flow but also to the deepening of the MLD. The presence of the Salvador Canyon, when subject to a downwelling favorable boundary current, caused an intensification of the downwelling process. Interestingly, the alongshore velocity at the shelf region adjacent to the head of the canyon was less affected when compared to the upwelling situation.