908 resultados para 16:1(n-7) 16:1(n-5) 20:5(n-3)


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SnO_2,ZnOFe_2O_3.,La_(0.5)Sr_(0.5)CoO_3.x-La_(0.5)Sr_(0.5)CoO_3,,

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UPNa. Instituto de Agrobiotecnologa. Laboratorio de Biofilms Microbianos.

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Treatment of the bicyclic iminium ion derived from 5-methoxyhexahydroindolizidin-3-one with allyltrimethylsilane gave exclusively the diastereoisomer in which the allyl group was axial. This substrate is a useful precursor to 5-propyl-3-alkylindolizidine alkaloids. (C) 1999 Elsevier Science Ltd. All rights reserved.

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Pour toute demande de reproduction de contenu se trouvant dans cette publication, communiquer avec lAssociation des diplms de lUdeM.

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http://digitalcommons.winthrop.edu/retrospect/1015/thumbnail.jpg

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Fundao de Amparo Pesquisa do Estado de So Paulo (FAPESP)

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No ano agrcola de 2006/07, no municpio de Selvria (MS), foi analisada a produtividade do feijo em funo de alguns atributos fsicos de um Latossolo Vermelho distrofrrico, cultivado nas condies de elevado nvel tecnolgico de manejo pelo sistema plantio direto irrigado com piv central. O objetivo foi selecionar, entre os atributos pesquisados do solo, aquele com a melhor representatividade para explicar a variabilidade da produtividade agrcola. Foi instalada a malha geoestatstica, para a coleta de dados do solo e da planta, com 117 pontos amostrais, numa rea de 2.025 m e declive homogneo de 0,055 m m-1. do ponto de vista linear e espacial, a produtividade de feijo foi explicada em funo da densidade de partculas e da umidade gravimtrica do solo, respectivamente. Assim, os valores de densidade de partculas entre 1,95 e 2,20 kg dm-3 e de umidade gravimtrica entre 0,205 e 0,239 kg kg-1; ambas coletadas na camada intermediria, resultaram em stios com as mais elevadas produtividades (2.200-2.600 kg ha-1). Entretanto, para as condies do elevado nvel tecnolgico de manejo empregado, a produtividade mdia do feijo no atingiu seu mximo potencial, uma vez que o agravado estado de compactao no qual o solo se encontrava proporcionou produtividade reduo de 26,6 %. Dessa forma, os valores mdios da densidade do solo e da resistncia do solo penetrao, respectivamente nas faixas de 1,36-1,41 kg dm-3 e de 1,56-3,24 MPa, tpicos de solos argilosos compactados, atestaram a substancial queda da produtividade de gros de feijo.

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The 5-enolpyruvylshikimate-3-phosphate synthase catalyses the sixth step of the shikimate pathway that is responsible for synthesizing aromatic compounds and is absent in mammals, which makes it a potential target for drugs development against microbial diseases. Here, we report the phosphate binding effects at the structure of the 5-enolpyruvyl shikimate-3-phosphate synthase from Mycobacterium tuberculosis. This enzyme is formed by two similar domains that close on each other induced by ligand binding, showing the occurrence of a large conformation change. We have monitored the phosphate binding effects using analytical ultracentrifugation, small angle X-ray scattering and, circular dichroism techniques. The low resolution results showed that the enzyme in the presence of phosphate clearly presented a more compact structure. Thermal-induced unfolding experiments followed by circular dichroism suggested that phosphate rigidified the enzyme. Summarizing, these data suggested that the phosphate itself is able to induce conformational change resulting in the closure movement in the M. tuberculosis 5-enolpyruvylshikimate-3-phosphate synthase. (c) 2006 Elsevier B.V. All rights reserved.

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Energy-transfer excited upconversion luminescence in Ho3+/Yb3+- and Tb3+/Yb3+ -codoped PbGeO3-PbF2-CdF2 glass and glass-ceramic under infrared excitation is investigated. In Ho3+/Yb3+-codoped samples, green (545 nm), red (652 nm), and near-infrared (754 nm) upconversion emission corresponding to the S-5(2) (F-5(4)) -> I-5(8), F-5(5) -> I-5(8), and S-5(2)(F-5(4)) -> I-5(7) transitions, respectively, was observed. Blue (490 nm) emission assigned to the F-5(2,3) -> I-5(8) transition was also detected. In the Tb3+/Yb3+-codoped system, bright UV-visible emission around 384, 415, 438, 473-490, 545, 587, and 623 nm, identified as due to the D-5(3)((5)G(6)) -> F-7(J)(J = 6, 5, 4) and D-5(4) -> F-7(J)(J = 6, 5, 4, 3) transitions, was measured. The comparison of the upconversion process in glass ceramic and its glassy precursor revealed that the former samples present much higher upconversion efficiencies. The dependence of the upconversion emission upon pump power, and doping contents was also examined. The results indicated that successive energy-transfer between ytterbium and holmium ions and cooperative energy-transfer between ytterbium and terbium ions followed by excited-state absorption are the dominant upconversion excitation mechanisms herein involved. The viability of using the samples for three-dimensional solid-state color displays is also discussed. (c) 2007 Elsevier B.V. All rights reserved.

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Table of Contents: Liberating Rat Island, page 4 Focus on . . . Through the Eyes of Children, pages 10-19 Back to Midway, page 23

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Table of Contents: Protecting Borders and Wildlife, page 4 Scientists Puzzle over Great Lakes Die-Offs, page 6 Focus on. . . Strategic Habitat Conservation, pages 8-17 People Who Keep the Wheels Turning, page 22

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In this issue...Coach McAuliffe, Handball Tournament, Clarks Field, Butte, Montana, mine safety, Professor Walter T. Scott, Butte Y. M. C. A., indoor tennis court