(Table 2) Radiocarbon contents of TOC and alkenone samples

Radiocarbon age relationships between co-occurring planktic foraminifera, alkenones, and total organic carbon in sediments from the continental margins of southern Chile, northwest Africa, and the South China Sea were compared with published results from the Namibian margin. Age relationships between the sediment components are site-specific and relatively constant over time. Similar to the Namibian slope, where alkenones have been reported to be 1000-4500 years older than co-occurring foraminifera, alkenones were significantly (~1000 years) older than co-occurring foraminifera in the Chilean margin sediments. In contrast, alkenones and foraminifera were of similar age (within 2 sigma error or better) in the NW African and South China Sea sediments. Total organic matter and alkenone ages were similar off Namibia (age difference TOC alkenones: 200-700 years), Chile (100-450 years), and NW Africa (360-770 years), suggesting minor contributions of preaged terrigenous material. In the South China Sea, total organic carbon is significantly (2000-3000 years) older owing to greater inputs of preaged terrigenous material. Age offsets between alkenones and planktic foraminifera are attributed to lateral advection of organic matter. Physical characteristics of the depositional setting, such as seafloor morphology, shelf width, and sediment composition, may control the age of co-occurring sediment components. In particular, offsets between alkenones and foraminifera appear to be greatest in deposition centers in morphologic depressions. Aging of organic matter is promoted by transport. Age offsets are correlated with organic richness, suggesting that formation of organic aggregates is a key process.

Sedimentation rates calculated on surface sediment samples from different site of the Atlantic and Pacific Oceans (Table 1)

Radiocarbon ages on CaCO3 from deep-sea cores offer constraints on the nature of the CaCO3 dissolution process. The idea is that the toll taken by dissolution on grains within the core top bioturbation zone should be in proportion to their time of residence in this zone. If so, dissolution would shift the mass distribution in favor of younger grains, thereby reducing the mean radiocarbon age for the grain ensemble. We have searched in vain for evidence supporting the existence of such an age reduction. Instead, we find that for water depths of more than 4 km in the tropical Pacific the radiocarbon age increases with the extent of dissolution. We can find no satisfactory steady state explanation and are forced to conclude that this increase must be the result of chemical erosion. The idea is that during the Holocene the rate of dissolution of CaCO3 has exceeded the rain rate of CaCO3. In this circumstance, bioturbation exhumes CaCO3 from the underlying glacial sediment and mixes it with CaCO3 raining from the sea surface.

(Table 1) Age determination of Arctic Ocean sediment cores

Accelerator mass spectrometer 14C dated stable isotope data from Neogloboquadrina pachyerma in cores raised from the Mendeleyev Ridge and slope provide evidence for significant influx of meltwater to the western Arctic Ocean during the early part of marine oxygen isotope stage 1 (OIS 1) and during several intervals within OIS 3. The strongest OIS 3 meltwater event occurred before ca. 45 ka (conventional radiocarbon age) and was probably related to the deglaciation at the beginning of OIS 3. Major meltwater input to the western Arctic Ocean during the last deglaciation coincides closely with the maximum rate of global sea-level rise as determined from the Barbados sea-level record, demonstrating a strong link between the global record and changes in the central Arctic Ocean. OIS 2, which includes the last glacial maximum, is very condensed or absent in the cores. Abundance and d13C values for N. pachyderma in the middle part of OIS 3 are similar to modern values, indicating high productivity and seasonal ice-free areas along the Arctic margin at that time. These records indicate that the Arctic Ocean was a source of heat and moisture to the northern polar atmosphere during parts of OIS 3.

Age determination of Holozene marine deposites from the western Mauritania (Table 1)

In an area regarded to be very favourable for the study of Holocene sea level changes one or several eustatic (?) oscillations of sea have been found using sedimentological and ecological methods. After a maximum of +3 m during the Nouakchottian stage (= Middle Flandrian or Late Atlantic) about 5500 YBP a drop of sea to -3.5 ± 0.5 m about 4100 YBP is testified by stromatolitic algae indicating the former sea level within the tidal zone with high accuracy. This evidence is supported by the observation of post-Nouakchottian regressive and transgressive geologic sequences, by buried beach deposits and flooded hardgrounds, post-Nouakchottian marine terraces of different height and age, the cutting off of one large and several small bays from the open sea etc. Possibly, one or two smaller oscillations followed between 4000 and 1500 years B. P. The radiocarbon age of the marine shells dated may be partly somewhat too old or too young.

Age determination using benthic and planktonic foraminifera of central Pacific Ocean sediment cores

A key constraint in attempts to reconstruct the patterns and rates of the ocean's thermohaline circulation during the last glacial period is the difference between the 14C to C ratio in surface and deep water. While imperfect, it is our best index of past deep-sea ventilation rates. In this paper we review published ventilation rate estimates based on the measured radiocarbon age difference between coexisting benthic and planktic foraminifera from glacial-age Pacific sediments. We also present new results from a series of eastern equatorial Pacific sediment cores. The conclusion is that the scatter in these results is so large that the apparent 14C age of glacial deep Pacific water could lie anywhere between double and half today's. Further, it is not clear what is responsible for the wide scatter in the radiocarbon results.

(Table 1) Radiocarbon ages of foraminifera from a Piston and a Trigger Weight from Ceara Rise

Radiocarbon-age measurements on single species of foraminifera from a core on the Ceara Rise demonstrate the importance of the joint effect of bioturbation and variable rain abundance of foraminifera. The relatively high mixed layer ages for Pulleniatina obliquiloculata reflect, at least in part, an early Holocene peak in its abundance while the relatively young ages for Globorotalia menardii reflect the delay until mid Holocene of its reappearance in the Atlantic Ocean. These results clearly demonstrate that core-top sediment samples need not be representative foraminifera falling from today's surface ocean. Rather, at least on the Ceara Rise, such samples consist of a composite of changing species groupings. These results also reconfirm the pitfalls associated with attempts to reconstruct the radiocarbon age of deep ocean water on the basis of benthic-planktonic foraminiferal age differences.

Sedimentology, age models and stable isotope ratios of sediment cores from the equatorial Pacific

Based on detailed reconstructions of global distribution patterns, both paleoproductivity and the benthic d13C record of CO2, which is dissolved in the deep ocean, strongly differed between the Last Glacial Maximum and the Holocene. With the onset of Termination I about 15,000 years ago, the new (export) production of low- and mid-latitude upwelling cells started to decline by more than 2-4 Gt carbon/year. This reduction is regarded as a main factor leading to both the simultaneous rise in atmospheric CO2 as recorded in ice cores and, with a slight delay of more than 1000 years, to a large-scale gradual CO2 depletion of the deep ocean by about 650 Gt C. This estimate is based on an average increase in benthic d13C by 0.4-0.5 per mil. The decrease in new production also matches a clear 13C depletion of organic matter, possibly recording an end of extreme nutrient utilization in upwelling cells. As shown by Sarnthein et al., [1987], the productivity reversal appears to be triggered by a rapid reduction in the strength of meridional trades, which in turn was linked via a shrinking extent of sea ice to a massive increase in high-latitude insolation, i.e., to orbital forcing as primary cause.

Age determination of sediment cores from the Laptev Sea

To establish a chronology of the Holocene transgression in Arctic Siberia, a total of 14 sediment cores from the Laptev Sea continental slope and shelf were studied covering the water depth range between 983 and 21 m. The age models of the cores were derived from 119 radiocarbon datings, which were all analyzed on marine biogenic calcite (mainly bivalve shells). The oldest shell sample was found at the slope and dates back to about 15.3 cal. ka, indicating that the time interval investigated starts prior to the onset of the meltwater pulse 1A (~14.2 cal. ka) when global sea-level rose dramatically. The inundation history was reconstructed mainly on the basis of major changes in average sedimentation rates (ASR), but also other sedimentological parameters were incorporated. A diachronous reduction in ASR from the outer to the inner shelf region is recognized, which was related to the southward migration of the coastline as the primary sediment source. We estimate that the flooding of the 50-, 43-, and 31-m isobaths was completed by approximately 11.1, 9.8, and 8.9 cal. ka, and that Holocene sea-level highstand was approached near 5 cal. ka. Between these time intervals, sea level in the Laptev Sea rose by 5.4, 13.3, and 7.9 mm/year, respectively.

Archaeometric evidence for the authenticity of the Jehoash inscription tablet

A gray, fine-grained arkosic sandstone tablet bearing an inscription in ancient Hebrew from the First Temple Period contains a rich assemblage of particles accumulated in the covering patina. Two types of patina cover the tablet: a thin layer of black to orange iron-oxide-rich layer, a product of micro-biogenic processes, and a light beige patina that contains feldspars, carbonate, iron oxide, subangular quartz grains, carbon ash particles and gold globules (1 to 4 microns [1 micron = 0.001 millimeter] in diameter). The patina covers the rock surface as well as the engraved lettering grooves and blankets and thus post-dates the incised inscription as well as a crack that runs across the stone and several of the engraved letters. Radiocarbon analyses of the carbon particles in the patina yield a calibrated radiocarbon age of 2340 to 2150 Cal BP. The presence of microcolonial fungi and associated pitting in the patina indicates slow growth over many years. The occurrence of pure gold globules and carbon ash particles is evidence of a thermal event in close proximity to the tablet (above 1000 degrees Celsius). This study supports the antiquity of the patina, which in turn, strengthens the contention that the inscription is authentic.

A Holocene paleotemperature record based on radiolaria from the northern Okinawa Trough (East China Sea)

Using a radiolarian-based transfer function, mean annual sea surface temperature (SST) and seasonal temperature range are reconstructed through the last 10,500yrs in the northern Okinawa Trough. Down-core SST estimates reveal that throughout the Holocene the changes of mean annual SST display a three-step trend: (i) an early Holocene continuous warming between 10,500 and 8500yr BP which ends up with a abrupt cooling at about 8200yr BP; (ii) a relatively stable middle Holocene with high SST that lasted until 3200yr BP; and (iii) a late-Holocene distinct SST decline between 3200 and 500yr BP. This pattern is in agreement with the ice core and terrestrial paleoclimatic records in the Chinese continent and other regions of the world. Five cooling events with abrupt mean annual SST drops, which occur at similar to 300-600, 1400, 3100, 4600-5100 and 8200yr BP, are recognized during the last 10,500yrs. Comparison of our results with records of GISP2 ice core and marine sediment in North Atlantic region suggests these cooling events are strongly coupled, which implies a possible significant climatic correlation between high- and low-latitude areas. (C) 2007 Elsevier Ltd and INQUA. All rights reserved.

Onset of recent rapid sea-level rise in the western Atlantic Ocean

A high-resolution record of sea-level change spanning the past 1000 years is derived from foraminiferal and chronological analyses of a 2m thick salt-marsh peat sequence at Chezzetcook, Nova Scotia, Canada. Former mean tide level positions are reconstructed with a precision of +/- 0.055 in using a transfer function derived from distributions of modern salt-marsh foraminifera. Our age model for the core section older than 300 years is based on 19 AMS C-14 ages and takes into account the individual probability distributions of calibrated radiocarbon ages. The past 300 years is dated by pollen and the isotopes Pb-206, Pb-207, Pb-210, Cs-137 and Am-241. Between AD 1000 and AD 1800, relative sea level rose at a mean rate of 17cm per century. Apparent pre-industrial rises of sea level dated at AD 1500-1550 and AD 1700-1800 cannot be clearly distinguished when radiocarbon age errors are taken into account. Furthermore, they may be an artefact of fluctuations in atmospheric C-14 production. In the 19th century sea level rose at a mean rate of 1.6mm/yr. Between AD 1900 and AD 1920, sea-level rise accelerated to the modern mean rate of 3.2mm/yr. This acceleration corresponds in time with global temperature rise and may therefore be associated with recent global warming. (c) 2005 Elsevier Ltd. All rights reserved.

Aspartic acid racemization dating of Holocene brachiopods and bivalves from the southern Brazilian shelf, South Atlantic

The extent of racemization of aspartic acid (Asp) has been used to estimate the ages of 9 shells of the epifaunal calcitic brachiopod Bouchardia rosea and 9 shells of the infaunal aragonitic bivalve Semele casali. Both taxa were collected concurrently from the same sites at depths of 10 m and 30 m off the coast of Brazil. Asp D/L values show an excellent correlation with radiocarbon age at both sites and for both taxa (r(Site)(2) (9) (B. rosea) = 0.97 r(Site)(2) (1) (B.) (rosea) = 0.997, r(Site)(2) (9) (S.) (casali) = 0.9998, r(2) (Site) (1) (S.casali) = 0.93). The Asp ratios plotted against reservoir-corrected AMS radiocarbon ages over the time span of multiple millennia can thus be used to develop reliable and precise geochronologies not only for aragonitic mollusks (widely used for dating previously), but also for calcitic brachiopods. At each collection site, Bouchardia specimens display consistently higher D/L values than specimens of Semele. Thermal differences between sites are also notable and in agreement with theoretical expectations, as extents of racemization for both taxa are greater at the warmer, shallower site than at the cooler, deeper one. In late Holocene marine settings, concurrent time series of aragonitic and calcitic shells can be assembled using Asp racemization dating, and parallel multi-centennial to multi-millennial records can be developed simultaneously for multiple biomineral systems. (c) 2006 University of Washington. All rights reserved.

Validated sample ages from 823 EPD sites

The number of well-dated pollen diagrams in Europe has increased considerably over the last 30 years and many of them have been submitted to the European Pollen Database (EPD). This allows for the construction of increasingly precise maps of Holocene vegetation change across the continent. Chronological information in the EPD has been expressed in uncalibrated radiocarbon years, and most chronologies to date are based on this time scale. Here we present new chronologies for most of the datasets stored in the EPD based on calibrated radiocarbon years. Age information associated with pollen diagrams is often derived from the pollen stratigraphy itself or from other sedimentological information. We reviewed these chronological tie points and assigned uncertainties to them. The steps taken to generate the new chronologies are described and the rationale for a new classification system for age uncertainties is introduced. The resulting chronologies are fit for most continental-scale questions. They may not provide the best age model for particular sites, but may be viewed as general purpose chronologies. Taxonomic particularities of the data stored in the EPD are explained. An example is given of how the database can be queried to select samples with appropriate age control as well as the suitable taxonomic level to answer a specific research question.

Stable isotope and geochemical record of sediments from the Bering Sea

here is controversy over the role of marine methane hydrates in atmospheric methane concentrations and climate change during the last glacial period. In this study of two sediment cores from the southeast Bering Sea (700 m and 1467 m water depth), we identify multiple episodes during the last glacial period of intense methane flux reaching the seafloor. Within the uncertainty of the radiocarbon age model, the episodes are contemporaneous in the two cores and have similar timing and duration as Dansgaard-Oeschger events. The episodes are marked by horizons of sediment containing 13C-depleted authigenic carbonate minerals; 13C-depleted archaeal and bacterial lipids, which resemble those found in ANME-1 type anaerobic methane oxidizing microbial consortia; and changes in the abundance and species distribution of benthic foraminifera. The similar timing and isotopic composition of the authigenic carbonates in the two cores is consistent with a region-wide increase in the upward flux of methane bearing fluids. This study is the first observation outside Santa Barbara Basin of pervasive, repeated methane flux in glacial sediments. However, contrary to the "Clathrate Gun Hypothesis" (Kennett et al., 2003), these coring sites are too deep for methane hydrate destabilization to be the cause, implying that a much larger part of the ocean's sedimentary methane may participate in climate or carbon cycle feedback at millennial timescales. We speculate that pulses of methane in these opal-rich sediments could be caused by the sudden release of overpressure in pore fluids that builds up gradually with silica diagenesis. The release could be triggered by seismic shaking on the Aleutian subduction zone caused by hydrostatic pressure increase associated with sea level rise at the start of interstadials.