(Table 1) Elemental abundances in DSDP Core 86-577B-1

An Ir anomaly of 61 ng/cm**2 was found in Deep Sea Drilling Project Hole 577B at the same stratigraphic level as the Cretaceous/Tertiary boundary defined by nannoplankton. This close correspondence supports the asteroid-impact theory for the Cretaceous/Tertiary boundary extinctions.

Benthic foraminiferal genera in DSDP Hole 95-612

On the basis of lithologic, foraminiferal, seismostratigraphic, and downhole logging characteristics, we identified seven distinctive erosional unconformities at the contacts of the principal depositional sequences at Site 612 on the New Jersey Continental Slope (water depth 1404 m). These unconformities are present at the Campanian/Maestrichtian, lower Eocene/middle Eocene, middle Eocene/upper Eocene, upper Eocene/lower Oligocene, lower Oligocene/upper Miocene, Tortonian/Messinian, and upper Pliocene/upper Pleistocene contacts. The presence of coarse sand or redeposited intraclasts above six of the unconformities suggests downslope transport from the adjacent shelf by means of sediment gravity flows, which contributed in part to the erosion. Changes in the benthic foraminiferal assemblages across all but the Campanian/Maestrichtian contact indicate that significant changes in the seafloor environment, such as temperature and dissolved oxygen content, took place during the hiatuses. Comparison with modern analogous assemblages and application of a paleoslope model where possible, indicate that deposition took place in bathyal depths throughout the Late Cretaceous and Cenozoic at Site 612. An analysis of two-dimensional geometry and seismic fades changes of depositional sequences along U.S.G.S. multichannel seismic Line 25 suggests that Site 612 was an outer continental shelf location from the Campanian until the middle Eocene, when the shelf edge retreated 130 km landward, and Site 612 became a continental slope site. Following this, a prograding prism of terrigenous debris moved the shelf edge to near its present position by the end of the Miocene. Each unconformity identified can be traced widely on seismic reflection profiles and most have been identified from wells and outcrops on the coastal plain and other offshore basins of the U.S. Atlantic margin. Furthermore, their stratigraphic positions and equivalence to similar unconformities on the Goban Spur, in West Africa, New Zealand, Australia, and the Western Interior of the U.S. suggest that most contacts are correlative with the global unconformities and sea-level falls of the Vail depositional model.

Natural oxides, elements and remanent magnetization intensities and directions at DSDP Hole 93-603B

Dark green spherules occur in the lower part of a turbidite in Section 603B-22-3, at the 70 cm level. In all probability these spherules originally consisted of massive glass, but now appear to have become completely altered into smectite. The presence of numerous microscopic fissures in the spherules probably mediated in the alteration process. Judging by the presence of similar spherules at the Cretaceous/Tertiary (K/T) boundary in DSDP Hole 390B, the green spherules are thought to represent diagenetically altered impact ejecta from one large or several smaller extraterrestrial objects at the end of the Cretaceous. The presence of anomalously high concentrations of Ni, Co, and As higher up in the turbidite are in agreement with an expected enrichment of these elements in the K/T boundary clay. However, precise Ir analyses are necessary in order to confirm this.

Petrology and carbon and oxygen stable isotopic composition of macrofossils and sediments from the Blake-Bahama Formation, DSDP Hole 93-603B

Strata that record the evolutionary history of the North American continental margin in a region that serves as the basin margin interface between allochthonous sedimentation from the continent and pelagic sedimentation from the oceanic realm were recovered at Deep Sea Drilling Project Site 603, on the lower continental rise. The lowermost unit recovered at this site is composed of upper Berriasian-Aptian interbedded laminated limestone and bioturbated limestone with sandstone to claystone turbidites. This unit can be correlated with the Blake-Bahama Formation in the western North Atlantic. Studies of the laminated and bioturbated limestones were used to determine the depositional environment. Geochemical and petrographic studies suggest that the laminated limestones were deposited from the suspended particulate loads of the nepheloid layer associated with weak bottom-current activity as well as moderate to poorly oxygenated bottom-water conditions. Fragments of macrofossils are also found in the Blake-Bahama Formation drilled at Site 603. Twelve specimens and their host sediment were analyzed for their carbon and oxygen isotopic composition. The macrofossil samples chosen for analysis consist of nine samples of Inoceramus, two ammonite aptychi, and one belemnite sample. Depletion in 18O is observed in recrystallized specimens. The ammonite aptychi have been diagenetically altered and/or exhibit evidence of isotopic fractionation by the organism. Oxygen isotope paleotemperatures obtained from five well-preserved specimens - four of Inoceramus and one of a belemnite - suggest that bottom-water temperatures in the North Atlantic Basin during the Early Cretaceous were very warm, at least 11°C.

Rare earth element composition and mass accumulation rates at DSDP Hole 92-598

Site 598 sediments were analyzed to determine the factors controlling the rare earth element (REE) geochemistry of the hydrothermal component. Site 598 provides an ideal sample suite for this purpose. Samples are lithologically "simple," primarily consisting of a hydrothermal component and biogenous carbonates. Also, the composition of the hydrothermal component appears unchanged through time or space, and the site appears to have undergone minimal diagenetic alteration. The shale-normalized REE patterns are similar to the pattern of seawater, varying only in absolute REE content. The REE content increases with distance from the paleorise crest and exhibits a pronounced increase in sediments deposited below the paleolysocline. Results presented are consistent with the following model: the source mechanism for the REE content of hydrothermal sediments is scavenging by Fe oxyhydroxides from seawater. With prolonged exposure to seawater resulting from transport far from the injection point and/or long residence at the seawatersediment interface, the absolute REE content of hydrothermal sediments increases and becomes more like seawater.

Geochemistry at DSDP Holes 80-550 amd 80-548

At Sites 548 and 550 of DSDP Leg 80 several condensed sedimentary sections contain various types of polymetallic crusts. The relationships between mineralogic and geochemical data in the sections have been studied in the context of the biostratigraphic and sedimentologic results. The diagenetic evolution during periods of low accumulation rate varies according to depth and sedimentary environment. At Site 548 on the continental margin, the phosphatic and manganiferous crusts are similar to those related to upwelling influences before Late Cretaceous deposition. At Site 550 the upper Paleocene cherts, deposited directly on oceanic crust, are overlain by pelagic brown clays containing diagenetic manganiferous concretions characterized by very high Sr and Ba contents. The origin of these small nodules is probably related to the authigenesis of fecal pellets. The upper Eocene indurated section is made up of authigenic zeolites, clays, and Fe-Mn phases and is similar to the volcanic-sedimentary deposits described in deep basins and seamounts of the Pacific. These crusts and a polynucleated nodule within the overlying sediments have geochemical characteristics (high Ni, Co, and Cu contents) similar to those formed in the deep ocean under volcanic influences during periods of low sedimentation rates or sedimentary hiatuses. Volcaniclastic material is ubiquitous and peculiarly abundant in Eocene sections and can be related to the volcanic formation of Iceland in the North Atlantic.

Lead and strontium isotope composition, mass accumulation rates and rare earth elements of selected samples from DSDP Sites 92-597 to 92-601

Most of the Pb isotope data for the Leg 92 metalliferous sediments (carbonate-free fraction) form approximately linear arrays in the conventional isotopic plots, extending from the middle of the field for mid-ocean ridge basalts (MORB) toward the field for Mn nodules. These arrays are directed closely to the average values of Mn nodules, the composition of which reflects the Pb isotope composition of seawater (Reynolds and Dasch, 1971). Since the Leg 92 samples are almost devoid of continentally derived detritus, it can be inferred that the more radiogenic end-member is seawater. The less radiogenic end-member lies in the very middle of the MORB field, and hence can be considered to reflect the Pb isotope composition of typical ocean-ridge basalt. The array of data lying between these two end-members is most readily interpreted in terms of simple linear mixing of Pb from the two different end-member sources. According to this model, eight samples from Sites 599 to 601 contain 50 to 100% basaltic Pb. Five of these samples have compositions that are identical within the uncertainty of the analyses. We use the average of these five values to define our unradiogenic end-member in the linear mixing model. The ratios used for this average are 206Pb/204Pb = 18.425 ± 0.010; 207Pb/204Pb = 15.495 ± 0.018; 208Pb/204Pb = 37.879 ± 0.068. These values should approximate the average Pb isotope composition of discharging hydrothermal solutions, and therefore also that of the basaltic crust, over the period of time represented by these samples ( 4 m.y., from 4 to 8 Ma). Sr isotope ratios show a significant range of values, from 0.7082 to 0.7091. The lower ratios are well outside the value of 0.70910 ± 6 for modern-day seawater (Burke et al., 1982). However, most values correspond very closely to the curve of 87Sr/86Sr versus age for seawater, with older samples having progressively lower 87Sr/86Sr ratios. The simplest explanation for this progressive reduction is that recrystallization of the abundant biogenic carbonate in the sediments released older seawater Sr which was incorporated into ferromanganiferous phases during diagenesis. Leg 92 metalliferous sediments have total rare earth element (REE) contents that range on a carbonate-free basis from 131 to 301 ppm, with a clustering between 167 and 222 ppm. The patterns have strong negative Ce anomalies. Samples from Sites 599 to 601 display a slight but distinct enrichment in the heavy REE relative to the light REE, whereas those from Sites 597 to 598 show almost no heavy REE enrichment. The former patterns (those for Sites 599 to 601) are interpreted as indicating moderate diagenetic alteration of metalliferous sediments originating at the EPR axis; the latter reflect more complete diagenetic modification.

Distribution of late Quaternary calcareous nannofossils in DSDP Leg 96 sites

Sediments from holes drilled at 11 sites in the northern Gulf of Mexico during Deep Sea Drilling Project Leg 96 were analyzed for calcareous nannofossil content. All sediments recovered are Holocene and late Pleistocene in age and are within the Emiliania huxleyi Zone. The datum level represented by the lowest stratigraphic occurrence of dominant E. huxleyi occurs at two sites (Sites 615 and 619) and can be dated at approximately 84,000 yr. ago at Site 619. Reworked Cretaceous nannofossils are generally common or abundant and dominate the floral assemblages of the late Wisconsin glacial sediments. When present, indigenous late Quaternary species are rare or few in abundance. Slight increases in the contemporaneous Quaternary component of the floral assemblages can be documented by the use of a calculated in s/fu/reworked ratio. This ratio, based on the relative abundances of the indigenous Quaternary taxa and reworked taxa, shows potential both for local correlations between drill sites and for correlation with glacio-eustatic fluctuations during the late Pleistocene.

Isotopic analysis of core gases at DSDP Leg 84 Holes

Methane carbon-isotopic compositions (d13C values relative to the PDB standard) at Sites 565, 566, 567, and 569 were lighter (enriched in 12C) than -60 per mil, indicating a biogenic origin. In the deeper sections at Sites 568 and 570, d13C values were heavier, approaching -40 per mil, and therefore suggest a thermogenic source. A significant thermogenic source was discounted, however, because the carbon dioxide d13C values in these sections were also anomalously heavy, suggesting that the methane may have formed biogenically by reduction of the heavy carbon dioxide. d13C values of ethane and higher hydrocarbons were measured in several sections from Sites 566 and 570 that contained sufficient C2-C4 hydrocarbon concentrations. Ethane values in six sections (245-395 m sub-bottom) from Site 570 were fairly uniform, ranging from -24 to -26 per mil. These values are among the heaviest ethane values reported for natural gases. The isobutane/ n-butane and isopentane/n-pentane ratios of the core gases suggested that the C2-C5 hydrocarbons are thermally produced by low-temperature chemical diagenesis of indigenous organic matter. This process apparently generates isotopically heavy C2-C5 hydrocarbons. High gas concentrations in the serpentinite basement rocks at Sites 566 and 570 appear to have resulted from migrated biogenic methane gas containing small amounts of immature C2-C5 hydrocarbons.

Sediment description, CaCO3, density and porosity at DSDP Site 89-585

Siliceous sediments and sedimentary rocks occur as chert and silicified chalk, limestone, and claystone in Site 585 lower Miocene to Campanian sediments, with one older occurrence of chert near the Cenomanian/Turonian boundary. The recovered drill breccia in the Miocene to middle Eocene interval is dominated by bright red, orange, yellow, and brown chips and fragments of chert. In early Eocene and older sediments gray silicified limestone and yellowish brown chert fragments predominate. Recovery is poor in cores with chert because chert tends to fracture into smaller pieces that escape the drill and because the hard chert fragments grind away other sediments during rotary drilling. Thin-section and hand-sample studies show complex diagenetic histories of silicification (silica pore infill) and chertification (silica replacement of host rock). Multiple events of silicification can occur in the same rocks, producing chert from silicified limestone. Despite some prior silicification, silicified limestone is porous enough to provide conduits for dissolved silica-charged pore waters. Silicification and chert are more abundant in the coarser parts of the sedimentary section. These factors reflect the importance of porosity and permeability as well as chemical and lithologic controls in the process of silica diagenesis.