Degradação de atrazina por processo foto-Fenton monitorado por injeção seqüencial e cromatografia a líquido de alta eficiência

Processos de fotodegradação de compostos orgânicos tóxicos têm sido bastante estudados. Este trabalho trata da aplicação do processo foto-Fenton para a degradação de atrazina em água (composto modelo). O efeito das concentrações dos seguintes compostos foi avaliado: peróxido de hidrogênio (2 a 6 mmol L-1) e ferrioxalato de potássio (0,2 a 1 mmol L-1). Os experimentos foram realizados em um reator com lâmpada UV - 8W (254nm). O processo de fotodegradação foi monitorado por medidas de espectrofotometria de absorção molecular automatizada por injeção seqüencial (SIA) para determinação de peróxido de hidrogênio e por cromatografia a líquido de alta eficiência (CLAE) para determinação de atrazina e metabólitos. Os experimentos demonstram que o processo de foto-Fenton é viável para o tratamento de atrazina em água.

Synthesis of high surface area TiO2 nanoparticles by mild acid treatment with HCl or HI for photocatalytic propene oxidation

Nanostructured TiO2 photocatalysts with small crystalline sizes have been synthesized by sol-gel using the amphiphilic triblock copolymer Pluronic P123 as template. A new synthesis route, based on the treatment of TiO2 xerogels with acid-ethanol mixtures in two different steps, synthesis and extraction-crystallization, has been investigated, analyzing two acids, hydrochloric and hydriodic acid. As reference, samples have also been prepared by extraction-crystallization in ethanol, being these TiO2 materials amorphous and presenting higher porosities. The prepared materials present different degrees of crystallinity depending on the experimental conditions used. In general, these materials exhibit high surface areas, with an important contribution of microporosity and mesoporosity, and with very small size anatase crystals, ranging from 5 to 7 nm. The activity of the obtained photocatalysts has been assessed in the oxidation of propene in gas phase at low concentration (100 ppmv) under a UVA lamp with 365 nm wavelength. In the conditions studied, these photocatalysts show different activities in the oxidation of propene which do not depend on their surface areas, but on their crystallinity and band gap energies, being sample prepared with HCl both during synthesis and in extraction-crystallizations steps, the most active one, with superior performance than Evonik P25.

Spectrally tunable light source based on light-emitting diodes for custom lighting solutions

This study describes a novel spectral LED-based tunable light source used for customized lighting solutions, especially for the reconstruction of CIE (Commission Internationale de l’Éclairage) standard illuminants. The light source comprises 31 spectral bands ranging from 400 to 700 nm, an integrating cube and a control board with a 16-bit resolution. A minimization algorithm to calculate the weighting values for each channel was applied to reproduce illuminants with precision. The differences in spectral fitting and colorimetric parameters showed that the reconstructed spectra were comparable to the standard, especially for the D65, D50, A and E illuminants. Accurate results were also obtained for illuminants with narrow peaks such as fluorescents (F2 and F11) and a high-pressure sodium lamp (HP1). In conclusion, the developed spectral LED-based light source and the minimization algorithm are able to reproduce any CIE standard illuminants with a high spectral and colorimetric accuracy able to advance available custom lighting systems useful in the industry and other fields such as museum lighting.

Revolutionary lyrics manuscript, [17--]

Satires written against the organizers of the American Revolution.

Cistinose : a propósito de uma doença renal de longa evolução com repercussões sobre o globo ocular

Trabalho Final do Curso de Mestrado Integrado em Medicina, Faculdade de Medicina, Universidade de Lisboa, 2014

Quando a oftalmologia diagnostica uma patologia sistémica : a propósito de um caso clínico

Trabalho Final do Curso de Mestrado Integrado em Medicina, Faculdade de Medicina, Universidade de Lisboa, 2014

Selections from the world's greatest short stories; illustrative of the history of short story writing;

Patient Griselda, from the "Decameron" of Boccaccio. Rewritten in English by the editor.--Aladdin, or The wonderful lamp, from "The Arabian nights".--Rip Van Winkle, by Washington Irving.--A passion in the desert, by Honoré de Balzac. Rewritten in English by the editor.--A child's dream of a star, by Charles Dickens.--A Christmas carol, by Charles Dickens.--A princess's tragedy, from "Barry Lyndon", by W.M. Thackeray.--The gold-bug, by Edgar Allan Poe.--The great stone face, by Nathaniel Hawthorne.--The necklace, and The string, by Guy de Maupassant. Rewritten in English by the editor.--The man who would be king, by Ruyard Kipling.--How Gavin Birse put it to Mag Lownie, from "A window in Thrums", by J.M. Barrie.--On the stairs, from "Tales of mean streets", by Arthur Morrison.

Physical metallurgy of tungsten and tungsten alloys

Vols. 1-3 photocopied by Armed Services Technical Information Agency, Arlington Hall Station, Arlington, Va.

Limehouse nights : tales of Chinatown /

Short stories.

How to make lampshades,

Mode of access: Internet.

Official proceedings of the New York Railroad Club.

No meetings held from June-August.

Home lighting fundamentals.

Mode of access: Internet.

The book buyer.

"A review and record of current literature."

Oriental tales.

"Limited to 500 copies, no. 361."

The collected works of Sir Humphry Davy ...

v. 1. Memoirs of the life of Sir Humphry Davy, by his brother, John Davy.--v. 2. Early miscellaneous papers from 1799 to 1805, with an introductory lecture and outlines of lectures on chemistry, delivered in 1802 and 1804.--v. 3. Researches, chemical and philosophical, chiefly concerning nitrous oxide ... and its respiration.--v. 4. Elements of chemical philosophy.--v. 5. Bakerian lectures and miscellaneous papers from 1806 to 1815.--v. 6. Miscellaneous papers and researches, especially on the safety-lamp, and flame, and on the protection of the copper sheathing of ships, from 1815 to 1828.--v. 7. Discourses delivered before the Royal society. Elements of agricultural chemistry, pt. I.--v. 8. Elements of agricultural chemistry, pt. II. Miscellaneous lectures and extracts from lectures.--v. 9. Salmonia, or Days of fly-fishing. Consolation in travel, or The last days of a philosopher.