Shifted loops and coercivity from field imprinted high energy barriers in ferritin and ferrihydrite nanoparticles

We show that the coercive field in ferritin and ferrihydrite depends on the maximum magnetic field in a hysteresis loop and that coercivity and loop shifts depend both on the maximum and cooling fields. In the case of ferritin, we show that the time dependence of the magnetization also depends on the maximum and previous cooling fields. This behavior is associated to changes in the intraparticle energy barriers imprinted by these fields. Accordingly, the dependence of the coercive and loop-shift fields with the maximum field in ferritin and ferrihydrite can be described within the frame of a uniform-rotation model considering a dependence of the energy barrier with the maximum and the cooling fields.

Changes in the phenolic content of low density lipoprotein after olive oil consumption in men. A randomized crossover controlled trial

Olive oil decreases the risk of CVD. This effect may be due to the fatty acid profile of the oil, but it may also be due to its antioxidant content which differs depending on the type of olive oil. In this study, the concentrations of oleic acid and antioxidants (phenolic compounds and vitamin E) in plasma and LDL were compared after consumption of three similar olive oils, but with differences in their phenolic content. Thirty healthy volunteers participated in a placebo-controlled, double-blind, crossover, randomized supplementation trial. Virgin, common, and refined olive oils were administered during three periods of 3 weeks separated by a 2-week washout period. Participants were requested to ingest a daily dose of 25 ml raw olive oil, distributed over the three meals of the day, during intervention periods. All three olive oils caused an increase in plasma and LDL oleic acid (P,0·05) content. Olive oils rich in phenolic compounds led to an increase in phenolic compounds in LDL (P,0·005). The concentration of phenolic compounds in LDL was directly correlated with the phenolic concentration in the olive oils. The increase in the phenolic content of LDL could account for the increase of the resistance of LDL to oxidation, and the decrease of the in vivo oxidized LDL, observed in the frame of this trial. Our results support the hypothesis that a daily intake of virgin olive oil promotes protective LDL changes ahead of its oxidation.

Active Damping and Energy Recovery in a Hydraulic Boom Controlled by an Electric Drive

The aim of the study is to obtain a mathematical description for an alternative variant of controlling a hydraulic circuit with an electrical drive. The electrical and hydraulic systems are described by basic mathematical equations. The flexibilities of the load and boom is modeled with assumed mode method. The model is achieved and proven with simulations. The controller is constructed and proven to decrease oscillations and improve the dynamic response of the system.

How much protein and energy are needed to equilibrate nitrogen and energy balances in ventilated critically ill children?

BACKGROUND & AIMS: Protein and energy requirements in critically ill children are currently based on insufficient data. Moreover, longitudinal measurements of both total urinary nitrogen (TUN) and resting energy expenditure (REE) are lacking. The aim of this study was to investigate how much protein and energy are needed to equilibrate nitrogen and energy balances in ventilated critically ill children on the basis of daily measurements of TUN, REE and protein and energy intakes. Comparisons were made with the guidelines of the American Society for Parenteral and Enteral Nutrition and the Dietary Reference Intakes. METHODS: Children with an expected duration of mechanical ventilation ≥72 h were prospectively recruited. TUN was measured by chemiluminescence, and REE was measured by indirect calorimetry. Generalised linear models for longitudinal data were used to study the relation between protein intake and nitrogen balance and to calculate the minimum intake of protein needed to achieve nitrogen equilibrium. A similar approach was used for energy. Results were compared to the recommended values. RESULTS: Based on 402 measurements performed in 74 children (median age: 21 months), the mean TUN was high at 0.20 (95% CI: 0.20, 0.22) g/kg/d and the REE was 55 (95% CI: 54, 57) kcal/kg/d. Nitrogen and energy balances were achieved with 1.5 (95% CI: 1.4, 1.6) g/kg/d of protein and 58 (95% CI: 53, 63) kcal/kg/d for the entire group, but there were differences among children of different ages. Children required more protein and less energy than the Dietary Reference Intakes. CONCLUSIONS: In critically ill children, TUN was elevated and REE was reduced during the entire period of mechanical ventilation. Minimum intakes of 1.5 g/kg/d of protein and 58 kcal/kg/d can equilibrate nitrogen and energy balances in children up to 4 years old. Older children require more protein.

Power Consumption in Carbon Capture and Storage Systems (CCS) and Possibilities to Reduce Power Consumption with Variable Speed Drives

The aim of this master´s thesis is to study which processes increase the auxiliary power consumption in carbon capture and storage processes and if it is possible to reduce the auxiliary power consumption with variable speed drives. Also the cost of carbon capture and storage is studied. Data about auxiliary power consumption in carbon capture is gathered from various studies and estimates made by various research centres. Based on these studies a view is presented how the power auxiliary power consumption is divided between different processes in carbon capture processes. In a literary study, the operation of three basic carbon capture systems is described. Also different methods to transport carbon dioxide and carbon dioxide storage options are described in this section. At the end of the thesis processes that consume most of the auxiliary power are defined and possibilities to reduce the auxiliary power consumption are evaluated. Cost of carbon capture, transport and storage are also evaluated at this point and in the case that the carbon capture and storage systems are fully deployed. According to the results, it can be estimated what are the processes are where variable speed drives can be used and what kind of cost and power consumption reduction could be achieved. Results also show how large a project carbon capture and storage is if it is fully deployed.

Utilisation of biomass for energy production in the North-West Russian forest industry

Traditionally, fossil fuels have always been the major sources of the modern energy production. However prices on these energy sources have been constantly increasing. The utilization of local biomass resources for energy production can substitute significant part of the required energy demand in different energy sectors. The introduction of the biomass usage can easily be started in the forest industry first as it possesses biomass in a large volume. The forest industry energy sector has the highest potential for the fast bioenergy development in the North-West Russia. Therefore, the question concerning rational and effective forest resources use is important today as well as the utilization of the forestry by-products. This work describes and analyzes the opportunities of utilising biomass, mainly, in the form of the wood by-products, for energy production processes in general, as well as for the northwest Russian forest industry conditions. The study also covers basic forest industry processes and technologies, so, the reader can get familiar with the information about the specific character of the biomass utilization. The work gives a comprehensive view on the northwest forest industry situation from the biomass utilisation point of view. By presenting existing large-scale sawmills and pulp and paper mills the work provides information for the evaluation of the future development of CHP investments in the northwest Russian forest industry.

Technical Wind Energy Potential in Russia

The goal of the master's thesis is a detailed research of the technical wind energy potential in Russian Federation: the distribution of the potential all over the territory of the country and the possibility of the application of the potential for power supply of various objects. The main attention of the thesis is devoted to the assessment of wind energy resources (potential) of Russian Federation, both for the territory of country in whole and for every region. Theoretical basic wind energy concepts and the scheme of transformation of kinetic energy of a wind into electric energy by modern wind turbines are given in the work. Also the costs of energy, stimuli of development of wind-engineering and obstacles which impact the industry development are analyzed. The review of existent and projected wind power plants in Russia is carried out.

Strategic groups and performance: an empirical analysis of strategic groups in the wind energy industry in Europe

The strategic group theory provides an intermediate level of analysis between a single company and the whole industry for identifying issues about the company's competitive position and strategic choices. Strategic groups are companies within an industry with similar strategic characteristics or competing on similar bases. Strategic choices are aligned with the firms’ resources. The purpose of this study was to identify the strategic groups in the wind energy industry in Europe, and study, whether a certain group membership results in financial performance differences. Altogether 80 European wind energy companies were included in the study, which were clustered into four strategic groups according to their age and growth rate. Each group corresponds to a different strategy. The results show that the wind energy companies can be clustered according to the chosen strategic characteristics. Strategic decisions were investigated with characteristic variables. Performance variables were used in the analysis measuring profitability, liquidity and solvency of the groups. These strategic choices of the companies did not have a significant influence on the firms’ performance. The more mature and slower growing group proved to be the most successful. However, the differences between groups were generally not statistically significant. The only statistically significant difference found was in the solvency ratio between Mature Slow and Young Rapid groups. Measured with these variables, more mature and slower growing companies performed better. Therefore, a certain strategic group membership results in performance differences.

Small scale energy production in Helsinki Metropolitan area in emission trading point of view

Emission trading with greenhouse gases and green certificates are part if the climate policy the main target of which is reduce greenhouse gas emissions. The carbon dioxide and fine particle emissions of energy production in Helsinki Metropolitan area are calculated in this study. The analysis is made mainly by district heating point of view and the changes of the district heating network are assessed. Carbon dioxide emissions would be a bit higher, if the district heating network is expanded, but then the fine particle emissions would be much lower. Carbon dioxide emissions are roughly 10 % higher, if the district heating network is expanded at same rate as it has in past five years in the year 2030. The expansion of district heating network would decrease the fine particle emissions about 40 %. The cost of the expansion is allocated to be reduction cost of the fine particle emissions, which is considerably higher than the traditional reduction methods costs. The possible new nuclear plant would reduce the emissions considerably and the costs of the nuclear plant would be relatively low comparing the other energy production methods.

Market of biomass fuels in Finland : IEA Bioenergy Task 40 and EUBIONET III - Country report of Finland 2009

This study considered the current situation of solid and liquid biomass fuels in Finland. The fact that industry consumes more than half of the total primary energy, widely applied combined heat and power production and a high share of solid biomass fuels in the total energy consumption are specific to the Finnish energy system. Wood is the most important source of bioenergy in Finland, representing 20% of the total energy consumption in 2007. Almost 80% of the woodbased energy is recovered from industrial by-products and residues. As a member of the European Union, Finland has committed itself to the Union’s climate and energy targets, such as reducing its overall emissions of green house gases to at least 20% below 1990 levels by 2020, and increasing the share of renewable energy in the gross final consumption. The renewable energy target approved for Finland is 38%. The present National Climate and Energy Strategy was introduced in November 2008. The strategy covers climate and energy policy measures up to 2020, and in brief thereafter, up to 2050. In recent years, the actual emissions have exceeded the Kyoto commitment and the trend of emissions is on the increase. In 2007, the share of renewable energy in the gross final energy consumption was approximately 25% (360 PJ). Without new energy policy measures, the final consumption of renewable energy would increase to 380 PJ, which would be approximately only 31% of the final energy consumption. In addition, green house gas emissions would exceed the 1990 levels by 20%. Meeting the targets will need the adoption of more active energy policy measures in coming years. The international trade of biomass fuels has a substantial importance for the utilisation of bioenergy in Finland. In 2007, the total international trading of solid and liquid biomass fuels was approximately 77 PJ, of which import was 62 PJ. Most of the import is indirect and takes place within the forest industry’s raw wood imports. In 2007, as much as 21% of wood energy was based on foreign-origin wood. Wood pellets and tall oil form the majority of export streams of biomass fuels. The indirect import of wood fuels peaked in 2006 to 61 PJ. The foreseeable decline in raw wood import to Finland will decrease the indirect import of wood fuels. In 2004– 2007, the direct trade of solid and liquid biomass fuels has been on a moderate growth path. In 2007, the import of palm oil and export of bio-diesel emerged, as a large, 170 000 t/yr biodiesel plant came into operation in Porvoo.

Lämpöpumppujen vaikutukset sähköverkkoliiketoiminnan kannalta

Energiatehokkuus sekä ilmastonmuutos ovat aiheuttaneet pyrkimyksen vähentää kokonaisenergiankulutuksia erilaisissa rakennuksissa. Lämmitysjärjestelmissä tämä on näkynyt voimakkaana lämpöpumppumäärien kasvuna. Lämpöpumput vaikuttavat erilaisissa rakennus- ja lämmitystyypeissä myös sähköenergiankulutukseen. Lämpöpumppujen käytöstä saadaan eniten hyötyä lämmityskustannuksiin sähkölämmitteisissä rakennuksissa. Seurauksena on, että tällaisen rakennuksen sähkönkulutus ja siten myös sähkölasku pienenevät. Toisaalta muihin kuin sähkölämmitteisiin rakennuksiin asennettu lämpöpumppu kasvattaa sähköenergiankulutusta. Lämpöpumppuihin integroitu jäähdytysominaisuus myös tavallisesti lisää sähkönkulutusta. Tämän tutkimuksen tarkoituksena on selvittää, kuinka lämpöpumput vaikuttavat sähköenergiankulutukseen. Vaikutuksia tutkitaan sähköverkkoyhtiöiden kannalta sähköenergian ja liikevaihdon osalta. Tarkastelussa käytetään neljää yleisintä lämpöpumpputyyppiä, ja niiden toimintaa verrataan eri rakennustyyppien lämmitysjärjestelmiin. Työssä käsitellään lämpöpumppujen toimintaa ja käytettävyyttä muiden lämmitysmenetelmien korvaajina tai lisänä. Tämän kirjallisen työn lisäksi on tehty laskentaohjelma, joka on perusteena työssä esitetyille tuloksille. Sen tarkoituksena on selvittää lämpöpumppujen vaikutukset sähköverkkoliiketoimintaan energiayhtiöissä. Vaikutukset yksittäiseen energiayhtiöön ovat eniten riippuvaisia lämpöpumppujen asennuskohteista, lämpöpumppujen toiminnasta ja lämpöpumpputyypistä. Kuluttajat tulevat määräämään vaikutusten suuruuden, koska lämpöpumppujen lukumäärällä ja käytöllä on sähköenergiankulutukseen huomattava merkitys. Vaikutus sähköenergiaan energiayhtiöiden kannalta voi yleisesti ottaen olla 2020-luvulle mentäessä merkittävä. Tutkittavassa verkkoyhtiössä vaikutuksen sähköenergiaan arvioidaan olevan 10 % luokkaa yhdeltä vuodelta verrattuna tämän päivän kokonaissähköenergiankulutukseen. Vaikutus verkkoliikevaihtoon on arviolta puolet pienempi. Tällaiset tulokset edellyttävät lämpöpumppumäärän moninkertaistumista nykyisestä, mikä on myös odotettavissa.

Energiatehokas toimisto - LED -teknologia

Tässä työssä käsitellään toimistorakennusten energiankulutusta ja nykyisiä toimistojen valaistusratkaisuja. Työssä perehdytään LED-valaistusteknologiaan sekä energiatehokkaaseen toimistovalaistukseen. Energiatehokkaan valaistuksen osalta käsitellään toimistovalaistuksen vaatimuksia, valaistuksen ohjausta ja luonnonvalon vaikutusta energiankulutukseen. Tutkimuskohteena oli Helsingin yliopiston tiloissa sijaitsevat neljä toimistohuonetta, joista kahden valaistusjärjestelmä uusittiin ja kahden jätettiin entiselleen vertailun vuoksi. Tutkimuksessa kartoitettiin toimistohuoneiden nykyistä energiankulutusta ja etsittiin keinoja sen tehostamiseen valaistuksen osalta. Tässä työssä tutkittiin erityisesti LED-valaisimien ja valaistuksen ohjauksen hyödynnettävyyttä toimistotiloissa. Toimistotilojen elinkaarikustannuslaskelmilla pyrittiin toteamaan valaistusjärjestelmien taloudellinen kannattavuus 30 vuoden tarkastelujaksolla. Tutkimuksessa tehtiin käyttäjäkysely toimistohuoneissa työskenteleville henkilöille ennen ja jälkeen muutoksen. Kyselyn perusteella voitiin todeta uusitun valaistusjärjestelmän hyödyt ja puutteet käyttäjän näkökulmasta.

Vesistöjen hyödyntäminen rakennusten lämmityksessä ja jäähdytyksessä

Suomen kokonaisenergiankulutuksesta noin viidesosa kuluu rakennusten lämmitykseen. Ilmastosopimuksien ja tiukentuvien päästömääräyksien vuoksi rakennusten lämmitys- jajäähdytysenergian tuotantoa täytyisi saada energiatehokkaammaksi. Energian kulutuksen vähentäminen onnistuu muun muassa lisäämällä rakennusten omaenergian tuottoa, jota on esimerkiksi lämpöpumpuilla tapahtuva rakennusten lämmitys. Samalla päästöjen määrä pienenee. Rakennusten energiatehokkuusluvun määritys tulee muuttumaan energiamuotojen kertoimiin pohjautuvaksi kokonaisenergiatarkasteluksi. Tämä ohjaa rakennusten energiantuotantoa kaukolämmitykseen ja erilaisiin lämpöpumppuratkaisuihin perustuvaksi. Diplomityössä tutkitaan tapoja, joilla pystytään hyödyntämään vesistöjä rakennusten lämmitykseen ja jäähdytyksen ja saamaan samalla energiankulutusta ja päästöjä pienemmiksi. Lisäksi työssä selvitetään vesistöistä saatavan energian määrää ja käyttökohteita.