InGaAs/InAlAs多量子阱结构的量子限制Stark效应研究

通过吸收光电流谱的测量,观察到用国产MBE设备生长的与InP衬底晶格匹配的InGaAs/InAlAs多量子阱结构的量子限制Stark效应及其与光偏振方向有关的各向异性电吸收特性,报道了可用于波导型调制器制作的MQW样品材料的X射线双晶衍射结果,并用计算机模拟出与实测十分相似的曲线,得到了可靠的量子阱结构,证明样品材料具有优良的外延质量.利用等效无限深阱模型进行的理论计算表明,应考虑样品p-i-n结内建电场的影响,才能使算出的吸收边红移与实验值符合.

InGaAs-GaAs短周期应变层超晶格调制反射光谱中的Franz-Keldysh振荡

在p-i-n结构的 InGaAs-GaAs应变层短周期超晶格的调制光反射谱中观察并确认了超晶格微带电子的Franz-Keldysh振荡, 通过对Franz-Keldysh振荡的分析,推算出超晶格区内建电场大小;讨论了内建电场对超晶格微带电子的影响,最后指出Franz-Keldysh振荡可以作为检验短周期超晶格样品质量的一种手段。

Characterization of polymorphous silicon thin film and solar cells

Polymorphous silicon (pm-Si:H) films have been prepared by a new regime of plasma enhanced chemical vapour deposition in the region adjacent of phase transition from amorphous to microcrystalline state. Comparing to the conventional amorphous silicon (a-Si:H), the pm-Si:H has higher photoconductivity (sigma(ph)), better stability, and a broader light spectral response range in the longer wavelength range. It can be found from Raman spectra that there is a notable improvement in the medium range order. There are a blue shift for the stretching mode of IR spectra and a red shift for the wagging mode. The shifts are attributed to the variation of the microstructure. By using pm-Si:H film as intrinsic layer, a p-i-n junction solar cell was prepared with the initial efficiency of 8.51% and a stabilized efficiency of 8.01% (AM1.5, 100mw/cm(2)) at room temperature (T-R).

Characterization of diphasic nc-Si/a-Si : H thin films and solar cells

Hydrogenated silicon films with diphasic structure have been prepared by using a new regime of plasma enhanced chemical vapor deposition (PECVD) in the region adjacent to the phase transition from amorphous to crystal. line state. The photoelectronic and microstructural properties of the films have been characterized by the constant photocurrent method (CPM), Raman scattering and nuclear magnetic resonance (NMR). In comparison with typical hydrogenated amorphous silicon (a-Si:H), these diphasic films with a crystalline fraction less than 0.3 show a similar optical absorption coefficient, lower deep-defect densities and higher stability upon light soaking. By using the diphasic nc-Si/a-Si films a p-i-n junction solar cell has been prepared With an initial efficiency of 8.51 % and a stabilized efficiency of 8.02 % on an area of 0.126 cm(2) (AM1.5, 100 mW/cm(2)).

Investigation on integrated high speed DFB light source and narrow bandwidth RCE photodetector for WDM fiber communication network application

Electroabsorption (EA) modulator integrated with partially gain coupling distributed feedback (DFB) lasers have been fabricated and shown high single mode yield and wavelength stability. The small signal bandwidth is about 7.5 GHz. Strained Si1-chiGechi/Si multiple quantum well (MQW) resonant-cavity enhanced (RCE) photodetectors with SiO2/Si distributed Bragg reflector (DBR) as the mirrors have been fabricated and shown a clear narrow bandwidth response. The external quantum efficiency at 1.3 mum is measured to be about 3.5% under reverse bias of 16 V. A novel GaInNAs/GaAs MQW RCE p-i-n photodetector with high reflectance GaAs/ALAs DBR mirrors has also been demonstrated and shown the selectively detecting function with the FWHM of peak response of 12 nm.

Visible vertical cavity surface emitting laser

We have designed and fabricated the visible vertical-cavity surface-emitting lasers (VCSEL's) by using metalorganic vapor phase epitaxy (MOVPE). We use the 8 lambda optical cavities with 3 quantum wells in AlGaInP/AlGaAs red VCSEL's to reduce the drift leakage current and enhance the model gain in AlGaInP active region. The structure has a p-type stack with 36 DBR pairs on the top and an n-type with 55-1/2 pairs on the bottom. Using micro-area reflectance spectrum, we try to get a better concordance between the center wavelength of DBR and the emitting wavelength of the active region. We used a component graded layer of 0.05 lambda thick (x = 0.5 similar to 0.9) at the p-type DBR AlGaAs/AlAs interface to reduce the resistance of p-type DBR. We use selective oxidation to define the current injection path. Because the oxidation rate of a thick layer is faster than a thinner one, we grown a thick AlAs layer close to the active region. In this way, we got a smaller active region for efficient confinement of injected carriers (the aperture area is 3 x 3 mu m) to reduce the threshold and, at the same time, a bigger conductive area in the DBR layers to reduce the resistance. We employ Zn doping on the p-side of the junction to improve hole injection and control the Zn dopant diffusion to get proper p-i-n junction. At room temperature, pulse operation of the laser has been achieved with the low threshold current of 0.8mA; the wavelength is about 670nm.

Synthesis and characterization of chiral smectic side-chain liquid crystalline polysiloxanes and ionomers containing sulfonic acid groups

The synthesis of new chiral smectic A (S-A) side-chain liquid crystalline polysiloxanes (LCPs) and ionomers (LCIs) containing 4-allyloxy-benzoyl-4-(S-2-ethylhexanoyl) p-benzenediol his ate (ABB) as mesogenic units and 4-[[4-(2-propenyloxy)phenyl] azo]benzensulfonic acid (AABS) as nonmesogenic units is presented. The chemical structures of the monomers and polymers are confirmed by FTIR spectroscopy or H-1-NMR. Differential scanning calorimetry (DSC), optical polarizing microscopy, and X-ray diffraction measurements reveal that all the polymers P-I-P-IV and ionomers P-V-P-VI exhibit S-A texture. The results seem to demonstrate that the tendency toward the S-A-phase region increases with increasing sulfonic acid concentration, and the thermal stability of the S-A phase is determined by the flexibility of the polymer backbones and the interactions of sulfonic acid groups. (C) 2001 John Wiley & Sons, Inc.

Seasonal changes in the distribution of dissolved organic nitrogen in coastal and open-ocean waters in the North East Pacific: sources and sinks

The distribution of dissolved organic nitrogen (DON) and nitrate were determined seasonally (winter, spring and summer) during three years along line P, i.e. an E-W transect from the coast of British Columbia, Canada, to Station P (50degreesN, 145degreesW) in the subarctic North East Pacific Ocean. In conjunction, DON measurements were made in the Straits of Juan de Fuca and Georgia within an estuarine system connected to the NE Pacific Ocean. The distribution of DON at the surface showed higher values of 4-17 muM in the Straits relative to values of 4-10 muM encountered along line P, respectively. Along line P, the concentration of DON showed an inshore-offshore gradient at the surface with higher values near the coast. The equation for the conservation of DON showed that horizontal transport of DON (inshore-offshore) was much larger than vertical physical mixing. Horizontal advection of DON-rich waters from the coastal estuarine system to the NE Pacific Ocean was likely the cause of the inshore-offshore gradient in the concentration of DON. Although the concentration of DON was very variable in space and time, it increased from winter to summer, with an average build up of 4.3 muM in the Straits and 0.7 muM in the NE subarctic Pacific. This implied seasonal DON sources of 0.3 mmol N m(-2) d(-1) at Station P and 1.5 mmol N m(-2) d(-1) in the Straits, respectively. These seasonal DON accumulation rates corresponded to about 15-20% of the seasonal nitrate uptake and suggested that there was a small seasonal build up of labile DON at the surface. However, the long residence times of 180-1560 d indicated that the most of the DON pool in surface waters was refractory in two very different productivity regimes of the NE Pacific. (C) 2002 Elsevier Science Ltd. All rights reserved.

Spatial distribution of ciliates, copepod nauplii and eggs, Engraulis japonicus post-larvae and microzooplankton herbivorous activity in the Yellow Sea, China

The abundance of anchovy Engraulis japonicus larvae, >20 mum ciliates, copepod eggs and nauplii, and microzooplankton herbivorous activity were studied in the Yellow Sea in June 2000. Anchovy juveniles and larvae were found in only 6 of the 19 stations sampled. The ciliate communities were dominated by 2 species: Laboea strobila and Strombidium compressum. In the surface waters, the abundance of L. strobila ranged between 0 and 560 ind. l(-1). S. compressum only appeared at Stns 15 to 18 (20 to 3300 ind. l(-1)). L. strobila was found mainly in the top 20 m. The abundance of L. strobila was less than 50 ind, l(-1) in waters deeper than 25 m. S, compressum showed subsurface abundance peaks at the salinity abnormality. Tintinnids occurred occasionally with abundance lower than 100 ind. l(-1), The total ciliate abundance fell in the range of 40 to 3420 ind. l(-1). The ciliate biomass in the surface water and the water column ranged between 0,15 and 6.76 mug C l(-1) and 0.4 and 134.4 mg C m(-2), respectively, In the surface waters, the abundance of copepod eggs and nauplii ranged from 0,3 to 3.1 and 1,1 to 15.6 ind, l(-1), respectively. The average abundance of copepod eggs and nauplii in 4 depth (0, 5, 10 and 20 m) fell in the range of 0.2 to 2.8 and 1.0 to 29.4 ind. l(-1), respectively. As a food item of the E. japonicus post-larvae, the abundance of copepod nauplii and eggs appeared to be low. The abundance peaks of ciliate and E, japonicus post-larvae coincided. Although not found in the gut of E, japonicus post-larvae, aloricate ciliates might be ingested by first-feeding anchovy larvae, preventing initial starvation and prolonging the time to irreversible starvation. On the basis of dilution experiments with positive microzooplankton grazing rates, microzooplankton grazed at rates of 0 to 0.61 d(-1). Grazing pressure of microzooplankton on chlorophyll a standing stock (P-i) and potential chlorophyll a primary production (P-p) were 17 to 46% and 35 to 109% d(-1), respectively.

松辽盆地河流-三角洲体系高分辩率层序地层学、储层构形及非均质模型研究

This dissertation tries to combine the new theories of high-resolution sequence stratigraphy and reservoir architecture with fine sedimentology to form a integral theory system -"high-resolution sequence sedimentology", which can be applied widely ranging from the early petroleum exploration to the tertiary recovery stage in marine and terrestrial basin. So the west slope area in south of Songliao basin, in which, early-fine exploration have been developed, and Xingnan area of Daqing placantictine in high water-bearing and tertiary recovery stage, are selected as target areas to research and analyze. By applying high-resolution sequence stratigraphy theory as well as analysis of source area-facies, the west slope area has been divided into two source areas and three drainage systems and the following conclusions have been drawn: three high values sandstone areas, two sandstone pinchout zones and one stratigraphic pinchout overlap; the facies between Baicheng-Tongyu drainage system is frist ascertained as large-scale argillaceous filled plain facies; fine-grained braided channel-delta depositional system has been found; plane sedimentary facies and microfacies maps of different-scale sequence have been completed, and then twenty-eight lithologic traps have been detected in the east of Taobao-Zhenlai reverse fault zone; In no exploration area of the west, large-scale stratigraiphic overlap heavy oil reservoirs has first been found, which has become an important prograss. In Xingnan area, in the view of high-resolution sequence stratigraphy, the surface of unconformity (the bottom of SSC13) in P I group has been identified, and the following method and technique have been advanced: the division and correlation methods of short-scale base-level cycle sequence (SSC); the comprehensive research methods of SSC plane microfacies; the division technique of hierarchy and type of flow unit, the origin of large-scale composite sandbody and flow unit; And ,on the basis of these, 103 monosandstone bodies and 87 flow units of the third levels have been identified, and four levels of flow units model of five sandstone-bodies types have been established. Because it is a very difficult task all over the world to research architecture in subsurface monosandstone body, brings forward a series of techniques as follows: technique of researching architecture of thin interbed in subsurface monosandstone body; classification, type and liquid-resisting mechanism of thin interbed; multiple-remember vertical subsequence model of remaining oil in monosadstone body. Models of heterogeneity and architecture of thin interbed in five types of monosandstone body have been established. Applying these techniques, type and distribution of remaining oil in different types of monosandstone bodies have been predicated.

岩溶水对不同环境的响应以及其与大气CO2源汇的关系－基于热力学的研究

碳酸盐岩是最大的无机碳库。这一无机碳库对全球变化的响应是目前科学界关心的一个重要问题。岩溶水是对外界气候和环境最敏感的介质。因此，认识不同环境条件下岩溶水体系对大气CO2源汇的贡献是认识碳酸盐岩无机碳库对全球变化响应的基础。 前人基于平衡常数热力学途径对岩溶水体系有一定的研究。本研究从热力学另一途径即吉布斯自由能原理出发，建立岩溶水体系（以方解石为例）的化学平衡式，采用Mathematic数学软件建立了岩溶水体系各组分的多参数方程，对其进行计算处理，本文主要对以下4个方面的内容进行了研究。 1. 对两种热力学途径计算值进行方差显著性分析，结果显示：基于吉布斯自由能途径的热力学方法是研究岩溶水SIc、pco2的有效方法，且其比平衡常数热力学途径的已有程序应用性更普遍，可应用于任一岩溶水体系的研究。 2. 研究了岩溶水对环境变化的响应。结果显示，岩溶水温度（T）、压强（p）、离子强度（I）、pH值的变化以及离子对存在与否等分别对岩溶水体系组分有重要的影响。其中，pH值对岩溶水体系组分的影响最大。 3. 对世界范围内不同岩溶地区140组实例岩溶水（河水、溪水等）进行研究，根据岩溶水体系SIc计算值，判定在所处环境条件下岩溶水体系与大气CO2源汇的潜在关系。结果显示，（1）河水、溪水、湖水等岩溶水在所处环境条件下释放CO2，因而是大气CO2的潜在源。（2）地下水在所处环境条件下是大气CO2潜在的汇。（3）泉水在所处环境条件下一部分是大气CO2潜在的源，另外一部分则是大气CO2潜在的汇。 4．对1993年、2002 ~ 2005年每年6月份红枫湖水SIc进行了计算并分析其变化趋势，结论如下：（1）据1993年以及近几年（2002 ~ 2005）监测的pH值，红枫湖水的pH值呈逐渐下降的大趋势。（2）红枫湖水1993年、2002 ~ 2005年每年6月份SIc呈下降的大趋势。这与对应年份红枫湖水pH值变化一致。红枫湖水SIc从1993年6月份的正值转变成2005年6月份的负值。这表明红枫湖水由发生方解石的沉积向发生方解石的溶解转变。 　　我们的研究表明，从吉布斯自由能途径热力学方法出发，不仅可以从理论上讨论岩溶水体系对岩溶环境差异的响应，而且也可应用于实例研究。特别是研究近年来西南地区酸雨对岩溶水体系的影响。因此，吉布斯自由能途径是一较好的方法。

Correct identification of polychlorinated biphenyls in temperature-programmed GC with ECD detection

A method has been developed for peak identification of PCBs in GC with ECD detection under different temperature programs and isothermal conditions on two commonly used columns (DB-5 and DB-1701). This was achieved by means of accurate calibration of retention times based on the concept of the relative retention index P-i and retention times of the selected PCB internal standards. The P-i was calculated from the predicted retention times with the database of the retention parameters (A, B) and the migration equations. Through comparison of the calibrated and experimental retention times of PCBs in technical samples, it was shown that the developed method was effective for correct PCB comprehensive, quantitative, congener-specific (CQCS) analyses.

Eficiência de fungicidas para controle da ferrugem asiática da soja, Phakopsora pachyrhizi, na safra 2006/07. Resultados sumarizados dos ensaios em rede.

2007

Eficiência de fungicidas para controle da ferrugem asiática da soja, Phakopsora pachyrhizi, na safra 2008/09. Resultados sumarizados dos ensaios cooperativos.

2009

Cultivar de soja BRS Nova Savana.

2001