Lämmöntuotannon energiatehokkuuden parantaminen Sotek-säätiön rakennuksissa

Diplomityössä tarkastellaan lämmöntuotannon energiatehokkuuden parantamista neljässä Sotek- säätiön rakennuksessa. Työssä oli tarkoitus selvittää, minkälainen lämmitysjärjestelmä on juuri kyseiseen kiinteistöön järkevin ja investointikustannuksiltaan kannattava. Työssä käydään läpi polttoaineita, lämmöntuotanto- ja lämmönjakotapoja, sekä mietitään kannattaako rakennuksia lisäeristää. Työssä verrataan vanhojen järjestelmien hiilidioksidipäästöjä valittujen uusien järjestelmien hiilidioksidipäästöihin. Kiinteistöjen lämmitys tuottaa Suomessa noin 30 % kaikista hiilidioksidipäästöistä. Se on siis merkittävä alue, josta päästöjä voitaisiin vähentää. Tehtävänä oli laskea kaikille kiinteistöille tarkat lämmitystarpeet ja lämmitystehontarpeet käyttäen apuna Suomen rakennusmääräyskokoelmaa. Työn perusteella lämmöntuotannon energiatehokkuuden parantaminen kohteissa on järkevää ja taloudellisesti kannattavaa muuttamalla lämmöntuotanto pääosin lämpöpumpuille. Täystehoiset järjestelmät eivät tulleet investoinnillisesti kannattavaksi, eikä se ilmalämpöpumpuissa ollut edes mahdollista. Tulosten perusteella lämmitysenergian kustannuksia saatiin vähennettyä parhaiten mitoittamalla kohteisiin osatehoiset lämpöpumput. Lisälämmöneristäminen kohteissa ei taloudellisesti tullut kannattavaksi, vaikka lämmitystarve väheni. Lämmöntuotannon hiilidioksidipäästöt vähenisivät kohteissa keskimäärin noin 50 %.

Sähkön kysyntäjouston kannattavuus teollisuuskiinteistössä

Tässä kandidaatintyössä tutkittiin sähkön kysyntäjouston kannattavuutta teollisuuskiinteis-tössä. Tutkimus suoritettiin tutkimalla vuosien 2014 ja 2015 sähkön käyttöraportteja sekä toteutuneita Elspot hintoja. Lisäksi suoritettiin mittauksia ilmalämpöpumpuista, joiden pe-rusteella selvitettiin ilmalämpöpumppujen soveltuvuutta kysyntäjoustoon. Työssä käydään läpi kysyntäjouston vaikutuksia sekä eri kuormanohjaus mahdollisuuksia asiakkaan näkökulmasta. Lisäksi tuodaan esille Elspot hinnan muodostuminen sekä Elspot hintaan vaikuttavat tekijät. Työssä vertaillaan esimerkkikiinteistön sähkönkulutuksen suh-detta toteutuneisiin Elspot hintoihin. Lisäksi tutkitaan lämmityskuormien ohjauspotentiaalia kysyntäjouston näkökulmasta. Potentiaalin kartoittamiseksi suoritettiin mittauksia sekä teh-tiin esimerkkilaskelmia kysyntäjouston kannattavuudesta. Tutkimusten perusteella voidaan huomata, että vuositasolla saavutetut säästöt jäävät pienik-si. Huomioiden riskit Elspot hinnan vaihteluissa voidaan todetta, ettei siirtyminen tuntihin-noiteltuun sähköenergiaan ole kannattavaa esimerkkikiinteistössä. Lämmityskuormien oh-jauksesta tuntitiedon mukaan saatavien lisäsäästöjen jäädessä vähäisiksi kiinteistöön ei ole järkevää investoida erillisiä järjestelmiä kuormien ohjaukseen.

Entwicklung und Anwendung einer Kraftwerks- und Speichereinsatzoptimierung für die Untersuchung von Energieversorgungsszenarien mit hohem Anteil erneuerbarer Energien in Deutschland

In dieser Arbeit wurde ein gemischt-ganzzahliges lineares Einsatzoptimierungsmodell für Kraftwerke und Speicher aufgebaut und für die Untersuchung der Energieversorgung Deutschlands im Jahre 2050 gemäß den Leitstudie-Szenarien 2050 A und 2050 C ([Nitsch und Andere, 2012]) verwendet, in denen erneuerbare Energien einen Anteil von über 85 % an der Stromerzeugung haben und die Wind- und Solarenergie starke Schwankungen der durch steuerbare Kraftwerke und Speicher zu deckenden residualen Stromnachfrage (Residuallast) verursachen. In Szenario 2050 A sind 67 TWh Wasserstoff, die elektrolytisch aus erneuerbarem Strom zu erzeugen sind, für den Verkehr vorgesehen. In Szenario 2050 C ist kein Wasserstoff für den Verkehr vorgesehen und die effizientere Elektromobilität hat einen Anteil von 100% am Individualverkehr. Daher wird weniger erneuerbarer Strom zur Erreichung desselben erneuerbaren Anteils im Verkehrssektor benötigt. Da desweiteren Elektrofahrzeuge Lastmanagementpotentiale bieten, weisen die Residuallasten der Szenarien eine unterschiedliche zeitliche Charakteristik und Jahressumme auf. Der Schwerpunkt der Betrachtung lag auf der Ermittlung der Auslastung und Fahrweise des in den Szenarien unterstellten ’Kraftwerks’-parks bestehend aus Kraftwerken zur reinen Stromerzeugung, Kraft-Wärme-Kopplungskraftwerken, die mit Wärmespeichern, elektrischen Heizstäben und Gas-Backupkesseln ausgestattet sind, Stromspeichern und Wärmepumpen, die durch Wärmespeicher zum Lastmanagment eingesetzt werden können. Der Fahrplan dieser Komponenten wurde auf minimale variable Gesamtkosten der Strom- und Wärmeerzeugung über einen Planungshorizont von jeweils vier Tagen hin optimiert. Das Optimierungsproblem wurde mit dem linearen Branch-and-Cut-Solver der software CPLEX gelöst. Mittels sogenannter rollierender Planung wurde durch Zusammensetzen der Planungsergebnisse für überlappende Planungsperioden der Kraftwerks- und Speichereinsatz für die kompletten Szenariojahre erhalten. Es wurde gezeigt, dass der KWK-Anteil an der Wärmelastdeckung gering ist. Dies wurde begründet durch die zeitliche Struktur der Stromresiduallast, die wärmeseitige Dimensionierung der Anlagen und die Tatsache, dass nur eine kurzfristige Speicherung von Wärme vorgesehen war. Die wärmeseitige Dimensionierung der KWK stellte eine Begrenzung des Deckungsanteils dar, da im Winter bei hoher Stromresiduallast nur wenig freie Leistung zur Beladung der Speicher zur Verfügung stand. In den Berechnungen für das Szenario 2050 A und C lag der mittlere Deckungsanteil der KWK an der Wärmenachfrage von ca. 100 TWh_th bei 40 bzw. 60 %, obwohl die Auslegung der KWK einen theoretischen Anteil von über 97 % an der Wärmelastdeckung erlaubt hätte, gäbe es die Beschränkungen durch die Stromseite nicht. Desweiteren wurde die CO2-Vermeidungswirkung der KWK-Wärmespeicher und des Lastmanagements mit Wärmepumpen untersucht. In Szenario 2050 A ergab sich keine signifikante CO2-Vermeidungswirkung der KWK-Wärmespeicher, in Szenario 2050 C hingegen ergab sich eine geringe aber signifikante CO2-Einsparung in Höhe von 1,6 % der Gesamtemissionen der Stromerzeugung und KWK-gebundenen Wärmeversorgung. Das Lastmanagement mit Wärmepumpen vermied Emissionen von 110 Tausend Tonnen CO2 (0,4 % der Gesamtemissionen) in Szenario A und 213 Tausend Tonnen in Szenario C (0,8 % der Gesamtemissionen). Es wurden darüber hinaus Betrachtungen zur Konkurrenz zwischen solarthermischer Nahwärme und KWK bei Einspeisung in dieselben Wärmenetze vorgenommen. Eine weitere Einschränkung der KWK-Erzeugung durch den Einspeisevorrang der Solarthermie wurde festgestellt. Ferner wurde eine untere Grenze von 6,5 bzw. 8,8 TWh_th für die in den Szenarien mindestens benötigte Wasserstoff-Speicherkapazität ermittelt. Die Ergebnisse dieser Arbeit legen nahe, das technisch-ökonomische Potential von Langzeitwärmespeichern für eine bessere Integration von KWK ins System zu ermitteln bzw. generell nach geeigneteren Wärmesektorszenarien zu suchen, da deutlich wurde, dass für die öffentliche Wärmeversorgung die KWK in Kombination mit Kurzzeitwärmespeicherung, Gaskesseln und elektrischen Heizern keine sehr effektive CO2 -Reduktion in den Szenarien erreicht. Es sollte dabei z.B. untersucht werden, ob ein multivalentes System aus KWK, Wärmespeichern und Wärmepumpen eine ökonomisch darstellbare Alternative sein könnte und im Anschluss eine Betrachtung der optimalen Anteile von KWK, Wärmepumpen und Solarthermie im Wärmemarkt vorgenommen werden.

UK Zero Carbon Homes 2016 - Exemplary Development

In October 2008 UK government announced very ambitious commitment to reduce greenhouse gas emissions of at least 34% by 2020 and by 80% by 2050 against a 1990 baseline. Consequently the government declares that new homes should be built to high environmental standards which means that from 2016 new homes will have to be built to a Zero Carbon standard. The paper sets out to present UK zero carbon residential development achieving the highest, Level 6 of Code for Sustainable Homes standard. Comprehensive information is provided about various environmental aspects of the housing development. Special attention is given to energy efficiency features of the houses and low carbon district heating solution which include biomass boiler, heat pumps, solar collectors and photovoltaic panels. The paper presents also challenges which designers and builders had to face delivering houses of the future.

The evolution of electricity demand and the role for demand side participation, in buildings and transport

This paper explores the possible evolution of UK electricity demand as we move along three potential transition pathways to a low carbon economy in 2050.The shift away from fossil fuels through the electrification of demand is discussed, particularly through the uptake of heat pumps and electric vehicles in the domestic and passenger transport sectors. Developments in the way people and institutions may use energy along each of the pathways are also considered and provide a rationale for the quantification of future annual electricity demands in various broad sectors. The paper then presents detailed modelling of hourly balancing of these demands in the context of potential low carbon generation mixes associated with the three pathways. In all cases, hourly balancing is shown to be a significant challenge. To minimise the need for conventional generation to operate with very low capacity factors, a variety of demand side participation measures are modelled and shown to provide significant benefits. Lastly, projections of greenhouse gas emissions from the UK and the imports of fossil fuels to the UK for each of the three pathways are presented.

The impact of installer business models on the uptake of residential microgeneration in the UK: Evidence from a nation-wide survey

This paper arises from a doctoral thesis comparing the impact of alternative installer business models on the rate at which microgeneration is taken up in homes and installation standards across the UK. The paper presents the results of the first large-scale academic survey of businesses certified to install residential microgeneration. The aim is to systematically capture those characteristics which define the business model of each surveyed company, and relate these to the number, location and type of technologies that they install, and the quality of these installations. The methodology comprised a pilot web survey of 235 certified installer businesses, which was carried out in June last year and achieved a response rate of 30%. Following optimisation of the design, the main web survey was emailed to over 2000 businesses between October and December 2011, with 317 valid responses received. The survey is being complemented during summer 2012 by semi-structured interviews with a representative sample of installers who completed the main survey. The survey results are currently being analysed. The early results indicate an emerging and volatile market where solar PV, solar hot water and air source heat pumps are the dominant technologies. Three quarters of respondents are founders of their installer business, while only 22 businesses are owned by another company. Over half of the 317 businesses have five employees or less, while 166 businesses are no more than four years old. In addition, half of the businesses stated that 100% of their employees work on microgeneration-related activities. 85% of the surveyed companies have only one business location in the UK. A third of the businesses are based either in the South West or South East regions of England. This paper outlines the interim results of the survey combined with the outcomes from additional interviews with installers to date. The research identifies some of the business models underpinning microgeneration installers and some of the ways in which installer business models impact on the rate and standards of microgeneration uptake. A tentative conclusion is that installer business models are profoundly dependent on the levels and timing of support from the UK Feed-in Tariffs and Renewable Heat Incentive.

Combined solar and pellet heating systems for single-family houses : How to achieve decreased electricity usage, increased system efficiency and increased solar gains

In Sweden, there are about 0.5 million single-family houses that are heated by electricity alone, and rising electricity costs force the conversion to other heating sources such as heat pumps and wood pellet heating systems. Pellet heating systems for single-family houses are currently a strongly growing market. Future lack of wood fuels is possible even in Sweden, and combining wood pellet heating with solar heating will help to save the bio-fuel resources. The objectives of this thesis are to investigate how the electrically heated single-family houses can be converted to pellet and solar heating systems, and how the annual efficiency and solar gains can be increased in such systems. The possible reduction of CO-emissions by combining pellet heating with solar heating has also been investigated. Systems with pellet stoves (both with and without a water jacket), pellet boilers and solar heating have been simulated. Different system concepts have been compared in order to investigate the most promising solutions. Modifications in system design and control strategies have been carried out in order to increase the system efficiency and the solar gains. Possibilities for increasing the solar gains have been limited to investigation of DHW-units for hot water production and the use of hot water for heating of dishwashers and washing machines via a heat exchanger instead of electricity (heat-fed appliances). Computer models of pellet stoves, boilers, DHW-units and heat-fed appliances have been developed and the parameters for the models have been identified from measurements on real components. The conformity between the models and the measurements has been checked. The systems with wood pellet stoves have been simulated in three different multi-zone buildings, simulated in detail with heat distribution through door openings between the zones. For the other simulations, either a single-zone house model or a load file has been used. Simulations were carried out for Stockholm, Sweden, but for the simulations with heat-fed machines also for Miami, USA. The foremost result of this thesis is the increased understanding of the dynamic operation of combined pellet and solar heating systems for single-family houses. The results show that electricity savings and annual system efficiency is strongly affected by the system design and the control strategy. Large reductions in pellet consumption are possible by combining pellet boilers with solar heating (a reduction larger than the solar gains if the system is properly designed). In addition, large reductions in carbon monoxide emissions are possible. To achieve these reductions it is required that the hot water production and the connection of the radiator circuit is moved to a well insulated, solar heated buffer store so that the boiler can be turned off during the periods when the solar collectors cover the heating demand. The amount of electricity replaced using systems with pellet stoves is very dependant on the house plan, the system design, if internal doors are open or closed and the comfort requirements. Proper system design and control strategies are crucial to obtain high electricity savings and high comfort with pellet stove systems. The investigated technologies for increasing the solar gains (DHW-units and heat-fed appliances) significantly increase the solar gains, but for the heat-fed appliances the market introduction is difficult due to the limited financial savings and the need for a new heat distribution system. The applications closest to market introduction could be for communal laundries and for use in sunny climates where the dominating part of the heat can be covered by solar heating. The DHW-unit is economical but competes with the internal finned-tube heat exchanger which is the totally dominating technology for hot water preparation in solar combisystems for single-family houses.

Dynamic whole system testing of combined renewable heating systems : the current state of the art

Objective: For the evaluation of the energetic performance of combined renewable heating systems that supply space heat and domestic hot water for single family houses, dynamic behaviour, component interactions, and control of the system play a crucial role and should be included in test methods. Methods: New dynamic whole system test methods were developed based on “hardware in the loop” concepts. Three similar approaches are described and their differences are discussed. The methods were applied for testing solar thermal systems in combination with fossil fuel boilers (heating oil and natural gas), biomass boilers, and/or heat pumps. Results: All three methods were able to show the performance of combined heating systems under transient operating conditions. The methods often detected unexpected behaviour of the tested system that cannot be detected based on steady state performance tests that are usually applied to single components. Conclusion: Further work will be needed to harmonize the different test methods in order to reach comparable results between the different laboratories. Practice implications: A harmonized approach for whole system tests may lead to new test standards and improve the accuracy of performance prediction as well as reduce the need for field tests.

Performance evaluation of ventilation radiators

A ventilation radiator is a combined ventilation and heat emission unit currently of interest due to its potential for increasing energy efficiency in exhaust ventilated buildings with warm water heating. This paper presents results of performance tests of several ventilation radiator models conducted under controlled laboratory conditions.   The purpose of the study was to validate results achieved by Computational Fluid Dynamics (CFD) in an earlier study and indentify possible improvements in the performance of such systems. The main focus was on heat transfer from internal convection fins, but comfort and health aspects related to ventilation rates and air temperatures were also considered.   The general results from the CFD simulations were confirmed; the heat output of ventilation radiators may be improved by at least 20 % without sacrificing ventilation efficiency or thermal comfort.   Improved thermal efficiency of ventilation radiators allows a lower supply water temperature and energy savings both for heating up and distribution of warm water in heat pumps or district heating systems. A secondary benefit is that a high ventilation rate can be maintained all year around without risk for cold draught.

Propriedades Físicas do Semicondutor Bi2Te3

Thermoelectric Refrigerators (TEC Thermoelectric Cooling) are solid-state heat pumps used in applications where stabilization of temperature cycles or cooling below the room temperature are required. TEC are based on thermoelectric devices, and these in turn, are based on the Peltier effect, which is the production of a difference in temperature when an electric current is applied to a junction formed by two non-similar materials. This is one of the three thermoelectric effects and is a typical semiconductor junction phenomenon. The thermoelectric efficiency, known as Z thermoelectric or merit figure is a parameter that measures the quality of a thermoelectric device. It depends directly on electrical conductivity and inversely on the thermal conductivity. Therefore, good thermoelectric devices have typically high values of electrical conductivity and low values of thermal conductivity. One of the most common materials in the composition of thermoelectric devices is the semiconductor bismuth telluride (Bi2Te3) and its alloys. Peltier plates made up by crystals of semiconductor P-type and N-type are commercially available for various applications in thermoelectric systems. In this work, we characterize the electrical properties of bismuth telluride through conductivity/resistivity of the material, and X-rays power diffraction and magnetoresistance measurements. The results were compared with values taken from specific literature. Moreover, two techniques of material preparation, and applications in refrigerators, are discussed

Coeficiente de operación de un sistema formado por un refrigerador doméstico acoplado a un acumulador de agua caliente para la recuperación de energía

An experimental apparatus containing a domestic refrigerator coupled to a vertical hot water storage tank was used for energy recovery. The original condenser of the refrigerator was maintained, but modified with a concentric tubes heat exchanger with countercurrent water and refrigerating gas flows. The coefficient of performance for the heat pump is calculated by the ratio of energy in the heat storage and the electric power consumed by the domestic refrigerator compressor. The results show that the increasing of hydrostatic pressure in the storage tank increases the water flow rate and the coefficient of performance. The proposed device also reduces the heat dissipation to the surroundings. This is more important in small confinements found in low-cost houses.

APR e FMEA em trocador de calor de bomba

The modernization of the world made the speed, accuracy and reliability of all existing processes become increasingly necessary. For this evolution to occur every day, the evolution of the equipment was strategic, but not as much as needed. It is necessary for such equipment to ensure its function and, in case of failure, an early diagnosis to prevent loss. Therefore the evolution of maintainability and reliability in equipment is also paramount. Thus, the growth of forms of maintenance was driven by this scenario, forming maintenance philosophies. Among many, there is the RCM, which have its focus on the identification, parameters development and performance preview. One of those methodologies from this idea is the FMEA, process that has been studied and implemented this work, aiming the anticipation of failure modes and guidance for the use of a heat exchanger and a pump. This implementation has the aid of another process of RCM, the PHA, which was also shown and implemented, these results being used to start the FMEA process. The results show the activities with the highest chance of failure, presenting also the measures to be taken to avoid or minimize them. It is shown, in this paper, concern with the valves because they maintain control and system security, and its flaws related to accidents with possible danger to people and the whole system, emphasizing the priority of action

APR e FMEA em trocador de calor de bomba

The modernization of the world made the speed, accuracy and reliability of all existing processes become increasingly necessary. For this evolution to occur every day, the evolution of the equipment was strategic, but not as much as needed. It is necessary for such equipment to ensure its function and, in case of failure, an early diagnosis to prevent loss. Therefore the evolution of maintainability and reliability in equipment is also paramount. Thus, the growth of forms of maintenance was driven by this scenario, forming maintenance philosophies. Among many, there is the RCM, which have its focus on the identification, parameters development and performance preview. One of those methodologies from this idea is the FMEA, process that has been studied and implemented this work, aiming the anticipation of failure modes and guidance for the use of a heat exchanger and a pump. This implementation has the aid of another process of RCM, the PHA, which was also shown and implemented, these results being used to start the FMEA process. The results show the activities with the highest chance of failure, presenting also the measures to be taken to avoid or minimize them. It is shown, in this paper, concern with the valves because they maintain control and system security, and its flaws related to accidents with possible danger to people and the whole system, emphasizing the priority of action

Modelli di scambio termico in pozzo sulla base della caratterizzazione geotermica di un reservoir a bassa entalpia: studio di sensitività sulla efficienza dei sistemi di condizionamento a pompa di calore

Tra i temi di attualità, quello del risparmio energetico è tra i più dibattuti negli ultimi anni; tale tema è strettamente correlato al problema del riscaldamento globale, infatti, mentre sul prossimo esaurimento delle risorse energetiche tradizionali non vi sono ancora certezze assolute, per quanto riguarda l’azione nociva dei gas serra, la Comunità Scientifica Internazionale si ritrova d’accordo su una netta presa di posizione contro l’emissione di tali sostanze, provocata in larga parte dall’utilizzo dei combustibili fossili. In questo contesto, l’Unione Europea sta promuovendo la diffusione di tecnologie che non prevedano l’utilizzo di gas, petrolio o carbone, soprattutto per il settore dell’edilizia, ove una corretta progettazione e l’utilizzo di tecnologie non convenzionali può portare alla riduzione anche dell’80% dei consumi, con conseguente abbattimento delle emissioni. Tra questi interventi innovativi, il più comune e conosciuto è sicuramente quello del solare termico e fotovoltaico; ma ne esistono anche di altri, ancora non molto pubblicizzati in Italia, ma ampiamente conosciuti e utilizzati in altri paesi dell’Unione. Tra questi, vi è il sistema di riscaldamento analizzato in questa tesi: la pompa di calore geotermica. Tale sistema, come verrà spiegato nell’elaborato di laurea, ha indubbi vantaggi economici, energetici ed ambientali, a fronte di una non trascurabile spesa iniziale. Attualmente, nel Nord Italia, si incominciano a vedere impianti di questo tipo, sulla scia del successo riscontrato nei paesi confinanti (in particolare Austria e Svizzera). La progettazione si basa attualmente su modelli statici, sviluppati dall’Università Svizzera del Canton Ticino, per l’utilizzo della pompa di calore nel territorio alpino. Obiettivo della tesi, è la verifica di tali modelli, di cui si è venuto a conoscenza grazie alla collaborazione con l’Università SUPSI, sulle condizioni idrogeologiche della Pianura Padana, soffermandosi su alcuni parametri fondamentali della progettazione di una pompa di calore geotermica, quali la conduttività e la capacità termica volumetrica dei terreni incontrati, la presenza di falde, ed i parametri geometrici del pozzo, al fine di dare una valutazione tecnica ed economica dell’impianto. Tali analisi è stata infatti fino ad ora affrontata in maniera sommaria dai perforatori, che eseguono generalmente sempre lo stesso modello di pozzo geotermico, sulla base degli esempi consolidati di Svizzera e Germania. Alcune misure di temperatura in situ sono state rilevate in collaborazione con la società Geotermia SRL di Mantova, ditta specializzata nella perforazione di pozzi geotermici (tale esperienza è parte centrale dell’estratto “Laboratorio di Tesi Ls”), mentre la parte modellistica della tesi è stata sviluppata in collaborazione con lo studio di progettazione Studio Seta SRL di Faenza, il cui stabile è climatizzato in parte con una pompa di calore geotermica.

Second law analysis and simulation techniques for the energy optimization of buildings

The research activity described in this thesis is focused mainly on the study of finite-element techniques applied to thermo-fluid dynamic problems of plant components and on the study of dynamic simulation techniques applied to integrated building design in order to enhance the energy performance of the building. The first part of this doctorate thesis is a broad dissertation on second law analysis of thermodynamic processes with the purpose of including the issue of the energy efficiency of buildings within a wider cultural context which is usually not considered by professionals in the energy sector. In particular, the first chapter includes, a rigorous scheme for the deduction of the expressions for molar exergy and molar flow exergy of pure chemical fuels. The study shows that molar exergy and molar flow exergy coincide when the temperature and pressure of the fuel are equal to those of the environment in which the combustion reaction takes place. A simple method to determine the Gibbs free energy for non-standard values of the temperature and pressure of the environment is then clarified. For hydrogen, carbon dioxide, and several hydrocarbons, the dependence of the molar exergy on the temperature and relative humidity of the environment is reported, together with an evaluation of molar exergy and molar flow exergy when the temperature and pressure of the fuel are different from those of the environment. As an application of second law analysis, a comparison of the thermodynamic efficiency of a condensing boiler and of a heat pump is also reported. The second chapter presents a study of borehole heat exchangers, that is, a polyethylene piping network buried in the soil which allows a ground-coupled heat pump to exchange heat with the ground. After a brief overview of low-enthalpy geothermal plants, an apparatus designed and assembled by the author to carry out thermal response tests is presented. Data obtained by means of in situ thermal response tests are reported and evaluated by means of a finite-element simulation method, implemented through the software package COMSOL Multyphysics. The simulation method allows the determination of the precise value of the effective thermal properties of the ground and of the grout, which are essential for the design of borehole heat exchangers. In addition to the study of a single plant component, namely the borehole heat exchanger, in the third chapter is presented a thorough process for the plant design of a zero carbon building complex. The plant is composed of: 1) a ground-coupled heat pump system for space heating and cooling, with electricity supplied by photovoltaic solar collectors; 2) air dehumidifiers; 3) thermal solar collectors to match 70% of domestic hot water energy use, and a wood pellet boiler for the remaining domestic hot water energy use and for exceptional winter peaks. This chapter includes the design methodology adopted: 1) dynamic simulation of the building complex with the software package TRNSYS for evaluating the energy requirements of the building complex; 2) ground-coupled heat pumps modelled by means of TRNSYS; and 3) evaluation of the total length of the borehole heat exchanger by an iterative method developed by the author. An economic feasibility and an exergy analysis of the proposed plant, compared with two other plants, are reported. The exergy analysis was performed by considering the embodied energy of the components of each plant and the exergy loss during the functioning of the plants.