Gas-phase nitronium ion affinities.

Evaluation of nitronium ion-transfer equilibria, L1NO2+ + L2 = L2NO2+ + L1 (where L1 and L2 are ligands 1 and 2, respectively) by Fourier-transform ion cyclotron resonance mass spectrometry and application of the kinetic method, based on the metastable fragmentation of L1(NO2+)L2 nitronium ion-bound dimers led to a scale of relative gas-phase nitronium ion affinities. This scale, calibrated to a recent literature value for the NO2+ affinity of water, led for 18 ligands, including methanol, ammonia, representative ketones, nitriles, and nitroalkanes, to absolute NO2+ affinities, that fit a reasonably linear general correlation when plotted vs. the corresponding proton affinities (PAs). The slope of the plot depends to a certain extent on the specific nature of the ligands and, hence, the correlations between the NO2+ affinities, and the PAs of a given class of compounds display a better linearity than the general correlation and may afford a useful tool for predicting the NO2+ affinity of a molecule based on its PA. The NO2+ binding energies are considerably lower than the corresponding PAs and well below the binding energies of related polyatomic cations, such as NO+, a trend consistent with the available theoretical results on the structure and the stability of simple NO2+ complexes. The present study reports an example of extension of the kinetic method to dimers, such as L1(NO2+)L2, bound by polyatomic ions, which may considerably widen its scope. Finally, measurement of the NO2+ affinity of ammonia allowed evaluation of the otherwise inaccessible PA of the amino group of nitramide and, hence, direct experimental verification of previous theoretical estimates.

Biostratigraphy and paleobiogeographic affinities of the Jurassic brachiopod assemblages from Sierra Espuña (Maláguide Complex, Internal Betic Zones, Spain)

The assemblages of Early Jurassic brachiopods (Pliensbachian - Toarcian) from Sierra Espuña (Murcia Province, SE Spain) are described. This is the only area in the Internal Zones of the Betic Cordillera, corresponding to the margins of the Alborán Terrane, where Jurassic brachiopods are known to occur. In the tectonic Unit of Morrón de Totana (more southward located) assemblage MT1 of Late Pliensbachian age has been characterized. This assemblage has been subdivided into three successive sub-assemblages: MT1a (Algovianum Zone), MT1b (Emaciatum Zone, Solare Subzone) and MT1c (Emaciatum Zone, Elisa Subzone). Northward, in the Perona tectonic Unit two distinct assemblages, P1 (Latest Sinemurian - Early Pliensbachian) and P2 (Early Toarcian, Serpentinum Zone) have been recognized. Differences between the assemblages from the two tectonic units are evident after the paleobiogeographical analysis. In the Morrón de Totana Unit, taxa with Mediterranean affinities occur. MT1 assemblage is very similar to assemblages previously known in the Eastern Subbetic as well as in other areas of the Mediterranean Province. In the Perona Unit the Mediterranean affinity of the assemblages is not so evident. P1 Assemblage consists of widely distributed taxa, lacking in the most characteristic elements of the Mediterranean Province which, however, are present in neighbouring Betic areas. P2 Assemblage belongs to the Spanish Province that develops in Western Tethys after the Early Toarcian Mass Extinction Event. The occurrence in this assemblage of Prionorhynchia aff. msougari Rousselle, until now only found in North Africa, indicates a closer connection of the Perona Unit with the African paleomargin of the Tethys than with the South Iberian paleomargin. The paleobiogeographical data suggest a more southern and marginal (close to epicontinental areas) position of the Perona Unit than the Morrón de Totana Unit.

Pennsylvanian invertebrates of the Mazon Creek Area, Illinois: the morphology and affinities of Tullimonstrum / Ralph Gordon Johnson -- and Eugene S. Richardson, Jr. --

v.12:no.8(1969)

Catalogue of birds of the Americas and the adjacent islands in Field Museum of Natural History and including all species and subspecies known to occur in North America, Mexico, Central America, South America, the West Indies, and islands of the Caribbean Sea, the Galapagos Archipelago, and other islands which may properly be included on account of their faunal affinities.

v.13:pt.1:no.1(1942)

An annotated bibliography on proton affinities /

Item 247.

The romance of devotion; famous affinities history,

Mode of access: Internet.

Preadamites; or, A demonstration of the existence of men before Adam : together with a study of their condition, antiquity, racial affinities, and progressive dispersion over the earth.

"Preadamitism in literature": p. 454-474.

The dolmens of Ireland, their distribution, structural characteristics, and affinities in other countries; together with the folk-lore attaching to them; supplemented by considerations on the anthropology, ethnology, and traditions of the Irish people. With four maps, and eight hundred illustrations, including two coloured plates.

Mode of access: Internet.

Observations on the structure and affinities of the more remarkable plants : collected by the late Walter Oudney and Major Denham and Captain Clapperton in the years 1822, 1823, and 1824, during their expedition to explore Central Africa.

"Printed as the Botanical appendix to the Narrative of travels and discoveries in Northern and Central Africa."

A natural system of botany, or, A systematic view of the organization, natural affinities, and geographical distribution, of the whole vegetable kingdom : together with the uses of the most important species in medicine, the arts, and rural or domestic economy /

Includes index.

An introduction to the natural system of botany: or, A systematic view of the organization, natural affinities, and geographical distribution of the whole vegetable kingdom; together with the uses of the most important species in medicine, the arts, and rural or domestic economy.

Mode of access: Internet.

Labiatarum genera et species ; or, A description of the genera and species of plants of the order labiatae; with their general history, characters, affinities, and geographical distribution.

Stafleu and Cowan, 2d ed.

Etymologicon universale: or, Universal etymological dictionary. On a new plan. In which it is shewn, that consonants are alone to be regarded in discovering the affinities of words, and that the vowels are to be wholly rejected; that languages contain the same fundamental idea; and that they are derived from the earth, and the operations, accidents, and properties belonging to it. /

Not a continuation of the author's "Etymologicon magnum."

Famous affinities of history : the romance of devotion /

Mode of access: Internet.