Avaliação mecânica e microestrutural de compósitos de poliéster com adição de cargas minerais e resíduos industriais

With the current growth in consumption of industrialized products and the resulting increase in garbage production, their adequate disposal has become one of the greatest challenges of modern society. The use of industrial solid residues as fillers in composite materials is an idea that emerges aiming at investigating alternatives for reusing these residues, and, at the same time, developing materials with superior properties. In this work, the influence of the addition of sand, diatomite, and industrial residues of polyester and EVA (ethylene vinyl acetate), on the mechanical properties of polymer matrix composites, was studied. The main objective was to evaluate the mechanical properties of the materials with the addition of recycled residue fillers, and compare to those of the pure polyester resin. Composite specimens were fabricated and tested for the evaluation of the flexural properties and Charpy impact resistance. After the mechanical tests, the fracture surface of the specimens was analyzed by scanning electron microscopy (SEM). The results indicate that some of the composites with fillers presented greater Young s modulus than the pure resin; in particular composites made with sand and diatomite, where the increase in modulus was about 168 %. The composites with polyester and EVA presented Young s modulus lower than the resin. Both strength and maximum strain were reduced when fillers were added. The impact resistance was reduced in all composites with fillers when compared to the pure resin, with the exception of the composites with EVA, where an increase of about 6 % was observed. Based on the mechanical tests, microscopy analyses and the compatibility of fillers with the polyester resin, the use of industrial solid residues in composites may be viable, considering that for each type of filler there will be a specific application

Obtenção de emulsões asfálticas modificadas utilizando resíduos industriais

The main objective of this research was the development and characterization of conventional and modified cationic asphalt emulsions. The asphalt emulsions were developed by using the Petroleum Asphalt Cement (CAP 50-70) from Fazenda Belém (Petrobras -Aracati-Ce). The first step in this research was the development of the oil phase (asphalt + solvent) and the aqueous phase (water + emulsifying agent + acid + additives), separately. During the experiments for the obtaining of the conventional asphalt emulsion, the concentration of each constituent was evaluated. For the obtaining of the oil phase, kerosene was used as solvent at 15 and 20 wt.%. For the development of the aqueous phase, the emulsifying agent was used at 0.3 and 3.0 wt.%, whereas the acid and the additive were set at 0.3 wt.%. The percentage of asphalt in the asphalt emulsion was varied in 50, 55, and 60 wt.% and the heating temperature was set at 120 °C. The aqueous phase in the asphalt emulsion was varied from 16.4 to 34.1 wt.% and the heating temperature was set at 60 °C. After the obtaining of the oil and the aqueous phases, they were added at a colloidal mill, remaining under constant stirring and heating during 15 minutes. Each asphalt emulsion was evaluated considering: sieve analysis, Saybolt Furol viscosity, pH determination, settlement and storage stability, residue by evaporation, and penetration of residue. After the characterization of conventional emulsions, it was chosen the one that presented all properties in accordance with Brazilian specifications (DNER-EM 369/97). This emulsion was used for the development of all modified asphalt emulsions. Three polymeric industrial residues were used as modifier agents: one from a clothing button industry (cutouts of clothing buttons) and two from a footwear industry (cutouts of sandals and tennis shoes soles), all industries located at Rio Grande do Norte State (Brazil).The polymeric residues were added into the asphalt emulsion (1 to 6 wt.%) and the same characterization rehearsals were accomplished. After characterization, it were developed the cold-mix asphalts. It was used the Marshall mix design. For cold-mix asphalt using the conventional emulsion, it was used 5, 6 and 7 wt.% asphalt emulsion. The conventional mixtures presented stability values according Brazilian specification (DNER-369/97). For mixtures containing asphalt modified emulsions, it was observed that the best results were obtained with emulsions modified by button residue

Caracterização dos óleos de algumas sementes de frutas como aproveitamento de resíduos industriais

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Espécies vegetais de cobertura e resíduos industriais e urbanos na cultura da soja em sistema de semeadura direta

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Proposta para o uso e manejo sustentável da bacia hidrográfica do Ribeirão Guaratinguetá, SP

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Obtenção de fotocatalisadores magnéticos a partir de resíduos industriais e TiO2 para a degradação de contaminantes orgânicos

In this work, magnetic photocatalysts were synthesized containing differents levels of TiO2 (40, 60 e 80%) supported at the supporter of C/LV, forming the photocatalysts 40, 60, 80Ti/C/LV, using tar pitch as carbon (C) source and red mud (LV) as iron source. The prepared magnetic photocatalysts and TiO2 were used to degrade the Remazol Black textile dye (PR5) and the organic material present in samples of a textile dye effluent. The characterization of photocatalysts by Raman, X-Ray Diffraction, Transmission Electron Micoscope and Scanning, Energy Dispersive X-ray Spectrometry, Termogravimetry and Elemental Analysis, confirms the presence of carbon and magnetite in support C/LV and the presence of TiO2 in prepared photocatalysts. The photocatalytic reactions with TiO2 were analyzed by different experimental conditions, such as: mass of TiO2 (30-240 mg), solution pH (2-10), light intensity (0.871 and 1.20 mWcm-2), type of radiation (UV and sunlight-1.420 mWcm-2), radiation incidence area (44.2 to 143.1 cm2) and dissolved oxygen (OD, 1.9 and 7.6 mg L- 1). Results showed that reactions with the following conditions: 220 mg of TiO2, pH 10, solar radiation, 7.6 mg L-1 of OD and an incidence area of radiation of 143.1 cm2 showed the best results for degradation of PR5 dye. Photocatalytic reactions with magnetic photocatalysts for degrading PR5 shows that efficiency increases with TiO2 content in the C/LV support, where, above 60% of TiO2, there was not significant increase in reaction velocity. In addition, solar radiation has proved to be advantageous for photocatalytic reactions. In order to verify the presence of a non-magnetic fraction in the photocatalyst 60Ti/C/LV0, magnetic separation was proceeded. The characterizations of the magnetic (FM) and nonmagnetic (NMF) fraction confirmed that about 25% of TiO2 did not fixed in 60Ti/C/LV photocatalyst. Results of photocatalytic reactions with FM and FNM showed that both phases have photocatalytic activity for degradation of PR5. The reactions executed for the degradation of organic matter present in the actual sample of textile effluent showed that TiO2 and magnetic photocatalyst 60Ti/C/ LV have better results for color removal (85 to 35%), soluble solids ( 11 and 3%), DQO (90 and 86%) and turbidity (94 and 11%) than the treatment done by the textile industry. Sedimentation kinetics tests in presence of a magnet showed that photocatalysts are separated faster from aqueous environment than pure TiO2. Obtained results showed that magnetic photocatalysts have excellent photocatalytic activity and can be separated from the reaction environment on a simple and quick way when a magnetic field is applied.

Avaliação da toxicidade de resíduos industriais e urbanos aplicados na agricultura

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Estudo de parâmetros físicoquímicos para a produção de argamassas utilizando resíduos industriais e da construção civil

As argamassas podem ser consideradas como a mistura de aglomerantes e agregados com água, possuindo capacidade de endurecimento e aderência. Como alternativa, é proposto produção de argamassas utilizando como agregado miúdo resíduos de construção civil (RCC), rico em silicoaluminatos, gerado nas obras de demolições e reformas, e cinza volante (CV) como material pozolânico, obtida a partir da combustão do carvão mineral em caldeiras de leitos fluidizados, em substituição parcial ao cimento Portland. Neste contexto, o resíduo de construção civil foi beneficiado e caracterizado pelas análises de espectrofotometria de raios- X e difração de raios-X, a cinza volante foi caracterizada pela análise granulométrica e espectrofotometria de raios-X. Para produção das argamassas formularam-se composições de RCC nas proporções de 95, 90, 85, 80, 75 e 70%; CV de 0, 5, 10, 15, 20 e 25% e 5% de cimento Portland CP II Z 32, sendo que em cada composição do traço de argamassa foi adicionado 0,8% em volume de água e para o ensaio reológico utilizou-se as mesmas proporções de resíduos (RCC e CV) com 35% em volume de água. Após a cura de 28 dias os corpos de prova foram submetidos a ensaios físicos de absorção, porosidade e massa específica aparente; ensaio mecânico de resistência à compressão e análise de difração de raios-X e microscopia eletrônica de varredura, cujos resultados obtidos mostraram-se ser viável a utilização da cinza volante e RCC na construção civil, na produção de argamassas.

Proposta de plano de marketing para os serviços de acolhimento a visitantes na igreja de Frei Galvão e Guaratinguetá (SP)

This work contains a preliminary marketing plan for host services on Frei Galvão’s Church in Guaratinguetá, SP, Brazil. It started from the analysis of the current situation and of a study on visitors’ profiles. The development of the marketing plan proposal used the methodology of the 7 P’s of service marketing. The studies brought some relevant results, as they have indicated a lack of restaurants, adequate signalization, restrooms and a good parking lot. The studies have also shown that the host services managers lack data about number of visitors and about the distribution of pills. These results allowed the author to elaborate some strategies and formulate the proposal here presented

Identificação de áreas de risco na região urbana do município de Guaratinguetá, SP, quanto à ocorrência de inundações e processos erosivos

The city of Guaratinguetá, SP, presents in its history, several instances of property damage and human losses, conditional on the event of flooding and mass movement of soil, resulting from the development of erosion processes. The extent and severity of these events that affect humans and their properties is the result of the illegal occupation of these areas as potential geohazard. Thus, it is of great importance to physical characterization and identification of such areas within the map of the same city as a way to minimize the effects and mitigate the consequences of these events. Thus, this graduate report presents a series of field campaigns, geotechnical laboratory testing, consultation with maps and satellite images, representative of the physical environment, and the city plan as a means conclusive for the delimitation of risk areas with potential for occurrence of erosion and / or flooding on the map representing the urban area of Guaratinguetá, SP. Also featured are the descriptions of the main characteristics of those areas identified as being at risk, along with proposals to avoid or minimize the impact of problems related to flooding and erosion processes on the local population

Viabilidade técnica e econômica na utilização de um sistema fotovoltaico para alimentação de luminárias LED na Faculdade de Engenharia do Campus de Guaratinguetá SP

Solar energy can be considered the largest source of energy available on earth and has attracted in recent decades, attention and interest for its rational use. The use of energy sources in a sustainable way is essential to the survival of future generations, due to the scarcity of natural resources and their exploitation in a disorderly way. This academic work aims to bring a possible alternative to reduce the consumption of eletrical energy, at the University of Engineering – Campus of Guaratinguetá, through the use of a photovoltaic system interconnected to the LED bulbs. For this, the necessary data for the design of the photovoltaic system componentes and their acquisition costs were obtained and three differents configurations were developed to choose the one that bests fits the studied case, considering the return time of the initial investment (payback)

Atendimento à norma NBR 12.209/2011 na implantação de uma Estação de Tratamento de Esgotos no município de Guaratinguetá (SP)

The progressive growth of the population and the increase of sewage generated has demanded of society and public policies that, besides the collection network deployment is carried out the treatment and proper disposal of treated sewage in all brazilian municipalities. The aim of this study was to monitor and evaluate the work of implementation of a Sewage Treatment Plant (STP) in Guaratinguetá city of São Paulo state, to identify the compliance with legal requirements and the NBR 12,209/2011. The construction of this ETE met all the requirements of NBR 12209/2011 and benefited a large portion of population with the sewage treatment. Based on the results of this assessment it was concluded that the construction of a STP is relatively simple, differing only on the legal requirements related to the location, area for the construction and materials used in the work. The knowledge generated in this study will assist the public policies in the implementation of STPs in municipalities that do not yet have this basic sanitation

Análise do desempenho térmico de habitações populares da microrregião de Guaratinguetá - SP

Pós-graduação em Engenharia Mecânica - FEG

Processo de produção de composto orgânico derivado de resíduos industriais com aplicação no cultivo de alface

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)