927 resultados para Função Sub-Ação


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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

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Pós-graduação em Agronomia (Horticultura) - FCA

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Foram preparados compostos carbonílicos heterobimetálicos do tipo [Fe(CO)4(HgX)2] ( X= Cl, Br, I), contendo ligação metal-metal, objetivando investigar suas estabilidades térmicas em função do halogênio coordenado aos átomos de mercúrio. A caracterização destes complexos foi feita usando-se de técnicas espectroscópicas de infravermelho e ressonância magnética nuclear, além de análise elementar. O produto final das termodecomposições foi identificado através de espectroscopia no infravermelho e difratograma de raios-X, método de pó.

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Neste trabalho são apresentadas aproximações lineares e quadráticas das equações de Zoeppritz para a obtenção dos coeficientes de reflexão e transmissão de eventos P-P e P-S em função dos ângulos de incidência e da média angular, bem como a análise de inversão linear de AVO, considerando os eventos de reflexão P-P e P-S dissociados e combinados. O uso das chamadas aproximações pseudo-quadráticas foi aplicado para obtenção de aproximações quadráticas apenas para eventos-PP, em torno dos contrastes médios das velocidades de ondas compressionais e cisalhantes e da razão Vs/Vp. Os resultados das aproximações desenvolvidas neste trabalho mostram que as aproximações quadráticas são mais precisas que as lineares, nas duas versões angulares. As comparações entre as aproximações em termos do ângulo de incidência e da média angular mostram que as aproximações quadráticas são equivalentes dentro do limite angular de [0º, 30º]. Por outro lado, as aproximações lineares em função do ângulo de incidência mostram-se mais precisas que as aproximações lineares em função da média angular. Na inversão linear, fez-se análises de sensibilidade e de ambigüidade e observou-se que, nos caso de eventos de reflexão P-P e P-S dissociados, apenas um parâmetro pode ser estimado e que a combinação destes eventos consegue estabilizar a inversão, permitindo a estimativa de dois dentre os parâmetros físicos dos meios (contrastes de impedância, de velocidade de onda P e de módulo de cisalhamento).

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O estudo do conteúdo de foraminíferos de 8 amostras de sedimentos superficiais coletados em manguezal do norte da Ilha do Cardoso, sul do Estado de São Paulo, no verão (período chuvoso) de 2001, ao longo de um transecto no sentido da Baía de Trapandé para o interior, revelou dois segmentos distintos: a) uma planície inferior lamosa, com menor tempo de exposição sub-aérea e maior diversidade específica, dominada por Ammotiumcassis, A.salsum, Arenoparrella mexicana e Trochamminainflata, com abundância expressiva de Caroniaexilis na parte mais baixa e de Miliammina fusca na parte mais alta; b) uma planície superior arenosa, com maior tempo de exposição sub-aérea e menor diversidade, dominada por M. fusca e com abundância expressiva de T. inflatana parte mais baixa. Os sedimentos investigados são colonizados por foraminíferos exclusivamente aglutinantes, representados por 21 espécies de 16 gêneros. Dados de abundância relativa, riqueza, diversidade e equitatividade das espécies ao longo do transecto são apresentados, bem como os valores de salinidade, pH, oxigênio dissolvido e temperatura, medidos a partir da água intersticial dos sedimentos no momento da coleta das amostras. São feitas comparações com um estudo anterior, similar, que focalizou amostras coletadas, nos mesmos pontos, no inverno (período seco) de 2002. Os resultados obtidos interessam às análises de sistemas estuarinos modernos e antigos, bem como a projetos envolvidos com o diagnóstico do estado de conservação de áreas litorâneas, sendo úteis ao Setor de Petróleo e Gás

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Pós-graduação em Agronomia - FEIS

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This study discusses the issue of deadlines in the purchasing process within the Federal Public Administration. Your main goal is to analyze the main factors that influenced, mainly in the implementation of sub-phases of electronic trading in BANT, in 2014, as service to the principle of celerity. The research is descriptive since they were identified and analyzed the factors that influenced in terms of purchases, through direct observation and interviews. Based on the theoretical framework, the purchasing function, four dimensions of analysis were established: "Legislation and procurement processes", "Structure and Organization of the purchasing department", "purchasing systems" and "Human Resources of the purchasing department." Analysis showed that, unlike what happens in the private sector, the public procurement sector has not reached a strategic status within organizations, which brings harmful consequences to the speed of the purchases. It was found that there is a need for greater involvement of the purchasing department staff and criers in the formulation of the organization's purchasing strategies and that these purchases elements present, about their attitudes, a hybrid profile, proactive regarding specifications of the items, but reactive in relation to the need to urgently purchase, due to the lack of a better plan, which overloads the work of the sector. The observation of these strategic aspects of the procurement function in BANT influenced the finding that the lack of staff and expertise in investments plus the lack of rigor and formality of legislation, among other factors, contributed mainly to the lack of speed of processes.

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Light varies widely in both time and space in forest formation of “Bioma Cerrado”. Cybistax antisyphilitica occurs in areas typical of this biome, such as cerrado sensu stricto, “cerradões”, and altered areas. The aim of this study was to understand the morphological and physiological responses of C. antisyphilitica to alterations in light intensity. Juvenile plants (5 month of age) were taken to a fragment of semideciduous forest in Uberlândia-MG, and were divided into three treatments: 50 were maintained under the canopy (UC) 20 were kept in small gap (SG) and 20 were maintained under in full sun (FS). The daily courses of chlorophyll a fluorescence were made at the beginning, middle and end of dry season in 2015. At the end of the experiment measurements of chlorophyll content, gas exchange and growth were made. The plants showed dynamic photoinhibition as exhibited by reductions on Fv/Fm close to midday at the end of the dry season. Regarding the effective quantum yield (ΔF/Fm'), plants under FS showed reduced values that coincided with the higher values of electron transport rates (ETR). Plants under FS showed higher values of net CO2 assimilation rates, stomatal conductance, transpiration rates, water use efficiency and chlorophyll content compared to plants under UC. The stem diameter, dry mass of leaves and stem, total dry mass and relative growth rate were higher in plants under FS than plants under UC. On the other hand, plants under UC showed superior values of height, specific leaf area and leaf area ratio. Our results indicate that C. antisyphilitica has plasticity to survive in the contrasting light environments of the semideciduous forests, but this species was able to growth better under full sun conditions.

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A month-long intensive measurement campaign was conducted in March/April 2007 at Agnes Water, a remote coastal site just south of the Great Barrier Reef on the east coast of Australia. Particle and ion size distributions were continuously measured during the campaign. Coastal nucleation events were observed in clean, marine air masses coming from the south-east on 65% of the days. The events usually began at ~10:00 local time and lasted for 1-4 hrs. They were characterised by the appearance of a nucleation mode with a peak diameter of ~10 nm. The freshly nucleated particles grew within 1-4 hrs up to sizes of 20-50 nm. The events occurred when solar intensity was high (~1000 W m-2) and RH was low (~60%). Interestingly, the events were not related to tide height. The volatile and hygroscopic properties of freshly nucleated particles (17-22.5 nm), simultaneously measured with a volatility-hygroscopicity-tandem differential mobility analyser (VH-TDMA), were used to infer chemical composition. The majority of the volume of these particles was attributed to internally mixed sulphate and organic components. After ruling out coagulation as a source of significant particle growth, we conclude that the condensation of sulphate and/or organic vapours was most likely responsible for driving particle growth during the nucleation events. We cannot make any direct conclusions regarding the chemical species that participated in the initial particle nucleation. However, we suggest that nucleation may have resulted from the photo-oxidation products of unknown sulphur or organic vapours emitted from the waters of Hervey Bay, or from the formation of DMS-derived sulphate clusters over the open ocean that were activated to observable particles by condensable vapours emitted from the nutrient rich waters around Fraser Island or Hervey Bay. Furthermore, a unique and particularly strong nucleation event was observed during northerly wind. The event began early one morning (08:00) and lasted almost the entire day resulting in the production of a large number of ~80 nm particles (average modal concentration during the event was 3200 cm-3). The Great Barrier Reef was the most likely source of precursor vapours responsible for this event.