Some parameters of distribution of hydrocarbon paraffin fraction in bottom sediments of the Kara Sea and the Yenisey estuary

During Cruise 49 of R/V Dmitry Mendeleev in the Kara Sea (August-September, 1993) chemical-bitumenological studies of bottom sediments were carried out. Hydrocarbons were analyzed by gas-liquid chromatography. It was found on the basis of distribution of n-alkanes and isoprenoids (pristan and phytan) that organic matter is mainly terrigenous consisting of higher plant remains.

Chemical composition of the soluble fraction of oxidate portions of Lakes Shebadnowan ferromanganese concretions

Shebandowan Lakes, Ontario, are the site of at least 49 shallow (2-12 m) ferromanganese concretion deposits, widely distributed throughout the 48 km of the watercourse. X-ray diffraction and Mossbauer methods have revealed the presence of goethite in some of the concretions. Chemical analyses of the acid soluble portions of 72 samples gave an average composition of 43.1% Fe and 5.65% Mn with a low content of trace elements. The Shebandowan concretions are among the richest in iron of lake concretions reported, possibly because only the acid soluble portion was analysed. Their low content of trace elements suggests rapid growth rates and a relatively young age. A positive correlation was found between Mn and K, Ca, Mg, Cu, Ni, and Co and the relationship between the last three and Mn was deemed significant. Zn was independent of association with either Mn and Fe, probably due to the presence locally of zinc sulphide deposits. Analyses of lake bottom and influent waters suggested that frequent resampling of the sites would be required throughout the year to permit meaningful interpretation of the effect of water composition of concretions. Analyses of sediment cores from 20 concretion sites indicated an upward increase in Fe and Mn and in the Mn/Fe ratio, consistent with the model of upward migration of the elements, where Mn is more mobile than Fe. This study concludes that a considerable proportion of the elements have been supplied to the Shebandowan concretions via the diagenetic process; generally a minor fraction of the elements has been abstracted directly from the superjacent water.

Grain size composition of sediment cores from the Weddell Sea, Antarctica

Sedimentary processes in the southeastern Weddell Sea are influenced by glacial-interglacial ice-shelf dynamics and the cyclonic circulation of the Weddell Gyre, which affects all water masses down to the sea floor. Significantly increased sedimentation rates occur during glacial stages, when ice sheets advance to the shelf edge and trigger gravitational sediment transport to the deep sea. Downslope transport on the Crary Fan and off Dronning Maud and Coats Land is channelized into three huge channel systems, which originate on the eastern-, the central and the western Crary Fan. They gradually turn from a northerly direction eastward until they follow a course parallel to the continental slope. All channels show strongly asymmetric cross sections with well-developed levees on their northwestern sides, forming wedge-shaped sediment bodies. They level off very gently. Levees on the southeastern sides are small, if present at all. This characteristic morphology likely results from the process of combined turbidite-contourite deposition. Strong thermohaline currents of the Weddell Gyre entrain particles from turbidity-current suspensions, which flow down the channels, and carry them westward out of the channel where they settle on a surface gently dipping away from the channel. These sediments are intercalated with overbank deposits of high-energy and high-volume turbidity currents, which preferentially flood the left of the channels (looking downchannel) as a result of Coriolis force. In the distal setting of the easternmost channel-levee complex, where thermohaline currents are directed northeastward as a result of a recirculation of water masses from the Enderby Basin, the setting and the internal structures of a wedge-shaped sediment body indicate a contourite drift rather than a channel levee. Dating of the sediments reveals that the levees in their present form started to develop with a late Miocene cooling event, which caused an expansion of the East Antarctic Ice Sheet and an invigoration of thermohaline current activity.

Investigation of sediment core PS2556 from Bellingshausen Sea, Antarctica

Die Rekonstruktion der glaziomarinen Sedimentationsprozesse am antarktischen Kontinentalrand des westlichen Bellingshausenmeeres erfolgte durch die sedimentologische Auswertung eines 962 cm langen Schwerelotkernes aus 3594 m Wassertiefe. Der Kern wurde während des Fahrtabschnittes ANT-XI/3 mit dem FS "Polarstern" vom Scheitel einer Sediment- "Drift" gezogen. An dem Sedimentkern wurde eine lithologische Beschreibung, sowie sedimentologische Untersuchungen und sedimentphysikalische Messungen durchgeführt. Anhand der Ergebnisse konnten signifikante Änderungen in der Zusammensetzung und Struktur der Sedimente erkannt, und drei Faziestypen unterschieden werden. Die Faziestypen charakterisieren jeweils glaziale oder interglaziale Zeiträume. Der größte Teil der Sedimentabfolge gehört der Laminitfazies an. Dabei handelt es sich um feinlaminierte Sedimentabschnitte, die vorwiegend aus feinkörnigen, terrigenen Komponenten zusammengesetzt sind. In die feinlaminierten Abschnitte sind vereinzelte, wenige Milimeter bis Zentimeter mächtige Siltlagen eingeschaltet. Die biogenen Anteile sind gering, Anzeichen für Bodenleben fehlen völlig. Die Manganfazies wird von authigen gebildeten Mangankonkretionen dominiert, die jeweils diskrete Lagen bilden. Dabei handelt es sich zum einen um Mikromanganknollen und -krusten und zum andern um manganhaltige Gangfüllungen. Biogene und terrigene Anteile sind in diesem Faziestyp unbedeutend. Die Biogenfazies ist von strukturlosen und stark bioturbierten Sedimenten gekennzeichnet. In diesen Sedimentabschnitten ist der hohe Anteil an Eisfracht (IRD) und die erhöhten Gehalte an Kalziumkarbonat und Opal in der Sandfraktion markant. Die stratigraphische Einordnung des Sedimentkernes erfolgte über die von Grobe & Mackensen (1992) entwickelte Lithostratigraphie, mit deren Einheiten die Faziestypen des Sedimentkernes korreliert werden konnten. Dabei ergaben sich zwei mögliche Altersmodelle und ein Basisalter von ca. 250.000 Jahren. Anhand der stratigraphischen Fixpunkte wurden Sedimentationsraten des Gesamtsedimentes und Akkumulationsraten des Kalziumkarbonates, des Biogenopals und des organisch gebundenen Kohlenstoffes berechnet. Dabei wurde gezeigt, daß lediglich das Kalziumkarbonat und der Biogenopal als Anzeiger für biologische Produktion dienen können, wobei Lösungsprozesse in der Wassersäule und im Sediment eine große Rolle spielen. Der Gehalt an organisch gebundenem Kohlenstoff ist in dem Sedimentkern nur erhaltungsbedingt zu erklären. Die Sedimentationsprozesse der einzelnen Faziestypen sind von den Eisverhältnissen, der biologischen Produktion, dem gravitativen Transport und der Umlagerung durch Meeresströmungen abhängig. Die Auswirkung der einzelnen Faktoren ist jeweils unterschiedlich ausgeprägt und wirkt sich spezifisch auf die einzelnen Parameter aus. In den Glazialen hatte ein Vorstoß des Schelfeises über die Schelfkante zur Anlieferung großer Sedimentmassen geführt, die über gravitativen Transport den Kontinentalhang hinunter transportiert wurden. Die Feinfracht wurde über parallel zum Kontinentalhang laufende Konturströme westwärts transportiert und in der Larninitfazies der Driftkörper abgelagert. Am Ende der Glaziale kam es zur Sedimentation der Manganfazies. Die geringen Sedimentationsraten am Kamm der Sedimentdrift kamen aufgrund reduzierter Intensität der Konturströme und fehlender Umlagerung von Schelfsedimenten in Folge rückschreitender Schelfeisrnassen zustande. In den Interglazialen kam es durch den aufsteigenden Meeresspiegel zum Aufschwimmen des Schelfeises. Der damit verbundene Abbau der Eisrnassen über dem Schelf, hatte eine hohe Sedimentation von IRD zur Folge. Mit fortschreitendem Interglazial kam es in Zeiten nur saisonaler Meereisbedeckung zu verstärkter biologischer Produktion und zur Sedimentation biogenen Materials.

Letters of "63" : written in York, Pennsylvania, during the occupation of that town by the Confederate troops in the summer of 1863.

Contains letters written by Cassandra Morris Small Blair.

Age determinations and stable isotope records of four sediment profiles off Nova Scotia

Continental margin sediments off Nova Scotia accumulate at high rates (up to 360 cm/kyr) and contain a history of millennial-scale environmental changes which are dominated by the proximity of the Laurentide ice sheet during the latest Quaternary. Using stable isotope ratios of oxygen, accelerator mass spectrometer radiocarbon dating, micropaleontology, and sedimentology, we document these changes in six piston cores ranging in water depth from ab. 450 to ab. 4300 m. We find that maximum d18O in N. pachyderma occurred about 15 ka and preceded the maximum abundance of this species in these cores by ab. 1000 years. Between 13 and 14 ka we find a second peak in abundance of N. pachyderma, minimum d18O, and two pulses of ice rafting. The sediment lithology supports terrestrial studies which indicate that there was a general withdrawal of ice beyond the upper Paleozoic and Mesozoic red beds by 14 ka in southeastern Canada, so the ice rafting events between 13 and 14 ka probably reflect ice stream activity in the St. Lawrence valley. The Younger Dryas event is recognized as a peak in abundance of N. pachyderma and ice rafting (dated as ab. 11.3 ka), but meltwater discharge to the Gulf of St. Lawrence was either too small or occurred over too long a time to leave a distinct d18O minimum off Nova Scotia. At 7.1 ka, in the middle of Holocene warming, we find a third peak in abundance of N. pachyderma and another d18O minimum but no ice rafting. We interpret these data as evidence of a late-occurring meltwater event which, if correct, could have originated in the Great Lakes, in the Labrador-Ungava region, or in both. The final millennial-scale phenomenon off Nova Scotia is the onset of "Neoglaciation," marked by increased ice rafting and increased % N. pachyderma beginning about 5 kyr ago.

Documentation and sedimentology of core PS1021-1 from the Antarctic continental margin off Kap Norvegia

Sedimentological analyses concerning ice rafted debris, grain size distribution, biogenous components, and clay mineral composition of four sediment cores from the Antarctic continental margin off Kapp Norvegia reveal a cyclical pattern of three different sediment facies. These are classified into warm and cold types representing warm and cold climatic periods and a short transition period from cold to warm events. The sedimentological parameters reflect the variations within the cryosphere and the hydrosphere, which are directly influenced by the climatic fluctuations. The unusually high content of carbonaceous planktonic and benthonic foraminifera in these polar sediments, as well as the interfingering of terrigeneous and biogeneous-rich sediments with increasing distance from the continent, might reflect the influence of the Weddell Sea Polynya and the oscillations of polynya, pack-ice and ice shelf extent during the late Pleistocene.

Sedimentology of the northwestern Weddel Sea continental shelf and slope

Geologie cores on two profiles oriented normaly to the continental shelf and slope, have been investigated to reconstruct the Quaternary sedimentary history of the southeast continental border of South Orkney (NW Weddell Sea). The sediments were described macroscopically and their fabric investigated by use of X-radiographs. Laboratory work comprised detailed grain-size analysis, determination of the watercontent, carbonate, organic carbon and sand fraction.composition. Stable oxygen and carbon isotopes have been measured On planktonic foraminifera. Palaeomagnetism, analysis of 230Th-content and detailed comparison of the lithlogic Parameters with the oxygen isotope stages (Martinson curve) were used for stratigraphic classification of the sediments. The sediment cores from the continental slope comprise a maximum age of 300,000 years B. P.. Bottom currents, ice rafting and biogenic input are the main sources of sediment. Based on lithologic parameters a distinction between glacial and interglacial facies is possible. Silty clays without microfossils and few bioturbation characterise the sediments of the glacial facies. Only small amounts of icerafted debris can be recognized. This type of sediment was accumulated during times of lower sea-level and drastically reduced rate of bottom water production. Based on grain-size distribution, bottom current velocities of 0.01 cmls were calculated. Thick sea-ice coverage reduced biogenic production in the surface water, and as consequence benthic communities were depleted. Because of the reduced benthic life, sediments are only slithly bioturbated. At the beginning of the interglacial Stage, the sea-level rised rapidly, and calving rate of icebergs, combined with input of ice-rafted material, increased considerably. Sediments of this transition facies are silty cliiys with a high proportion of coarse ice-rafted debris, but without microfossils. With the onset of bottom water production in connection with shelf ice water, sediments of interglacial facies were formed. They consist of silty clays to clayey silts with considerable content of sand and gravel. Sediments are strongly bioturbated. Based On the sediment caracteristics, current velocities of the bottom water were calculated to be of 0.96 cmls for interglacials. At the southern slope of a NW/SE-striking ridge, bottom water current is channelized, resulting in a drastic increase of current velocities. Current velocities up to 7.5 cm/s lead to formation of residual sediments. While the continental slope has predominantly fine sediments, the South Orkney shelf are mainly sandy silts and silty sands with a high proportion of gravel. These sediments were formed dominantly by ice-rafting during Brunhes- and Matuyama-Epoch. Currents removed the fine fraction of the sediments. Based on microfossil contents it was not possible to differentiate sediments from glacial to interglacial. In the upper Parts of the cores graded sequences truncated by erosion were observed. These sequences were formed during Brunhes-Epoch by strong currents with velocities decreasing periodically from about 7.5 cm/s to about 1 cm/s. Sediments with a high proportion of siliceous microfossils but barren of foraminifera compose the lower part of the shelf cores. These sediments have formed during the warmer Matuyama-Epoch.