Formation of an unusual copper(II) complex from the degradation of a novel tricopper(II) carbohydrazone complex

An unusual copper(II) complex [Cu(L1a)2Cl2] CH3OH H2O H3O+Cl (1a) was isolated from a solution of a novel tricopper(II) complex [Cu3(HL1)Cl2]Cl3 2H2O (1) in methanol, where L1a is 3-(2-pyridyl)triazolo [1,5-a]-pyridine, and characterized with single crystal X-ray diffraction study. The tricopper(II) complex of potential ligand 1,5-bis(di-2-pyridyl ketone) carbohydrazone (H2L1) was synthesized and physicochemically characterized, while the formation of the complex 1a was followed by time-dependant monitoring of the UV–visible spectra, which reveals degradation of ligand backbone as intensity loss of bands corresponding to O?Cu(II) charge transfer

Analysis of the electronic structure, hyperfine structure, and volume isotope shifts in the low lying states of BA I and BA II

Relativistic multi-configuration Dirac Fock (MCDF) wavefunctions coupled to good angular momentum J have been calculated for low lying states of Ba I and Ba II. These wavefunctions are compared with semiempirical ones derived from experimental atomic energy levels. It is found that significantly better agreement is obtained when close configurations are included in the MCDF wavefunctions. Calculations of the electronic part of the field isotope shift lead to very good agreement with electronic factors derived from experimental data. Furthermore, the slopes of the lines in a King plot analysis of many of the optical lines are predicted accurately by these calculations. However, the MCDF wavefunctions seem not to be of sufficient accuracy to give agreement with the experimental magnetic dipole and electric quadrupole hyperfine structure constants.

Predicted properties of the superheavy elements, II. Element 111, Eka-Gold

The chemical properties of element 111, eka-gold, are predicted through the use of the periodic table, relativistic Hartee-Fock-Slater calculations, and various qualitative theories which have established their usefulness in understanding and correlating properties of molecules. The results indicate that element 111 will be like Au(III) in its chemistry with little or no tendency to show stability in the I or II states. There is a possibility that the 111 - ion, analogous to the auride ion, will be stable.

State dependent volume isotope shift analysis of the low lying states of Ba I and Ba II

Relativistic multi-configuration Dirac-Fock wavefunctions, coupled to good angular momentum J, have been calculated for low lying states of Ba I and Ba II. The resulting electronic factors show good agreement with data derived from recent high-resolution laser spectroscopy experiments and results from a comparison of muonic and optical data.

Psychometric properties of the School Fears Survey Scale for preadolescents (SFSS-II)

Resumen tomado de la publicaci??n

The end of old Europe : the causes of the First World War, 1914-1918.

Dividido en tres partes, se repasan en ellas las características de las cinco grandes potencias europeas del momento: los imperios británico, alemán, ruso, austro-húngaro y la república de Francia, así como las figuras de sus gobernantes; en segundo lugar, trata de la expansión por el continente de un frágil sistema de alianzas, y por último, del polvorín político de los Balcanes. Incluye fragmentos de fuentes históricas originales, así como material de aprendizaje activo: ejercicios, preguntas y pruebas.

Edexcel GCSE history A : the making of the modern world. Unit 2A : Germany 1918-39. Student book.

Es una de las cuatro unidades del curso de preparación para los exámenes del General Certificate Secondary Education (GCSE). Estos temas explican los acontecimientos históricos sucedidos en los últimos cien años y ayudan a entender los problemas del mundo actual. Esta unidad se centra en el estudio de la República de Weimar, el asombroso ascenso de Hitler al poder y la creación de un estado policial en la Alemania nazi. Una parte del libro se dedica al repaso y la preparación del examen.

Measuring experiential avoidance and psychological inflexibility : The Spanish version of the Acceptance and Action Questionnaire - II

Resumen tomado de la publicaci??n