I. Nuclear spin-internal-rotation-coupling. II. Fluorine spin-rotation interaction and magnetic shielding in fluorobenzene

Part I.

The interaction of a nuclear magnetic moment situated on an internal top with the magnetic fields produced by the internal as well as overall molecular rotation has been derived following the method of Van Vleck for the spin-rotation interaction in rigid molecules. It is shown that the Hamiltonian for this problem may be written

H_SR = Ῑ · M · Ĵ + Ῑ · M” · Ĵ”

Where the first term is the ordinary spin-rotation interaction and the second term arises from the spin-internal-rotation coupling.

The F¹⁹ nuclear spin-lattice relaxation time (T₁) of benzotrifluoride and several chemically substituted benzotrifluorides, have been measured both neat and in solution, at room temperature by pulsed nuclear magnetic resonance. From these experimental results it is concluded that in benzotrifluoride the internal rotation is crucial to the spin relaxation of the fluorines and that the dominant relaxation mechanism is the fluctuating spin-internal-rotation interaction.

Part II.

The radiofrequency spectrum corresponding to the reorientation of the F¹⁹ nuclear moment in flurobenzene has been studied by the molecular beam magnetic resonance method. A molecular beam apparatus with an electron bombardment detector was used in the experiments. The F¹⁹ resonance is a composite spectrum with contributions from many rotational states and is not resolved. A detailed analysis of the resonance line shape and width by the method of moments led to the following diagonal components of the fluorine spin-rotational tensor in the principal inertial axis system of the molecule:

F/Caa = -1.0 ± 0.5 kHz

F/Cbb = -2.7 ± 0.2 kHz

F/Ccc = -1.9 ± 0.1 kHz

From these interaction constants, the paramagnetic contribution to the F¹⁹ nuclear shielding in C₆H₅F was determined to be -284 ± ppm. It was further concluded that the F¹⁹ nucleus in this molecule is more shielded when the applied magnetic field is directed along the C-F bond axis. The anisotropy of the magnetic shielding tensor, σ_” - σ_⊥, is +160 ± 30 ppm.

Investigation of effective internal field in congruent lithium niobate crystal by digital holographic interferometry

The phase contrast across the crystal thickness induced by the internal field is measured by the digital holographic interferometry just after the congruent lithium niobate crystal is partially poled. The direction of applied external field is antiparallel to that of internal field, and the measured phase contrast varies linearly with the applied external field. A new internal field is obtained by this method and named effective internal field. The distinct discrepancy between effective and equivalent internal fields is observed. The authors attribute this effect to the new macroscopic representation of elastic dipole components of defect complex in the crystal. (c) 2007 American Institute of Physics.

Relativistic quark models and the current algebra

In this thesis we are concerned with finding representations of the algebra of SU(3) vector and axial-vector charge densities at infinite momentum (the "current algebra") to describe the mesons, idealizing the real continua of multiparticle states as a series of discrete resonances of zero width. Such representations would describe the masses and quantum numbers of the mesons, the shapes of their Regge trajectories, their electromagnetic and weak form factors, and (approximately, through the PCAC hypothesis) pion emission or absorption amplitudes.

We assume that the mesons have internal degrees of freedom equivalent to being made of two quarks (one an antiquark) and look for models in which the mass is SU(3)-independent and the current is a sum of contributions from the individual quarks. Requiring that the current algebra, as well as conditions of relativistic invariance, be satisfied turns out to be very restrictive, and, in fact, no model has been found which satisfies all requirements and gives a reasonable mass spectrum. We show that using more general mass and current operators but keeping the same internal degrees of freedom will not make the problem any more solvable. In particular, in order for any two-quark solution to exist it must be possible to solve the "factorized SU(2) problem," in which the currents are isospin currents and are carried by only one of the component quarks (as in the K meson and its excited states).

In the free-quark model the currents at infinite momentum are found using a manifestly covariant formalism and are shown to satisfy the current algebra, but the mass spectrum is unrealistic. We then consider a pair of quarks bound by a potential, finding the current as a power series in 1/m where m is the quark mass. Here it is found impossible to satisfy the algebra and relativistic invariance with the type of potential tried, because the current contributions from the two quarks do not commute with each other to order 1/m³. However, it may be possible to solve the factorized SU(2) problem with this model.

The factorized problem can be solved exactly in the case where all mesons have the same mass, using a covariant formulation in terms of an internal Lorentz group. For a more realistic, nondegenerate mass there is difficulty in covariantly solving even the factorized problem; one model is described which almost works but appears to require particles of spacelike 4-momentum, which seem unphysical.

Although the search for a completely satisfactory model has been unsuccessful, the techniques used here might eventually reveal a working model. There is also a possibility of satisfying a weaker form of the current algebra with existing models.

Super-resolution with a nonlinear thin film: Beam reshaping via internal multi-interference

In laser applications, the size of the focus spot can be reduced beyond the diffraction limit with a thin film of strong nonlinear optical Kerr effect. We present a concise theoretical simulation of the device. The origin of the super-resolution is found to be mainly from the reshaping effect due to the strongly nonlinear refraction mediated multi-interference inside the thin film. In addition, both diffraction and self-focusing effects have been explored and found negligible for highly refractive and ultrathin films in comparison with the reshaping effect. Finally, the theoretic model has been verified in experiments with single Ge2Sb2Te5 film and SiN/Si/SiN/Ge2Sb2Te2 multilayer structures. (c) 2006 American Institute of Physics.

Obasan, by Joy Kogawa, and Alias Grace, by Margaret Atwood: fictional representations of Canadian identity and History

Esta dissertação investiga de que maneiras a representação do sujeito canadense pode ser encontrada em dois romances representativos da literatura canadense contemporânea: Obasan, de Joy Kogawa, e Alias Grace, de Margaret Atwood. Esta investigação também demonstra que a busca pela definição da identidade canadense tem sido tema constante e relevante da cultura deste país. A indefinição quanto ao que significa ser canadense também tem permeado a literatura canadense ao longo dos séculos, notadamente desde o século XIX. A fim de observar a representação literária da busca pela definição da identidade canadense, esta investigação aborda os conceitos relativos à representação de grupos subalternos tradicionalmente silenciados. A análise comparativa dos romances citados contempla a relação entre memória e trauma autobiográficos, assim como as semelhanças narrativas entre ficção e história. Esta investigação também verifica de que maneiras a literatura pós-moderna emprega documentação oficial, relatos históricos e dados (auto) biográficos a serviço da reescrita da história através da metaficção historiográfica

Antes só do que mal (ou bem) acompanhado: um estudo sobre a representação social da mulher solteira no mundo feminino

Esse trabalho teve origem numa monografia de conclusão de curso de graduação em psicologia, e parte da constatação de que atualmente, nos grandes centros urbanos, o grupo de mulheres financeiramente independentes sem um companheiro é cada vez mais numeroso, tornando-se muito presente no nosso cotidiano e na mídia. A pesquisa teve como objetivo descrever, analisar e discutir a representação social da mulher solteira construída por 210 mulheres, com idades entre 20 e 49 anos, habitantes da cidade do Rio de Janeiro. A coleta de dados foi realizada pela aplicação individual de um questionário às participantes da pesquisa. O questionário consistiu na solicitação de tarefas de evocação, em seu contexto normal e de substituição, além de perguntas fechadas e abertas, e da obtenção de dados de caracterização sociodemográfica. Os dados coletados por meio da evocação livre foram processados com auxílio do softwareEvoc e analisados de acordo com a abordagem estrutural das representações sociais, segundo a qual os conteúdos cognitivos de uma representação se organizam em dois sistemas internos: um sistema central, também chamado de núcleo central, e um sistema periférico. A análise do questionário envolveu tratamentos estatísticos descritivos das respostas às perguntas fechadas e abertas, tendo sido estas últimas submetidas a um processo prévio de categorização temática. A representação da mulher com 30 anos ou mais, solteira e sem filhos, construída pelas mulheres em geral, é fortemente marcada por elementos contraditórios, mas sem deixar de caracterizar a mulher contemporânea. O conteúdo representacional evidencia uma dimensão imagética muito influenciada pela mídia, e expressa o sentimento de autonomia, refletindo o atual momento da mulher. Esse perfil de mulher, apesar de corresponder a uma mulher que rompe com o seu papel tradicional na sociedade e que tem um poder de escolha, ainda incorpora a imagem de encalhada, o que pode indicar a persistência de um grande conservadorismo por parte das próprias mulheres.