持久性有毒物污染底泥修复技术进展

评述了底泥中持久性有毒污染物的危害。在分析持久性有毒污染物污染底泥修复技术现状及面临问题的基础上 ,指出浅水湖泊持久性有毒污染物污染底泥修复的发展方向是植物 -微生物联合修复 ,水库、深水湖泊等持久性有毒物污染底泥修复的发展趋势为物理化学 -生物协同修复 ,修复目标是在环保疏浚、生态清淤的基础上 ,实现持久性有毒污染物污染底泥的无害化和资源化处置

Surface pigments,algal biomass profiles,and potential production of the euphotic layer:Relationships reinvestigated in view of remote-sensing applications

Maps of surface chlorophyllous pigment (Chl a + Pheo a) are currently produced from ocean color sensors. Transforming such maps into maps of primary production can be reliably done only by using light-production models in conjuction with additional information about the column-integrated pigment content and its vertical distribution. As a preliminary effort in this direction. $\ticksim 4,000$ vertical profiles pigment (Chl a + Pheo a) determined only in oceanic Case 1 waters have been statistically analyzed. They were scaled according to dimensionless depths (actual depth divided by the depth of the euphotic layer, $Z_e$) and expressed as dimensionless concentrations (actual concentration divided by the mean concentration within the euphotic layer). The depth $Z_e$ generally unknown, was computed with a previously develop bio-optical model. Highly sifnificant relationships were found allowing $\langle C \rangle_tot$, the pigment content of the euphotic layer, to be inferred from the surface concentration, $\bar C_pd$, observed within the layer of one penetration depth. According to their $\bar C_pd$ values (ranging from $0.01 to > 10 mg m^-3$), we categorized the profiles into seven trophic situations and computed a mean vertical profile for each. Between a quasi-uniform profile in eutrophic waters and a profile with a strong deep maximum in oligotrophic waters, the shape evolves rather regularly. The wellmixed cold waters, essentially in the Antarctic zone, have been separately examined. On average, their profiles are featureless, without deep maxima, whatever their trophic state. Averaged values their profiles are featureless, without deep maxima, whatever their trophic state. Averaged values their profiles are featureless, without deep maxima, whatever their trophic state. Averaged values of $ρ$, the ratio of Chl a tp (Chl a + Pheo a), have also been obtained for each trophic category. The energy stored by photosynthesizing algae, once normalized with respect to the integrated chlorophyll biomass $\langle C \rangle _tot $ is proportional to the available photosythetic energy at the surface via a parameter $ψ∗$ which is the cross-section for photosynthesis per unit of areal chlorophyll. By tanking advantage of the relative stability of $ψ∗.$ we can compute primary production from ocean color data acquired from space. For such a computation, inputs are the irradiance field at the ocean surface, the "surface" pigment from which $\langle C \rangle _tot$ can be derived, the mean $ρ value pertinent to the trophic situation as depicted by the $\bar C_pd or $\langle C \rangle _tot$ values, and the cross-section $ψ∗$. Instead of a contant $ψ∗.$ value, the mean profiles can be used; they allow the climatological field of the $ψ∗.$ parameter to be adjusted through the parallel use of a spectral light-production model.

Quantitative electrochemiluminescence detection of proteins: Avidin-based sensor and tris(2,2 '-bipyridine) ruthenium(II) label

Quantitative electrochemilumineseence (ECL) detection of a model protein, bovine serum albumin (BSA) was achieved via biotin-avidin interaction using an avidin-based sensor and a well-developed ECL system of tris(2,2'-bipyridine) ruthenium(II) derivative as label and tri-n-propylamine (TPA) as coreactant. To detect the protein, avidin was linked to the glassy carbon electrode through passive adsorptions and covalent interaction with carboxylate-terminated carbon nanotubes that was used as binder to immobilize avidin onto the electrode. Then, biotinylated BSA tagged with tris(2,2'-bipyridine) ruthenium(II) label was attached to the prepared avidin surface.

Colorimetric recognition of the coralyne-poly(dA) interaction using unmodified gold nanoparticle probes, and further detection of coralyne based upon this recognition system

Among the functional nucleic acids studied, adenine-rich nucleic acids have attracted attention due to their critical roles in many biological processes and self-assembly-based nanomaterials, especially deoxyribonucleic acids (abbreviated as poly(dA)). Therefore the ligands binding to poly(dA) might serve as potential therapeutic agents. Coralyne, a kind of planar alkaloid, has been firstly found that it could bind strongly to poly(dA). This work herein reports an approach for visual sensing of the coralyne-poly(dA) interaction. This method was based on the coralyne inducing poly(dA) into the homo-adenine DNA duplex and the difference in electrostatic affinity between single-stranded DNA and double-stranded DNA with gold nanoparticles (GNPs). Furthermore, we applied the recognition process of the interaction between coralyne and poly(dA) into specific coralyne detection with the assistance of certain software (such as Photoshop). A linear response from 0 to 728 nM was obtained for coralyne, and a detection limit of 91 nM was achieved.

硫醇自组装膜对金电极上吡咯电化学聚合的影响

用电化学聚合法在多种烷基硫醇自组装膜修饰金电极上制备了聚吡咯 .通过计时安培法、循环伏安法和交流阻抗技术研究了自组装膜的烷基链长和端基功能团对吡咯聚合过程和性质的影响 .当自组装膜较完美时 ,聚吡咯沉积在自组装膜表面 ;而当自组装膜有一定缺陷时 ,吡咯在针孔处成核 ,然后继续生长并完全覆盖在自组装膜表面 .研究结果表明 ,烷基硫醇的链越短 ,吡咯聚合越容易 ;疏水的烷基硫醇自组装膜有利于聚吡咯在电极表面的生长.

BLENDS OF POLY[3,3-BIS(CHLOROMETHYL)OXETANE] WITH POLY(VINYL ACETATE) .1. THERMAL AND MECHANICAL-PROPERTIES

Blends of poly[3,3-bis(chloromethyl)oxetane] (Penton) with poly(vinyl acetate) were prepared. Compatibility, morphology, thermal behavior, and mechanical properties of blends with various compositions were studied using differential scanning calorimetry (DSC), dynamic mechanical measurements (DMA), tensile tests, and scanning electron microscopy (SEM). DMA study showed that the blends have two glass transition temperatures (T(g)). The T(g) of the PVAc rich phase shifts significantly to lower temperatures with increasing Penton content, suggesting that a considerable amount of Penton dissolves in the PVAc rich phase, but that the Penton rich phase contains little PVAc. The Penton/PVAc blends are partially compatible. DSC results suggest that PVAc can act as a beta-nucleator for Penton in the blend. Marked negative deviations from simple additivity were observed for the tensile strength at break over the entire composition range. The Young's modulus curve appeared to be S-shaped, implying that the blends are heterogeneous and have a two-phase structure. This was confirmed by SEM observations.

Bi-Sr-Ca-Cu-O体系中可能存在一个新的高T_c超导相

最近,Pb能加强BiSrCaCuO超导体中高T_c相(即2223相,其c(?)37,T_c(?)110K)的出现和掺入sb形成BiPbSbSrCaCuO的T_c可以达到132 K已见报道,我们希望通过其它元素的掺杂取代也出现类似的结果。我们做了大量掺Sb、Ba、In的实验,通过改变

工业机器人的小脑模型控制

本文为动力学控制工业机器人提出了一种综合学习算法,这种学习算法可将以前所学的信息用于新的控制输入.这种控制方法不需要事先知道机器人动力学,它易于应用于特殊的控制问题或修改以适应实际系统中的变化,控制方法在时间上是有效的,且很适合于定点实现.学习控制算法的有效性通过4自由度的直接驱动机器人前两个关节在重复运动中的计算机仿真实验得到了验证.

月表有效太阳辐照度实时模型

月表太阳辐射是深入研究月表温度分布的关键问题之一.本文根据月表有效太阳辐照度与太阳常数、太阳辐射入射角以及日月距离之间的关系,建立月表有效太阳辐照度的实时模型.该模型在1950-2050年的100年内的理论误差百分比小于0.28%,相对前人提出的模型在精度上有了很大程度的提高,能较为真实地反映月表有效太阳辐照度随时间的变化规律.计算结果表明2007年月表太阳辐照度的年变化范围在1321.5-1416.6 W·m^-2之间,平均为1368.0 W·m^-2.通过对月表太阳辐射入射角计算结果的分析,证实了月球的两极可能存在极昼极夜.

贵州红枫湖水体溶解有机质的剖面特征和季节变化

溶解有机氮(dissolved organic nitrogen , DON) 与溶解有机碳(dissolved organic carbon , DOC) 相结合在湖泊水体溶解有机质(dissolved organic matter , DOM) 的研究中少有报道. 本研究对贵州喀斯特地区高原性湖泊-红枫湖水体DOC 和DON 的含量进行了近2a 的测定,研究了DOM 的剖面特征和季节变化,并探讨了DOM 垂向分布和季节变化的影响因素. 结果表明,红枫湖DOC 的浓度范围为1160～3108 mg·L - 1 ,DON 的浓度范围为0110～0137 mg·L - 1 . 在湖水混合期表层和底层的DOC和DON 的浓度基本一致,在湖水分层期DOC 和DON 浓度表现出从表层往底层减小的趋势. 表层水体(0～2m 或3m) DOC 的浓度在春末夏初或夏季达到最大,DON 的浓度在春末夏初稍高于其它月份. 结合叶绿素和降雨的数据分析认为,藻类活动和陆源输入直接导致了表层水体DOM 的季节变化模式. DOM 的C/ N 在一般情况下向下增大,但在夏季南湖的垂向水柱上,DOC 和DON 的浓度在12m 以下增大,C/ N 从12m 的1811 下降为14m 的1419 ,并向下持续减小,这很有可能是颗粒态有机质发生降解释放出C/ N 较低的DOM ,成为水体内DOM 的一个内源.