Enhanced photocatalytic activity of TiO2 nano-structured thin film with a silver hierarchical configuration

TiO2 sol-gels with various Ag/TiO2 molar ratios from 0 to 0.9% were used to fabricate silver-modified nano-structured TiO2 thin films using a layer-by-layer dip-coating (LLDC) technique. This technique allows obtaining TiO2 nano-structured thin films with a silver hierarchical configuration. The coating of pure TiO2 sol-gel and Ag-modified sol-gel was marked as T and A, respectively. According to the coating order and the nature of the TiO2 sol-gel, four types of the TiO2 thin films were constructed, and marked as AT (bottom layer was Ag modified, surface layer was pure TiO,), TA (bottom layer was pure TiO,, surface layer was Ag modified), TT (pure TiO, thin film) and AA (TiO, thin film was uniformly Ag modified). These thin films were characterized by means of linear sweep voltammetry (LSV), X-ray diffraction (XRD), scanning electron microscopy (SEM), electrochemical impedance spectroscopy and transient photocurrent (I-ph). LSV confirmed the existence of Ago state in the TiO, thin film. SEM and XRD experiments indicated that the sizes of the TiO,, nanoparticles of the resulting films were in the order of TT > AT > TA > AA, suggesting the gradient Ag distribution in the films. The SEM and XRD results also confirmed that Ag had an inhibition effect on the size growth of anatase nanoparticles. Photocatalytic activities of the resulting thin films were also evaluated in the photocatalytic degradation process of methyl orange. The preliminary results demonstrated the sequence of the photocatalytic activity of the resulting films was AT > TA > AA > TT. This suggested that the silver hierarchical configuration can be used to improve the photocatalytic activity of TiO2 thin film.

Compact and efficient triple-pass optical parametric chirped pulse amplification

Compact and efficient triple-pass optical parametric chirped pulse amplification in a single crystal has been demonstrated. The signal was triple-pass amplified in a single nonlinear crystal by a nanosecond pump pulse. The first-pass optical parametric amplification is completely phase matched in the plane of the maximum effective nonlinearity, and the other two passes work symmetrically near to the first-pass optical parametric amplification plane. This architecture efficiently increases the overall gain, overcomes the optical parametric fluorescence, and clearly simplifies the amplification scheme.

Dynamics of Cavity Polaritons in a GaAs Quantum-well Semiconductor Microcavity

To provide the dynamics of cavity polariton in semiconductor microcavity containing GaAs quantum-well, the dispersions of the three cavity polaritons have been given by the model of three coupled oscillators, meanwhile the linewidths, group velocities and the mass of the three cavity polaritons have been demonstrated. The results indicated that because of the weight occupied by the photon, heavy hole exciton and light hole extiton in the three cavity ploariton the cavity polaritons exhibited different dynamic behaviors.

Tunable and switchable multiwavelength fiber lasers with broadband range based on nonlinear polarization rotation technique

Switchable multiwavelength fiber laser outputs with a wide tuning range are experimentally observed in an ultralong cavity. Because of the long spooled single-mode fiber and filter effect of the cavity, multiwavelength lasers with the spacing of similar to 14.5 nm are obtained. The proposed fiber laser has the capacity of simultaneously emitting the three wavelengths. By means of adjusting the polarization controllers, the arbitrary single- and dual-wavelength operations are achieved in our laser. (C) 2010 Society of Photo-Optical Instrumentation Engineers. [DOI: 10.1117/1.3485754]

二维无关联振子系统的量子化及能谱中长程关联的理论分析

量子经典对应是人们一直关心的基本问题．早期的WKB量子论及其推广EBK理论分别给出了一维及多维可积系统周期轨道的作用量量子化条件，但是，这些理论都没有明确的给出周期轨道与量子能级之间的对应关系．另一方面，近年来，人们在数值计算中发现量子能谱中存在着与周期轨道有紧密联系的长程关联，但是目前对长程关联的研究大多局限于数值计算，其背后的动力学原因有待进一步的探讨。应用二维无关联振子系统具有的标度不变性，对量子态密度进行Fourier变换，得到二维无关联振子系统的回归函数．另一方面，在有理环面上积分Hamiltonian运动方程，数值计算给出二维无关联四次振子系统的半经典回归谱。对二维无关联四次振子系统的量子回归谱和经典回归谱进行比较，量子和经典回归谱中的峰(显示了能级之间存在着长程关联)的位置大致一定验证了Berry-Tabor求迹公式的有效性。从可积系统的Be：rry-Tabor公式出发，导出了二维可积系统周期轨道作用量量子化条件，考虑有理环面上周期轨道必须满足的周期性条件，找到了量子能级与经典周期轨道之间的对应关系．这一对应关系表明，二维无关联振子系统的一组能级与一组周期轨道之间存在着一一对应关系。这组能级对应的周期轨道具有相同的拓扑，但每条周期轨道对应的系统能量等于它所对应的量子能级。进一步的，我们用二维无关联振子系统的量子经典对应关系去分析量子能谱中的长程关联。分析表明，当二维无关联振子系统回归函数中的作用量取某一系统能量下某一周期轨道的作用量的值时，那些与这一周期轨道拓扑相同的周期轨道对应的量子能级对回归函数的贡献相干。这些具有相同拓扑的周期轨道对应的量子能级间存在着长程关联。

ECR离子源发射度探测器的研制

成功研制一套适合于ECR离子源引出束流发射度测量的探测器ESS（Electric-SweeP Scanner）。该探测器主要由测量探头、机械驱动装置、计算机控制及数据获取系统组成。ESS探测器所采用的测量方法是双狭缝加电扫描法，具有速度快、精度高，能够比较直观的反映束流的发射度相图、相空间密度分布等特点，是目前ECR离子源引出束流发射度测量的有效手段。本论文对发射度探测器ESS的原理、结构及物理和技术设计作了较详细的描述，并给出了相应的设计图纸及数值模拟结果。最后，利用Ess探测器对LECR3（Lanzhou No.3）离子源引出的04＋离子束的发射度作了初步测量。当04＋引出束流为343μA日寸，初步测量所得水平方向的发射度为227mm·mrad（约90％束流），并给出了相应的束流发射度相图和束流相空间密度分布。

Application of static and dynamic enclosures for determining dimethyl sulfide and carbonyl sulfide exchange in Sphagnum peatlands: Implications for the magnitude and direction of flux

A static enclosure method was applied to determine the exchange of dimethyl sulfide (DMS) and carbonyl sulfide (OCS) between the surface of Sphagnum peatlands and the atmosphere. Measurements were performed concurrently with dynamic (flow through) enclosure measurements with sulfur-free air used as sweep gas. This latter technique has been used to acquire the majority of available data on the exchange of S gases between the atmosphere and the continental surfaces and has been criticized because it is thought to overestimate the true flux of gases by disrupting natural S gas gradients. DMS emission rates determined by both methods were not statistically different between 4 and >400 nmol m−2 h−1, indicating that previous data on emissions of at least DMS are probably valid. However, the increase in DMS in static enclosures was not linear, indicating the potential for a negative feedback of enclosure DMS concentrations on efflux. The dynamic enclosure method measured positive OCS flux rates (emission) at all sites, while data using static enclosures indicated that OCS was consumed from the atmosphere at these same sites at rates of 3.7 to 55 nmol m−2 h−1. Measurements using both enclosure techniques at a site devoid of vegetation showed that peat was a source of both DMS and OCS. However, the rate of OCS efflux from decomposing peat was more than counterbalanced by OCS consumption by vegetation, including Sphagnum mosses, and net OCS uptake occurred at all sites. We propose that all wetlands are net sinks for OCS.

Simultaneous electrochemical determination of uric acid, dopamine, and ascorbic acid at single-walled carbon nanohorn modified glassy carbon electrode

Single-walled carbon nanohorn modified glassy carbon electrode (SWCNH-modified GCE) was first employed for the simultaneous determination of uric acid (UA), dopamine (DA), and ascorbic acid (AA). The SWCNH-modified GCE displayed excellent electrochemical catalytic activities. The oxidation overpotentials of UA, DA, and AA decrease significantly and their oxidation peak currents increase dramatically at SWCNH-modified GCE. Linear sweep voltammetry (LSV) was used for the simultaneous determination of UA, DA, and AA in their ternary mixture. The peak separations between UA and DA, and DA and AA are large up to 152 mV and 221 mV, respectively.

Single-walled carbon nanohorn as new solid-phase extraction adsorbent for determination of 4-nitrophenol in water sample

Single-walled carbon nanohorn (SWCNH) was developed as new adsorbent for solid-phase extraction using 4-nitrophenol as representative. The unique exoteric structures and high surface area of SWCNH allow extracting a large amount of 4-nitrophenol over a short time. Highly sensitive determination of 4-nitrophenol was achieved by linear sweep voltammetry after only 120 s extraction. The calibration plot for 4-nitrophenol determination is linear in the range of 5.0 x 10(-8) M-1.0 x 10(-5) M under optimum conditions. The detection limit is 1.1 x 10(-8) M. The proposed method was successfully employed to determine 4-nitrophenol in lake water samples, and the recoveries of the spiked 4-nitrophenol were excellent (92-106%).

Realization of negative differential resistance and switching devices based on copper phthalocyanine by the control of evaporation rate

We have observed, respectively, a negative differential resistance (NDR) and switching conduction in current-voltage (I-V) characteristics of organic diodes based on copper phthalocyanine (CuPc) film sandwiched between indium-tin-oxide (ITO) and aluminum (Al) by controlling the evaporation rate. The NDR effect is repeatable which can be well, controlled by sweep rate and start voltage, and the switching exhibits write-once-read-many-times (WORM) memory characteristics. The traps in the organic layer and interfacial dipole have been used to explain the NDR effect and switching conduction. This opens up potential applications for CuPc organic semiconductor in low power memory and logic circuits.

Application of Ru(bpy)(3)(2+) in control and formation of gold surface nanostructure through oxidation-reduction cycling

It was studied that the nanostructure formed on a gold surface via a simple oxidation-reduction cycles (ORC) in 0.1 M KCl containing Ru(bpy)(3)(2+) with different concentrations. Atomic force microscopy (AFM) and energy-dispersed spectroscopy (EDS) were used to characterize the nanostructure formed on the gold surface. Sweep-step voltammetry and corresponding electroluminescence (ECL) response, in situ electrochemical quartz crystal microbalance (EQCM) measurement were used to monitor the ORC. procedure. It was found that the surface structure became more uniform in the presence of Ru(bpy)(3)(2+), and the surface roughness was decreasing with the increasing of Ru(bpY)(3)(2+) concentration, suggesting a simple and effective method to control the formation of nanostructure on the gold surface.

Anodic voltammetric behavior of ethacridine at a glassy carbon electrode

The anodic voltammetric behavior of ethacridine (EAD) in the presence of various electrolytes was studied by using linear potential sweep voltammetry, differential-pulse voltammetry and cyclic voltammetry at a glassy carbon electrode. In the medium of 0.1 mol/L NaOH solution, an oxidative peak of ethaeridine was obtained. The peak potential is at about 0.40 V (vs. Ag/AgCl). The peak current is linearly increased with the concentration of ethaeridine over the range of 0.05 similar to 80 mg/L. The method has been used for the direct determination of ethacridine in injection. The relative standard deviation (n = 10) is 1.4% similar to 2.7%. The recoveries of ethacridine in urine samples are 89% similar to 95%. The mechanism of the electrode reaction was also discussed.

Digital simulation in a thin layer spectroelectrochemical cell with minigrid platinum electrode by microregion approximation explicit finite difference method

The microregion approximation explicit finite difference method is used to simulate cyclic voltammetry of an electrochemical reversible system in a three-dimensional thin layer cell with minigrid platinum electrode. The simulated CV curve and potential scan-absorbance curve were in very good accordance with the experimental results, which differed from those at a plate electrode. The influences of sweep rate, thickness of the thin layer, and mesh size on the peak current and peak separation were also studied by numerical analysis, which give some instruction for choosing experimental conditions or designing a thin layer cell. The critical ratio (1.33) of the diffusion path inside the mesh hole and across the thin layer was also obtained. If the ratio is greater than 1.33 by means of reducing the thickness of a thin layer, the electrochemical property will be far away from the thin layer property.

Anodic voltammetric behavior of inosine on a glassy carbon electrode

The anodic voltammetric behavior of inosine (I) was investigated by linar-sweep voltammetry, differential-pulse voltammetry and cyclic voltammetry at a glassy carbon electrode. In a medium of 0.1 mol/L N2HPO4, inosine showed a well defined anodic peak. The peak potential was about 1.42 V (vs. Ag/AgCl). A linear relationship held between the peak current and the concentration of inosine in the rang of 5 x 10(-4) similar to 8 x 10(-2) g/L. The peak potential decreased with the decrease of the acidity of the solution. The four anodic peaks of inosine with hypoxanthine, xanthine and uric acid were obtained. Their peak potentials were about at 1.42, 1.07, 0.72 and 0.26 Vt vs. Ag/AgCl). The method has been used for the direct determination of inosine in injections. Recoveries of inosine in urine samples were about 85%. Experimental result proved that the electrode reaction was diffusion-controlled and irreversible.

Simultaneous voltammetric determination of acetophenetidin, aminopyrine, acetaminophenol and aminophenol on a glassy carbon electrode

The voltammetric behaviour of acetophenetidin(A(1)) aminopyrine(A(2)) acetaminophenol(A(3)) and aminophenol(A(4)) was investigated by linear-sweep, differential-pulse, cyclic voltammetry at a glassy carbon electrode. In a medium of 0.1 mol/L NaOH solution, 4 high sensitivity and resolution anodic peaks were obtained. Their peak potentials are about at 0.68 V, 0.51, 0.22 and - 0.06 V( vs. Ag/AgCl). They can be used for direct determination of A(1), A(2),A(3),A(4) in samples respectively. The method is simple and rapid. The mechanism of the electrode reaction was discussed.