999 resultados para Biblioteca Medicea Laurenziana - Collezioni [:] Manoscritti - Ms. Plut. 61.45
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Pós-graduação em Agronomia - FEIS
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This work deals with the synthesis, spectroscopic characterization of mono and polynuclear Pd(II) compounds obtained from the reaction between [PdCl2(MeCN)2] precursor and imidazolidine-2-thione (L1) and benzimidazoline-2-thione (L2). The interaction between [PdCl2(MeCN)2] and imidazolidine-2-thione, in the 1:2 molar ratio, using MeOH as solvent, yielded compound [Pd2Cl4(L1)4]Cl2 (1) whereas the complex [Pd2Br4(L1)4]Br2 (2) was obtained from the reaction between 1 and Br- ions. Binuclear compounds of general formulae [Pd2(L2)4]X23/2 MeOH {X= Cl-(3), Br-(4)} were synthesized using benzimidazoline-2-thione as ligand, employing the same procedure used in the synthesis of 1 and 2, respectively. The new complexes 1-4 are crystalline, air stable and soluble in methanol and dmso. The compounds were characterized by elemental analysis, IR spectroscopy, ESI/MS mass spectrometry and thermogravimetry. Coordination of the ligands L1 and L2 via sulphur atom was evidenced by the shift of the CS band (~499 cm-1, 1 and 2; ~620 cm-1, 3 and 4) to lower frequencies in comparison with those found in the free ligands (510 cm-1, L1; 660 cm-1, L2), indicating the weakening of the CS bom after coordination. ESI/EM mass spectra (positive mode) of the complexes 1-4 allowed atribute the molecular formulae [Pd2X4(L1)4]X2 {X= Cl-(1), Br-(2)} and [Pd2(L2)4]X2 {X= Cl-(3), Br-(4)} by the appearance of the peaks at m/z 794,61 [(1) + MeOH]+, m/z 836,77 [(2) - 2H - L1]+, m/z 810 [(3) - 2Cl]+, m/z 810 [(4) - 2Br]+. The TG-DTA curves showed that the complexes 1 and 2 are thermally stable up to 212 and 169º C, respectively, and further decompose to metallic palladium at 527º C (1, obt. 28,46 %; calcd. 27,88%) and 895º C (2, obt. 22,85 %; calcd. 22,62%). Compounds 3 and 4 exhibited an initial mass loss of ~5% between 25 -146º C related to the release of metanol molecules. The complexes 3...Fujimura Leite.
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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Pós-graduação em Serviço Social - FCHS
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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Pós-graduação em Geografia - IGCE
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Boletim elaborado pela Assessoria de Comunicação e Imprensa da Reitoria da UNESP
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Revista elaborada pela Assessoria de Comunicação e Imprensa da Reitoria da UNESP
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Studies on feeding ecology are important tools for the understanding of feeding strategies and niche dynamics. Information on the type of food consumed, how, and where it is acquired, enable the elucidation of species behavioral, evolutionary and ecological aspects. The diet study based on fecal material enables a low-cost, informative research and avoids the sacrifice of animals. The general aim of this study is to characterize the diet of Euphractus sexcinctus, the yellow-armadillo, based on fecal samples, to contribute with additional information on their feeding habits. The study was undertaken at the Nhumirim ranch, Pantanal da Nhecolândia, MS, during the months of February and March, 2014. The fecal material was collected during the manual capture of the animals and oven dried at 60°C. The food items found in the feces were sorted using a magnifying glass and separated in the following categories: plant matter, invertebrates and soil. Invertebrates were identified to the order level and the plant matter to the lowest taxonomic level possible. Aiming to evaluate the invertebrate availability in the soil, pitfall traps were installed next to the location where individuals were captured, during the months of April and May. We were able to estimate the frequency with which item was consumed during the studied period, and if there is a relationship between the frequency of consumed invertebrates and their availability environment. Among the analyzed samples, we could observe the frequency of occurrence (FO) of plant matter, invertebrates and soil in all the samples. The main invertebrate orders found in the samples were: Coleoptera, Orthoptera and Hymenoptera, with FO of 100%, 100% and 87,5%, respectively. Seeds were found in 100% of the samples. The FO of the Byrsonima orbignyana was high (62,5%), and evidences the potential of the yellow-armadillos as seed dispersers. The use of other techniques, such as the micro-histological...
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Studies on feeding ecology are important tools for the understanding of feeding strategies and niche dynamics. Information on the type of food consumed, how, and where it is acquired, enable the elucidation of species behavioral, evolutionary and ecological aspects. The diet study based on fecal material enables a low-cost, informative research and avoids the sacrifice of animals. The general aim of this study is to characterize the diet of Euphractus sexcinctus, the yellow-armadillo, based on fecal samples, to contribute with additional information on their feeding habits. The study was undertaken at the Nhumirim ranch, Pantanal da Nhecolândia, MS, during the months of February and March, 2014. The fecal material was collected during the manual capture of the animals and oven dried at 60°C. The food items found in the feces were sorted using a magnifying glass and separated in the following categories: plant matter, invertebrates and soil. Invertebrates were identified to the order level and the plant matter to the lowest taxonomic level possible. Aiming to evaluate the invertebrate availability in the soil, pitfall traps were installed next to the location where individuals were captured, during the months of April and May. We were able to estimate the frequency with which item was consumed during the studied period, and if there is a relationship between the frequency of consumed invertebrates and their availability environment. Among the analyzed samples, we could observe the frequency of occurrence (FO) of plant matter, invertebrates and soil in all the samples. The main invertebrate orders found in the samples were: Coleoptera, Orthoptera and Hymenoptera, with FO of 100%, 100% and 87,5%, respectively. Seeds were found in 100% of the samples. The FO of the Byrsonima orbignyana was high (62,5%), and evidences the potential of the yellow-armadillos as seed dispersers. The use of other techniques, such as the micro-histological...
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Joseph Barbosa de Sáa (? – 1775), mais conhecido por seus escritos sobre a história do estado do Mato Grosso, Brasil, completou em 1769 um volumoso (408 fólios) e erudito manuscrito, intitulado “Dialogos geograficos, coronologicos, polliticos e naturais”, que nunca foi publicado na íntegra. Esse manuscrito está depositado na Biblioteca Pública do Porto (manuscrito no. 235), em Portugal. Dez capítulos desse manuscrito tratam dos produtos naturais do Brasil (acima de mil, quase a metade sendo animais), observados por Sáa ao longo da costa do Rio de Janeiro, em São Paulo, sul de Goiás e especialmente no Mato Grosso, sendo a primeira monografia sobre a história natural deste último estado. Esses capítulos são aqui transcritos e comentados.
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La Biblioteca Universitaria de Las Palmas de Gran Canaria ha tomado parte activa en la promoción de la lectura entre sus comunidades de usuarios. Para conseguir este objetivo se han adquirido colecciones de literatura de ocio, tanto en formato físico como electrónico, y se han comenzado a utilizar herramientas 2.0, fundamentalmente los blogs para dar a conocer novedades literarias y actividades de la biblioteca relacionadas con el fomento de la lectura. Pero se ha ido más allá, y se han creado una serie de proyectos más ambiciosos que permiten una mayor participación de los usuarios. Estamos ante una Biblioteca 2.0. donde se pueden compartir contenidos, opiniones, conocimientos, valoraciones, etc. Es el caso de sitios webs, opac social y otros como facebook, tuenti, twitter, wikipedia, canal youtube, todas ellas vías descritas en esta comunicación con el fin de promocionar el fondo bibliográfico y la lectura en general.
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[ES]Con motivo de la celebración del Día Internacional del Libro 2014 la empresa canaria de divulgación de obras de divulgación científica sobre las ciencias del mar, Oceanográfica, nos cuenta cómo lo han hecho y porqué se han auditado conforme a los principios de la Economñia del Bien Común. Una de las razones del éxito obtenido parece residir en el maridaje del trabajo editorial con contenidos de calidad proporcionado por los científicos con vocación de divulgar dicho conocimiento
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[ES]El Sterna, velero de 26 metros capitaneado por el reconocido navegante oceánico y emprendedor Albert Bargués, es el único barco de nuestro país que ofrece viajes a vela por las grandes latitudes. A finales de octubre llega a Barcelona después de estar 5 meses para el Ártico. Albert y su equipo, junto con los grupos de viajeros que han embarcado en el Sterna este verano, han vivido experiencias irrepetibles y un acercamiento intenso a la naturaleza navegando por las Islas Svalbard, Isla del Hueso, Jan Mayen, costa este de Groenlandia …. La filosofía de Sterna se que “Todavía hay lugares en la tierra donde sólo se puede llegar desde el mar”. Con este principio, se navega por destinos poco habituales y remotos donde predomina el valor ambiental y el descubrimiento. Es un proyecto empresarial nacido en nuestro país y que, entre otras cosas, ha sido elegido por distintas entidades e iniciativas, como una de las empresas más innovadoras del momento invitándola a participar en diversos eventos (Salón Internacional del Turismo de Cataluña 2014 en Innovation Zone, Exposición Ayer, hoy y mañana Cataluña Emprende…). La voluntad de los fundadores de Sterna se aportar un valor ambiental y social a través de su actividad. Por eso el barco y sus navegaciones están disponibles para llevar a cabo proyectos de investigación y de divulgación del conocimiento. Entre las colaboraciones de Sterna de esta primera campaña en el ártico han salido una serie de publicaciones periódicas en la sección El Viajero de El País digital y un documental, en edición en estos momentos, “Latitud 80º” que ya ha sido presentado en foros internacionales del sector www.goroka.tv/portfolio/latitud-80-sterna/.
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[ES] El artículo hace un recorrido por la historia de Jable, el archivo de prensa digital que la Biblioteca de la Universidad de Las Palmas de Gran Canaria pone a disposición de cualquier persona interesada, desde sus orígenes hasta el momento de la redacción del artículo, resaltando las mejoras incorporadas a la herramienta y las principales cabeceras que contiene.