Novas métricas holísticas para avaliação da verdura de reações de síntese em laboratório

New semi-quantitative metrics for simple evaluation of global greenness of chemical reactions used in teaching laboratories, namely, the Green Circle (GC) and Green Matrix (GM), were developed. These metrics globally consider all Twelve Principles of Green Chemistry. To illustrate their construction, the greenness of several syntheses performed in the laboratory under different sets of conditions was assessed. The tools were validated by comparing the results with another metric, the Green Star (GS), developed in our previous study. Results showed these new metrics were useful for the intended purpose, having the advantage of being simpler than the GS.

Avaliação da "microverdura" de sínteses com a estrela verde

This article reports a study to increase the overall greenness of chemical syntheses for first-year university laboratories. The separate evaluation of the micro-greenness of the three stages of synthesis (reaction, isolation and purification) using the Green Star (GS) was implemented and their respective contribution to overall greenness was investigated for two examples: syntheses of cobalt (III) tris(acetylacetonate) and potassium nitrilosulfonate. Results showed that the post-reaction (work-up) steps are the most problematic for overall greenness. Greenness optimization can be achieved by combining the greenest procedures for each step obtained from different protocols available in the literature.

Bateria de métricas para avaliação da verdura material de reações de síntese

The use of a battery of three mass metrics (atomic economy - AE, reaction mass efficiency - RME, and mass intensity - MI) for systemic evaluation of the material greenness of synthesis reactions is presented. Material greenness is discussed in terms of materialization/dematerialization of the reaction system and also according to the first two Principles of Green Chemistry, and is shown to involve two components: atomic greenness (incorporation of the atoms provided by reagents into the product, evaluated by AE and RME); and massic greenness (global mass of reagents and non-stoichiometric materials, evaluated by MI, related to the production of residues).

Cinética de la lombriz de tierra Eisenia fetida (Edwards y Bholen, 1996) en la generación de Humus para la producción de nopal verdura

Tesis ( Maestro en Ciencias de Producción Agrícola) U.A.N.L.

Efecto de biofertilizantes y productos orgánicos en la producción de nopal verdura.

Tesis (Maestría en Ciencias en Producción Agrícola) UANL, 2014.

Semelhanças e diferenças de valores pessoais entre consumidores de eletrodomésticos nos municípios de Lajeado e Estrela-RS

O comportamento das pessoas é baseado na sua cultura, valores e atitudes. Conhecendo-os melhor, é possível entender um pouco melhor como as pessoas agem. Este trabalho objetivou identificar semelhanças e diferenças de valores pessoais entre os consumidores domiciliados na cidade de Lajeado e de Estrela através da escala de Valores de Rokeach (1973). Rokeach divide os Valores em Instrumentais e Valores Terminais. Os primeiros seriam ferramentas para atingir os segundos, desejos do ser humano. Este trabalho foi realizado através de um instrumento de coleta, aplicado a 102 clientes de Lajeado e a 100 clientes de Estrela. Os dados foram então tabulados e analisados. Os resultados demonstraram que há semelhanças e diferenças significativas entre as duas cidades, segundo a Escala de Rokeach. Os dois primeiros Valores Instrumentais em ambas as cidades são Honesto e Responsável. Os dois primeiros Valores Terminais são Um Mundo de Paz e Segurança Familiar. Ocorrem diferenças entre as cidades quando se considera a segmentação, como é o caso da Idade. Os valores “Amizade Verdadeira”, “Segurança Familiar” e “Salvação” são significativos para Estrela, mas não para Lajeado. Nesta, por sua vez, é significativo “Sabedoria”.

Entre o mar e estrela, um lugar para se bem viver : a problemática da expansão urbana da Cidade de Baía Formosa/RN

The urban expansion problem of Baía Formosa, a southern edge city of de Rio Grande do Norte eastern coast, which has been presented in other coast Brazilian towns, specially on those with tourist activities increase. Therefore, this situation brings huge concerns to their inhabitants, to their technical /scientific community and to the governments, because of the conflicts of interest and of the growth of urban problems that this has been created. At Baía Formosa, the situation is aggravated because the city is confined, once around it, there are large private proprieties, environmental preservation area and the sea, at the eastern edge. The objectives of this study are the analyses of this city expansion process in order to obtain adequate alternatives and defining methodology to apply in other urban nucleus that are subjected to similar situations. Of course, presents social relations, environmental conditions and promoting local population insertion should be considered in order that enjoin this process and contributing to a better social balance. This case study has used bibliography research, field data, maps and soil occupation recorders and photographs of the area, besides the primary data gathering by surveys carried out with many social actors. The present analysis shows that the urban expansion observed today is featured by a recent unsustainable model, which attacks the environment and brings either farm conflicts. On the other hand, the ecological tourism can represent an alternative in order to achieve an adequate expansion form, without forgetting the several structural parameters necessary to support the sustainable activities

No céu da boca das gentes, tem estrela e maravilhas: atualização e permanência das narrativas populares nos contos de enganar a morte

This current study consists in an analysis of the work Contos de enganar a morte (2004), of the novelist, illustrator and researcher of popular culture Ricardo Azevedo, aiming to highlight aspects and elements present in this work which show the update and the permanence of traditional popular narratives, widespread by orality, especially those collected by the Luís da Câmara Cascudo in Literatura oral no Brasil (1984), linked to the category of the Cycle of the Death and Tales of the Deceived Demon. It is argued that the symbolic, playful, humor and aspects of orality, evident in these narratives are cultural possessions own of a popular tradition that diffuses, is updated and maintained by the memory of handmade anonymous narrators (BENJAMIN, 1994), poets and brazilian singers of cordel, holders of the traditional knowledge not established, but polyphonic, dialogical and democratic in essence (BAKHTIN, 1996). Still, alongside the people who know and counts the stories of Trancoso and Fairies, the tale, as a written literary genre, has allowed to maintain outstanding the same subjects successively renewed, enabling the resistance of popular narrative tradition and understanding and appreciation of popular orality (ZUMTHOR, 1993; 2000) and of the updates performed in the contemporarity (CANDIDO, 1976), without losing sight of the singularity and autonomy of the literary work

Um estudo sobre a interação estrela-planeta a partir da relação massa-período planetário com a atividade estelar

n this work, we analyze the behavior of the chromospheric and coronal activities as a function of the mass and the orbital period of extrasolar planets which were detected by transit technique. So we look for possible effects of the planet on the star s chromosphere and corona. For this study we selected a sample of 48 stars with chromospheric activity indicator and 23 with coronal activity indicator. Our work is based on the work from Pont et al. (2011) in order to study stars with planets which were obtained by transit technique. Furthermore, we studied the relationship between planetary mass and orbital period with the chromospheric and coronal activity in order to better understand which influences the planets cause in the outer layers of stellar atmosphere. In our analysis we can observe that the mass of the planets exerts no influence in the stellar activity. However, we observed that the stellar coronal and chromospheric activities decrease with the increase of the orbital period of the planet

Um estudo sobre a interação estrela-planeta a partirda relação massa-período planetário com a atividade estelar

In this work, we analyze the behavior of the chromospheric and coronal activities as a function of the mass and the orbital period of extrasolar planets which were detected by transit technique. So we look for possible effects of the planet on the star s chromosphere and corona. For this study we selected a sample of 48 stars with chromospheric activity indicator and 23 with coronal activity indicator. Our work is based on the work from Pont et al. (2011) in order to study stars with planets which were obtained by transit technique. Furthermore, we studied the relationship between planetary mass and orbital period with the chromospheric and coronal activity in order to better understand which influences the planets cause in the outer layers of stellar atmosphere. In our analysis we can observe that the mass of the planets exerts no influence in the stellar activity. However, we observed that the stellar coronal and chromospheric activities decrease with the increase of the orbital period of the planet

Interação estrela planeta: sobre o magnetismo de planetas gigantes gasosos

In this thesis we analyze the effects that the presence of a near gas giant planet can cause in its host star. It has been argued that the star planet interaction can cause changes in the coronal and chromospheric stellar activity. With this in mind, we analyze a sample of 53 extrasolar planets orbiting F, G and K main sequence stars, among them three super-Earths. In this analysis, we look for evidence of changes in the chromospheric activity due to the proximity of the giant planet. We show that, so far, there is not enough evidence to support such a hypothesis. Making use of the same sample and also taking in account available data for the Solar System, we revisit the so-called magnetic Bode s law. This law proposes the existence of a direct relationship between magnetism and rotation. By using estimations for the stellar and planetary magnetic momentM and the angular momentumL, we construct a Blackett s diagram (logL 􀀀logM). In this diagram is evident that the magnetic Bode s law is valid for both the Solar System and the new planetary systems

Análise espectroscópica da estrela HD 150050: uma nova estrela gigante rica em lítio

Conselho Nacional de Desenvolvimento Científico e Tecnológico