Rapidly Infrared-Assisted Cooperatively Self-Assembled Highly Ordered Multiscale Porous Materials

In this paper, cooperative self-assembly (CSA) of colloidal spheres with different sizes was studied. It was found that a complicated jamming effect makes it difficult to achieve an optimal self-assembling condition for construction of a well-ordered stacking of colloidal spheres in a relatively short growth time by CSA. Through the use of a characteristic infrared (IR) technique to significantly accelerate local evaporation on the growing interface without changing the bulk growing environment, a concise three-parameter (temperature, pressure, and IR intensity) CSA method to effectively overcome the jamming effect has been developed. Mono- and multiscale inverse opals in a large range of lattice scales can be prepared within a growth time (15-30 min) that is remarkably shorter than the growth times of several hours for previous methods. Scanning electron microscopy images and transmittance spectra demonstrated the superior crystalline and optical qualities of the resulting materials. More importantly, the new method enables optimal conditions for CSA without limitations on sizes and materials of multiple colloids. This strategy not only makes a meaningful advance in the applicability and universality of colloidal crystals and ordered porous materials but also can be an inspiration to the self-assembly systems widely used in many other fields, such as nanotechnology and molecular bioengineering.

A generalized model for the effective thermal conductivity of porous media based on self-similarity

A generalized model for the effective thermal conductivity of porous media is derived based on the fact that statistical self-similarity exists in porous media. The proposed model assumes that porous media consist of two portions: randomly distributed non-touching particles and self-similarly distributed particles contacting each other with resistance. The latter are simulated by Sierpinski carpets with side length L = 13 and cutout size C = 3, 5, 7 and 9, respectively, depending upon the porosity concerned. Recursive formulae are presented and expressed as a function of porosity, ratio of areas, ratio of component thermal conductivities and contact resistance, and there is no empirical constant and every parameter has a clear physical meaning. The model predictions are compared with the existing experimental data, and good agreement is found in a wide range of porosity of 0.14-0.80, and this verifies the validity of the proposed model.

On the computation of space-time correlations by large-eddy simulation

The effect of subgrid-scale (SGS) modeling on velocity (space-) time correlations is investigated in decaying isotropic turbulence. The performance of several SGS models is evaluated, which shows superiority of the dynamic Smagorinsky model used in conjunction with the multiscale large-eddy simulation (LES) procedure. Compared to the results of direct numerical simulation, LES is shown to underpredict the (un-normalized) correlation magnitude and slightly overpredict the decorrelation time scales. This can lead to inaccurate solutions in applications such as aeroacoustics. The underprediction of correlation functions is particularly severe for higher wavenumber modes which are swept by the most energetic modes. The classic sweeping hypothesis for stationary turbulence is generalized for decaying turbulence and used to analyze the observed discrepancies. Based on this analysis, the time correlations are determined by the wavenumber energy spectra and the sweeping velocity, which is the square root of the total energy. Hence, an accurate prediction of the instantaneous energy spectra is most critical to the accurate computation of time correlations. (C) 2004 American Institute of Physics.

About generalized scaling for passive scalars in fully developed turbulence

In this paper we use a simple normal form approach of scale invariant fields to investigate scaling laws of passive scalars in turbulence. The coupling equations for velocity and passive scalar moments are scale covariant. Their solution shows that passive scalars in turbulence do not generically follow a general scaling observed for velocity field because of coupling effects.

Composite materials dynamic fracture studies by generalized Shmuely difference algorithm

The generalized Shmuely Difference Algorithm (GSDA) is presented here to analyze the dynamic fracture performance of orthogonal-anisotropic composite materials, such as glass fibre reinforced phenolplast. The difference recurrence Formulae and boundary condition difference extrapolation formulae are derived and programmed. The dynamic stress intensity factors (DSIF) of the isotropic and anisotropic centrally cracked plates are computed respectively using GSDA and compared with that published previously. GSDA is proved effective and reliable. Copyright (C) 1996 Elsevier Science Ltd.

Some comments on the stability theory of mhd shock waves

The stability (evolutionarity) problem for a kind of MHD shock waves is discussed in this paper. That is to solve the interaction problem of MHD shock waves with (2-dimensional) oblique incident disturbances. In other words, the result of gasdynamic shocks is generalized to the case of MHD shocks. The previous conclusion of stability theory of MHD shock waves obtained from the solution of interaction problem of MHD shock wave with (one-dimensional) normal shock wave is that only fast and slow shocks are stable, and intermediate shocks are unstable. However, the results of this paper show that when the small disturbances are the Alfven waves a new stability condition which is related to the parameters in front of and behind the shock wave is derived. When the disturbances are entropy wave and fast and slow magneto acoustic waves the stability condition is related to the frequency of small disturbances. As the limiting ease, i. e. when a normal incident (reflection, refraction) is consid...更多ered, the fast and slow shocks are unstable. The results also show that the conclusion drawn by Kontorovich is invalid for the stability theory of shock waves.

Generalized rayleigh principle and its applications

In this paper, we mainly deal with cigenvalue problems of non-self-adjoint operator. To begin with, the generalized Rayleigh variational principle, the idea of which was due to Morse and Feshbach, is examined in detail and proved more strictly in mathematics. Then, other three equivalent formulations of it are presented. While applying them to approximate calculation we find the condition under which the above variational method can be identified as the same with Galerkin's one. After that we illustrate the generalized variational principle by considering the hydrodynamic stability of plane Poiseuille flow and Bénard convection. Finally, the Rayleigh quotient method is extended to the cases of non-self-adjoint matrix in order to determine its strong eigenvalne in linear algebra.