Neotectonics in the northern equatorial Brazilian margin

An increasing volume of publications has addressed the role of tectonics in inland areas of northern Brazil during the Neogene and Quaternary, despite its location in a passive margin. Hence, northern South America plate in this time interval might have not been as passive as usually regarded. This proposal needs further support, particularly including field data. In this work, we applied an integrated approach to reveal tectonic structures in Miocene and late Quaternary strata in a coastal area of the Amazonas lowland. The investigation, undertaken in Marajo Island, mouth of the Amazonas River, consisted of shallow sub-surface geophysical data including vertical electric sounding and ground penetrating radar. These methods were combined with morphostructural analysis and sedimentological/stratigraphic data from shallow cores and a few outcrops. The results revealed two stratigraphic units, a lower one with Miocene age, and an upper one of Late Pleistocene-Holocene age. An abundance of faults and folds were recorded in the Miocene deposits and, to a minor extent, in overlying Late Pleistocene-Holocene strata. In addition to characterize these structures, we discuss their origin, considering three potential mechanisms: Andean tectonics, gravity tectonics related to sediment loading in the Amazon Fan, and rifting at the continental margin. Amongst these hypotheses, the most likely is that the faults and folds recorded in Marajo Island reflect tectonics associated with the history of continental rifting that gave rise to the South Atlantic Ocean. This study supports sediment deposition influenced by transpression and transtension associated with strike-slip divergence along the northern Equatorial Brazilian margin in the Miocene and Late Pleistocene-Holocene. This work records tectonic evidence only for the uppermost few ten of meters of this sedimentary succession. However, available geological data indicate a thickness of up to 6 km, which is remarkably thick for an area regarded as a passive margin. (C) 2012 Elsevier Ltd. All rights reserved.

Consolidation of Bi-2223 superconducting powders by spark plasma sintering

The spark plasma sintering (SPS) technique, by using a compacting pressure of 50 MPa, was used to consolidate pre-reacted powders of Bi1.65Pb0.35Sr2Ca2Cu3O10+delta (Bi-2223). The influence of the consolidation temperature, T-D, on the structural and electrical properties has been investigated and compared with those of a reference sample synthesized by the traditional solid-state reaction method and subjected to the same compacting pressure. From the X-ray diffraction patterns, performed in both powder and pellet samples, we have found that the dominant phase is the Bi-2223 in all samples but traces of the Bi2Sr2CaCu2O8+x (Bi-2212) were identified. Their relative density were similar to 85% of the theoretical density and the temperature dependence of the electrical resistivity, rho(T), indicated that increasing T-D results in samples with low oxygen content because the SPS is performed in vacuum. Features of the rho(T) data, as the occurrence of normal-state semiconductor-like behavior of rho(T) and the double resistive superconducting transition, are consistent with samples comprised of grains with shell-core morphology in which the shell is oxygen deficient. The SPS samples also exhibited superconducting critical current density at 77 K, J(c)(77K), between 2 and 10A/cm(2), values much smaller than similar to 22A/cm(2) measured in the reference sample. Reoxygenation of the SPS samples, post-annealed in air at different temperatures and times, was found to improve their microstructural and transport properties. Besides the suppression of the Bragg peaks belonging to the Bi-2212 phase, the superconducting properties of the post-annealed samples and particularly J(c)(77K) were comparable or better than those corresponding to the reference sample. Post-annealed samples at 750 degrees C for 5min exhibited J(c)(77K) similar to 130A/cm(2) even when uniaxially pressed at only 50 MPa. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4768257]

Superconductivity at 9.5 K in the Ti2GeC compound

We report on the investigation of the Ti2GeC properties by X-ray diffraction, magnetic and electrical resistivity measurements. Polycrystalline samples of Ti2GeC with nominal compositions were prepared by solid state reaction. X-ray powder patterns suggest that all peaks can be indexed with the hexagonal phase of Cr2AlC prototype. The temperature dependence of both electrical resistivity and magnetization indicate a bulk type-II superconductivity at 9.5 K. Magnetoresistive data suggest an upper critical field of B-c2 similar to 8.1 T and coherence length similar to 61 A degrees . Furthermore, the results highlight the highest critical temperature reported up to now for an H-phase.

Interstitial doping induced superconductivity at 15.3 K in Nb5Ge3 compound

It is reported superconductivity in Nb5Ge3C0.3, an interstitial carbide compound. The temperature dependence of the electrical resistivity, ac-susceptibility, and heat capacity (HC) indicate that a bulk type-II superconductivity appears at T-C - 15.3 K. Magneto-resistance measurements suggest an upper critical field of B-C2 similar to 10.6 T and a coherence length of xi similar to 55 angstrom at zero temperature. Neutron diffraction analyzes locate the carbon atoms at the interstitial 2b site of the Mn5Si3 type-structure. Heat capacity data below T-C are well described by BCS theory. The size of the jump at T-C is in good agreement with the superconducting volume fraction observed in susceptibility measurements. A Debye temperature and Sommerfeld constant were also extracted from heat capacity data as 343 K and 34 mJ/mol K-2, respectively. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4730611]

Conduction mechanisms in p-type Pb1-xEuxTe alloys in the insulator regime

Electrical resistivity measurements were performed on p-type Pb1-xEuxTe films with Eu content x = 4%, 5%, 6%, 8%, and 9%. The well-known metal-insulator transition that occurs around 5% at room temperature due to the introduction of Eu is observed, and we used the differential activation energy method to study the conduction mechanisms present in these samples. In the insulator regime (x>6%), we found that band conduction is the dominating conduction mechanism for high temperatures with carriers excitation between the valence band and the 4f levels originated from the Eu atoms. We also verified that mix conduction dominates the low temperatures region. Samples with x = 4% and 5% present a temperature dependent metal insulator transition and we found that this dependence can be related to the relation between the thermal energy k(B)T and the activation energy Delta epsilon(a). The physical description obtained through the activation energy analysis gives a new insight about the conduction mechanisms in insulating p-type Pb1-xEuxTe films and also shed some light over the influence of the 4f levels on the transport process in the insulator region. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4729813]

Microstructure and metal-insulator transition in single crystalline KMo4O6

High quality KMo4O6 single crystals with tetragonal structure (space group P4/mbm) have been prepared by fused salt electrolysis. The crystals were studied by scanning electron microscopy (SEM), X-ray diffractometry, electrical resistivity, and magnetization measurements. X-ray powder diffraction patterns and SEM have given some information on the growth of single crystals. Electrical resistivity as a function of temperature shows that the KMo4O6 compound is a bad metal with resistivity change of approximately 30% in the temperature range from 2 to 300K. A metal-insulator transition (MIT), observed at approximately 110K, has been also confirmed for this material. Magnetization as a function of temperature agrees with previous report, however a magnetic ordering has been observed in M(H) curves in the whole temperature range.

Ensayo de correlación entre los parámetros geofísicos e hidrológicos de los depósitos volcánicos de la Caldera de Bandama (Gran Canaria)

[EN]The geometry and the hydraulic conductivity of the unsaturated zone is difficult to study from traditional techniques, like samples from trenches that normally provide surficial data or boreholes, that are expensive and provide local information. Non-destructive geophysical techniques and among them the electrical resistivity tomography method can be applicable in volcanic areas, where the lava flows and pyroclastic deposits have a wide range of values depending on the degree of fracturing and weathering of lava flows, and porosity and texture of the pyroclastic deposits. In order to characterize the subsurface geology below the golf course of Bandama (Gran Canaria) has conducted a campaign of electrical resistivity tomography profiles.

Ancient Greek harbours used as geo-archives for palaeotsunami research : case studies from Krane (Cefalonia), Lechaion (Gulf of Corinth) and Kyllini (Peloponnese)

Since historical times, coastal areas throughout the eastern Mediterranean are exposed to tsunami hazard. For many decades the knowledge about palaeotsunamis was solely based on historical accounts. However, results from timeline analyses reveal different characteristics affecting the quality of the dataset (i.e. distribution of data, temporal thinning backward of events, local periodization phenomena) that emphasize the fragmentary character of the historical data. As an increasing number of geo-scientific studies give convincing examples of well dated tsunami signatures not reported in catalogues, the non-existing record is a major problem to palaeotsunami research. While the compilation of historical data allows a first approach in the identification of areas vulnerable to tsunamis, it must not be regarded as reliable for hazard assessment. Considering the increasing economic significance of coastal regions (e.g. for mass tourism) and the constantly growing coastal population, our knowledge on the local, regional and supraregional tsunami hazard along Mediterranean coasts has to be improved. For setting up a reliable tsunami risk assessment and developing risk mitigation strategies, it is of major importance (i) to identify areas under risk and (ii) to estimate the intensity and frequency of potential events. This approach is most promising when based on the analysis of palaeotsunami research seeking to detect areas of high palaeotsunami hazard, to calculate recurrence intervals and to document palaeotsunami destructiveness in terms of wave run-up, inundation and long-term coastal change. Within the past few years, geo-scientific studies on palaeotsunami events provided convincing evidence that throughout the Mediterranean ancient harbours were subject to strong tsunami-related disturbance or destruction. Constructed to protect ships from storm and wave activity, harbours provide especially sheltered and quiescent environments and thus turned out to be valuable geo-archives for tsunamigenic high-energy impacts on coastal areas. Directly exposed to the Hellenic Trench and extensive local fault systems, coastal areas in the Ionian Sea and the Gulf of Corinth hold a considerably high risk for tsunami events, respectively.Geo-scientific and geoarcheaological studies carried out in the environs of the ancient harbours of Krane (Cefalonia Island), Lechaion (Corinth, Gulf of Corinth) and Kyllini (western Peloponnese) comprised on-shore and near-shore vibracoring and subsequent sedimentological, geochemical and microfossil analyses of the recovered sediments. Geophysical methods like electrical resistivity tomography and ground penetrating radar were applied in order to detect subsurface structures and to verify stratigraphical patterns derived from vibracores over long distances. The overall geochronological framework of each study area is based on radiocarbon dating of biogenic material and age determination of diagnostic ceramic fragments. Results presented within this study provide distinct evidence of multiple palaeotsunami landfalls for the investigated areas. Tsunami signatures encountered in the environs of Krane, Lechaion and Kyllini include (i) coarse-grained allochthonous marine sediments intersecting silt-dominated quiescent harbour deposits and/or shallow marine environments, (ii) disturbed microfaunal assemblages and/or (iii) distinct geochemical fingerprints as well as (iv) geo-archaeological destruction layers and (v) extensive units of beachrock-type calcarenitic tsunamites. For Krane, geochronological data yielded termini ad or post quem (maximum ages) for tsunami event generations dated to 4150 ± 60 cal BC, ~ 3200 ± 110 cal BC, ~ 650 ± 110 cal BC, and ~ 930 ± 40 cal AD, respectively. Results for Lechaion suggest that the harbour was hit by strong tsunami impacts in the 8th-6th century BC, the 1st-2nd century AD and in the 6th century AD. At Kyllini, the harbour site was affected by tsunami impact in between the late 7th and early 4th cent. BC and between the 4th and 6th cent. AD. In case of Lechaion and Kyllini, the final destruction of the harbour facilities also seems to be related to the tsunami impact. Comparing the tsunami signals obtained for each study areas with geo-scientific data from palaeotsunami events from other sites indicates that the investigated harbour sites represent excellent geo-archives for supra-regional mega-tsunamis.

Indagini di tomografia geoelettrica sulle dune costiere della Provincia di Ravenna

Questa tesi Magistrale è frutto di un'attività di ricerca, che consiste nella realizzazione di un'indagine geofisica di tipo geoelettrico (ERT Electrical Resistivity Tomography). Lo scopo è quello di caratterizzare l'idrogeologia di una porzione limitata dell'acquifero freatico costiero ravennate, situato nella Pineta Ramazzotti di Lido di Dante, cercando di apportare nuove conoscenze sulle dinamiche che favoriscono l'ingressione marina (problema di forte attualità)che potrebbero contribuire a migliorare la gestione e la tutela delle risorse idriche. In questo contesto la tesi si pone come obiettivo quello di valutare l'applicabilità del metodo geoelettrico verificando se questo è in grado d'individuare efficacemente l'interfaccia acqua dolce-salata e le strutture presenti nel sottosuolo, in due tipologie di ambiente, con e senza un sistema di dune. I risultati dimostrano che dal punto di vista scientifico, il metodo geoelettrico ha verificato il principio di Ghyben-Herzberg, il quale suppone che vi sia una relazione inversa tra quota topografica e limite superiore della zona satura con acqua salata, inoltre si è riscontrata una certa stagionalità tra i profili acquisiti in momenti diversi (influenzati dalla piovosità). Mentre dal punto di vista tecnologico, il metodo, è di difficile utilizzo negli ambienti di transizione tanto ché chi si occupa professionalmente di questi rilievi preferisce non eseguirli. Questo è dovuto alla mancanza di un protocollo per le operazioni di acquisizione e a causa dell'elevato rumore di fondo che si riscontra nelle misurazioni. Con questo studio è stato possibile calibrare e sviluppare un protocollo, utilizzabile con diverse spaziature tra gli elettrodi, che è valido per l'area di studio indagata. Si è riscontrato anche che l'utilizzo congiunto delle informazioni delle prospezioni e quelle dei rilievi classici (monitoraggio della superficie freatica, parametri chimico-fisici delle acque sotterranee, rilievo topografico e sondaggi geognostici), generino un prodotto finale di semplice interpretazione e di facile comprensione per le dinamiche in atto.

Metodi di valutazione diretta ed indiretta della conducibilità idraulica verticale dei terreni sciolti Esempi applicativi nella Alta e Bassa Pianura Friulana

Nel corso del tempo, nell’ambito dell’idrogeologia sono state sviluppate diverse tecniche per la determinazione conducibilità idraulica (K). Negli ultimi decenni sempre maggiori sforzi sono stati compiuti per integrare le tecniche geofisiche a questo specifico settore di ricerca; in particolare le metodologie geoelettriche sono state fonte di molteplici studi per la determinazione indiretta di K. Su questa idea è stato impostato il lavoro presentato in questo elaborato di tesi. Ciò che questo propone è infatti l’esecuzione di test in campo che prevedono il monitoraggio time lapse con tecnologia ERT (Electrical Resistivity Tomography) di un tracciante salino iniettato nel terreno. Il fine ultimo è quello di poter sviluppare una tecnica indiretta per la stima della conducibilità idraulica verticale dei terreni sciolti. Le immagini tomografiche, realizzate in sequenza nel tempo, premettono la visualizzazione l’avanzamento del plume basso resistivo in movimento nel terreno (causato dalla salamoia iniettata). Un successivo confronto grafico fra queste permette di quantificare lo spostamento nel tempo, in modo da calcolare in seguito la velocità di infiltrazione del tracciante, e in ultimo stimare la K del terreno in analisi. I risultati ottenuti con tale metodologia sperimentale, opportunamente elaborati tramite specifici software, sono stati confrontati, dove possibile, con i valori forniti dall’impiego di altre tecniche più tradizionali, in modo da poter valutare la bontà del dato ottenuto. Le aree studio individuate per condurre tali sperimentazioni ricadono all’interno del territorio regionale del Friuli Venezia Giulia, in particolare nell’area di Alta e Bassa pianura friulana. La strumentazione (resistivimetro multicanale VHR X612-EM della MAE-Molisana Apparecchiature Elettroniche) e il software (Res2dinv) per la raccolta e l’elaborazione delle immagini tomografiche sono stati gentilmente messi a disposizione dalla società Geomok s.r.l. del Dott. Geol. Mocchiutti (Udine) con la cui collaborazione è stato realizzato questo elaborato di tesi.

Integrated Geophysical Investigation of the St. James Fault Complex: A Case Study

We noninvasively detected the characteristics and location of a regional fault in an area of poor bedrock exposure complicated by karst weathering features in the subsurface. Because this regional fault is associated with sinkhole formation, its location is important for hazard avoidance. The bedrock lithologies on either side of the fault trace are similar; hence, we chose an approach that capitalized on the complementary strengths of very low frequency (VLF) electromagnetic, resistivity, and gravity methods. VLF proved most useful as a first-order reconnaissance tool, allowing us to define a narrow target area for further geophysical exploration. Fault-related epikarst was delineated using resistivity. Ultimately, a high-resolution gravity survey and subsequent inverse modeling using the results of the resistivity survey helped to further constrain the location and approximate orientation of the fault. The combined results indicated that the location of the fault trace needed to be adjusted 53 m south of the current published location and was consistent with a north-dipping thrust fault. Additionally, a gravity low south of the fault trace agreed with the location of conductive material from the resistivity and VLF surveys. We interpreted these anomalies to represent enhanced epikarst in the fault footwall. We clearly found that a staged approach involving a progression of methods beginning with a reconnaissance VLF survey, followed by high-resolution gravity and electrical resistivity surveys, can be used to characterize a fault and fault-related karst in an area of poor bedrock surface exposure.

Petrophysical investigation on sediment core CRP-3 from the Ross Sea, Antarctica

A suite of petrophysical properties - velocity, resistivity, bulk density, porosity, and matrix density - was measured on 88 core plugs from the CRP-3 drillhole. Core-plug bulk densities were used to recalibrate both whole-core and downhole bulk density logs. Core-plug measurements of matrix density permit conversion of the whole-core and downhole bulk density logs to porosity. Both velocity and formation factor (a normalized measure of resistivity) are strongly correlated with porosity. The velocity/porosity pattern is similar to that for the lower part of CRP-2A and is consistent with the empirical relationship for sandstones. Core-plug and whole-core measurements of P-wave velocity at atmospheric pressure exhibit excellent agreement. Measurements of velocity as a function of pressure indicate a significantly higher velocity sensitivity to pressure than has been observed at CRP-1 and CRP-2A; rebound or presence of microcracks at CRP-3 may be responsible. The percentage difference between velocities at in situ pressures and atmospheric pressures increases downhole from 0% at the seafloor to 9% at the bottom. This pattern can be used to correct whole-core velocity data, measured at atmospheric pressure, to in situ velocities for depth-to-time conversion and associated comparison to the seismic profile across the drillsite

(Table 1) Physical properties of basalts from DSDP Holes 69-504B and 70-504B

A detailed study of physical properties was made on core samples from Deep Sea Drilling Project Hole 504B. The measured properties are density, porosity, sonic velocity, electrical resistivity, and fluid permeability. Basalts from this young oceanic crust have higher density and sonic velocity than the average DSDP basalts. Porosity (and temperature) dependences of physical properties are given by V = Vo - a-phi; roo = roo-0 exp(E*/RT)phi**-q; k = k0' phi**2q-1; where V is the sonic velocity (km/s), Vo = 6.45 (km/s), a = 0.111 (km/s %), phi is the porosity (%), roo is the electrical resistivity (ohm m), roo-0 = 0.002 (ohm m), E* = 2.7 (Kcal/mol) for fresh basalts, RT has its usual meaning, q = 1.67 ± 0.27, k is the permeability, k0' = (1 to about 10) x 10**-12 (cm**2). Porosity distribution in the crust in this area is estimated by combining the seismic velocity distribution and velocity-porosity relation. Because of the rapid decrease in porosity with depth, resistivity increases and permeability decreases rapidly with depth. The decreasing rate of permeability with increasing depth is approximately given by k(cm**2) = 2 x 10**-10 exp(-z (km)/0.3).

(Table 1) Anisotropy of magnetic susceptibility parameters of ODP Hole 134-833B

Ocean Drilling Program (ODP) Sites 832 and 833 were drilled in the intra-arc North Aoba Basin of the New Hebrides Island Arc (Vanuatu). High volcanic influxes in the intra-arc basin sediment resulting from erosion of volcanic rocks from nearby islands and from volcanic activity are associated with characteristic magnetic signals. The high magnetic susceptibility in the sediment (varying on average from 0.005 to more than 0.03 SI) is one of the most characteristic physical properties of this sedimentary depositional environment because of the high concentration of magnetites in redeposited ash flows and in coarse-grained turbidites. Susceptibility data correlate well with the high resolution electrical resistivity logs recorded by the formation microscanner (FMS) tool. Unlike the standard geophysical logs, which have low vertical resolution and therefore smooth the record of the sedimentary process, the FMS and whole-core susceptibility data provide a clearer picture of turbiditic sediment deposition. Measurements of Curie temperatures and low-temperature susceptibility behavior indicate that the principal magnetic minerals in ash beds, silt, and volcanic sandstone are Ti-poor titanomagnetite, whereas Ti-rich titanomagnetites are found in the intrusive sills at the bottom of Site 833. Apart from an increase in the concentration of magnetite in the sandstone layer, acquisition of isothermal and anhysteretic remanences does not show significant differences between sandstone and clayey silts. The determination of the anisotropy of magnetic susceptibility (AMS) in more than 400 samples show that clayey siltstone have a magnetic anisotropy up to 15%, whereas the AMS is much reduced in sandstone layers. The magnetic susceptibility fabric is dominated by the foliation plane, which is coplanar to the bedding plane. Reorientations of the samples using characteristic remanent magnetizations indicate that the bedding planes dip about 10° toward the east, in agreement with results from FMS images. Basaltic sills drilled at Site 833 have high magnetic susceptibilities (0.05 to 0.1 SI) and strong remanent magnetizations. Magnetic field anomalies up to 50 µT were measured in the sills by the general purpose inclinometer tool (GPIT). The direction of the in-situ magnetic anomaly vectors, calculated from the GPIT, is oriented toward the southeast with shallow inclinations which suggests that the sill intruded during a reversed polarity period.

The physical properties of basalt at DSDP Hole 45-395A

A detailed study has been made of the physical properties of core samples from Deep Sea Drilling Project Hole 395A. The properties include: density, porosity, compressional and shear wave velocity, thermal conductivity, thermal diffusivity, and electrical resistivity. Of particular importance are the relations among the parameters. Most of the variations in the basalt properties follow the porosity, with smaller inferred dependence on pore structure, original mineralogy differences, and alteration. The sample measurements give very similar results to (and extend previous data from) Mid-Atlantic Ridge drillholes, the sample data from this site and previous data are used to estimate relations between porosity and other large-scale physical properties of the upper oceanic crust applicable to this area. These relations are important for the analysis and interpretation of downhole logging measurements and marine geophysical data.