Interstitial doping induced superconductivity at 15.3 K in Nb5Ge3 compound


Autoria(s): Bortolozo, Ausdinir Danilo; Santos, Carlos Alberto Moreira dos; Jardim, Renato de Figueiredo; Ritter, C.; Devishvili, A.; Rotter, M.; Gandra, F. G.; Machado, Antonio Jefferson da Silva
Contribuinte(s)

UNIVERSIDADE DE SÃO PAULO

Data(s)

06/11/2013

06/11/2013

2012

Resumo

It is reported superconductivity in Nb5Ge3C0.3, an interstitial carbide compound. The temperature dependence of the electrical resistivity, ac-susceptibility, and heat capacity (HC) indicate that a bulk type-II superconductivity appears at T-C - 15.3 K. Magneto-resistance measurements suggest an upper critical field of B-C2 similar to 10.6 T and a coherence length of xi similar to 55 angstrom at zero temperature. Neutron diffraction analyzes locate the carbon atoms at the interstitial 2b site of the Mn5Si3 type-structure. Heat capacity data below T-C are well described by BCS theory. The size of the jump at T-C is in good agreement with the superconducting volume fraction observed in susceptibility measurements. A Debye temperature and Sommerfeld constant were also extracted from heat capacity data as 343 K and 34 mJ/mol K-2, respectively. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4730611]

FAPESP

FAPESP [2004/13267-6, 2005/01257-1, 2009/142524-6, 2009/54001-2, 2009/00610-8]

CNPq [309084/2010-5]

CNPq

Identificador

JOURNAL OF APPLIED PHYSICS, MELVILLE, v. 111, n. 12, supl., Part 3, pp. 799-813, 42156, 2012

0021-8979

http://www.producao.usp.br/handle/BDPI/42348

10.1063/1.4730611

http://dx.doi.org/10.1063/1.4730611

Idioma(s)

eng

Publicador

AMER INST PHYSICS

MELVILLE

Relação

JOURNAL OF APPLIED PHYSICS

Direitos

restrictedAccess

Copyright AMER INST PHYSICS

Palavras-Chave #RESISTIVITY #PHASE #TEMPERATURE #SATURATION #METALS #SYSTEM #NBGE2 #HEAT #PHYSICS, APPLIED
Tipo

article

original article

publishedVersion