First-principles study on electronic and structural properties of Cu(In/Ga)Se alloys for solar cells

Thin-film photovoltaic solar cells based on the Cu(In1−xGax)Se2 (CIGS) alloys have attracted more and more attention due to their large optical absorption coefficient, long term stability, low cost, and high efficiency. Modern theoretical studies of this material with first-principles calculations can provide accurate description of the electronic structure and yield results in close agreement with experimental values, but takes a large amount of calculation time. In this work, we use first-principles calculations based on the computationally affordable meta- generalized gradient approximation of the density-functional theory to investigate electronic and structural properties of the CIGS alloys. We report on the simulation of the lattice parameters and band gaps, as a function of chemical composition. The obtained results were found to be in a good agreement with the available experimental data.

Kraft recovery boilers – Principles and practice

This book was created as postgraduate lecture notes for Lappeenranta University of Technology's special course of steam power plants. But as with anything ever written the ideas shown have nurtured for a long time. Parts of these chapters have appeared elsewhere as individual papers or work documents. One of the most helpful episodes have been presentations and discussions during Pohto Operator training seminars. Input from those sessions can be seen in chapter firing. You who run recovery boilers, I salute you. The purpose of this text is to give the reader an overview of recovery boiler operation. Most parts of the recovery boiler operation are common to boilers burning other fuels. The furnace operation differs significantly from operation of other boiler furnaces. Oxygen rich atmosphere is needed to burn fuel efficiently. But the main function of recovery boiler is to reduce spent cooking chemicals. Reduction reactions happen best in oxygen deficient atmosphere. This dual, conflicting nature of recovery furnace makes understanding it so challenging. To understand the processes happening in the recovery furnace one must try to understand the detailed processes that might occur and their limitations. Therefore chapters on materials, corrosion and fouling have been added.

Modelling Energy Consumption of a Switch using Fuzzy-Rule Classifier

The energy consumption of IT equipments is becoming an issue of increasing importance. In particular, network equipments such as routers and switches are major contributors to the energy consumption of internet. Therefore it is important to understand how the relationship between input parameters such as bandwidth, number of active ports, traffic-load, hibernation-mode and their impact on energy consumption of a switch. In this paper, the energy consumption of a switch is analyzed in extensive experiments. A fuzzy rule-based model of energy consumption of a switch is proposed based on the result of experiments. The model can be used to predict the energy saving when deploying new switches by controlling the parameters to achieve desired energy consumption and subsequent performance. Furthermore, the model can also be used for further researches on energy saving techniques such as energy-efficient routing protocol, dynamic link shutdown, etc.

How Lean Six Sigma and Agile principles optimize ITIL-based processes

Imagine the potential implications of an organization whose business and IT processes are well aligned and are capable of reactively and proactively responding to the external and internal changes. The Philips IT Infrastructure and Operations department (I&O) is undergoing a series of transformation activities to help Philips business keeping up with the changes. I&O would serve a critical function in any business sectors; given that the I&O’s strategy switched from “design, build and run” to “specify, acquire and performance manage”, that function is amplified. In 2013, I&O’s biggest transforming programme I&O Futures engaged multiple interdisciplinary departments and programs on decommissioning legacy processes and restructuring new processes with respect to the Information Technology Internet Library (ITIL), helping I&O to achieve a common infrastructure and operating platform (CI&OP). The author joined I&O Futures in the early 2014 and contributed to the CI&OP release 1, during which a designed model Bing Box and its evaluations were conducted through the lens of six sigma’s structured define-measure-analyze-improve-control (DMAIC) improvement approach. This Bing Box model was intended to firstly combine business and IT principles, namely Lean IT, Agile, ITIL best practices, and Aspect-oriented programming (AOP) into a framework. Secondly, the author implemented the modularized optimization cycles according to the defined framework into Philips’ ITIL-based processes and, subsequently, to enhance business process performance as well as to increase efficiency of the optimization cycles. The unique of this thesis is that the Bing Box model not only provided comprehensive optimization approaches and principles for business process performance, but also integrated and standardized optimization modules for the optimization process itself. The research followed a design research guideline that seek to extend the boundaries of human and organizational capabilities by creating new and innovative artifacts. The Chapter 2 firstly reviewed the current research on Lean Six Sigma, Agile, AOP and ITIL, aiming at identifying the broad conceptual bases for this study. In Chapter 3, we included the process of constructing the Bing Box model. The Chapter 4 described the adoption of Bing Box model: two-implementation case validated by stakeholders through observations and interviews. Chapter 5 contained the concluding remarks, the limitation of this research work and the future research areas. Chapter 6 provided the references used in this thesis.

Tulevaisuuden lähtökohdista kansanvallan kolmiliittoon. Kansallinen Edistyspuolue ja kansallisen eheytymisen politiikka 1919–1939.

Kansallista Edistyspuoluetta ja sen toimijoita maailmansotien välisen Suomen sisäpolitiikassa tarkasteleva väitöstutkimus paneutuu puolueen kansallista eheytymistä ajaneen poliittisen linjan taustoihin, muodostumiseen ja toteutumiseen maailmansotien välisenä aikana vuosina 1919-1939. Vahvasti aineistopohjainen ja lähdekriittinen poliittisen historian tutkimus keskittyy parlamentaarisiin toimijoihin, poliittiseen kenttään ja näiden tuottamiin aineistoihin, kuten edistyspuolueen ja sen toimijoiden arkistoihin, lehdistöön ja valtiopäiväpöytäkirjoihin. Tutkimus selvittää, millainen oli edistyspuolueen kansallisen eheytymisen linja, mihin sillä pyrittiin, miten sitä toteutettiin ja miten se toteutui. Kansainvälisen vertailun kautta tutkimuksessa luodaan myös kuva suomalaisesta liberalismista ja liberalistista. Joulukuussa 1918 perustettu Kansallinen Edistyspuolue oli liberaali puolue, jonka politiikassa korostui erityisesti liberalismin sosiaalinen tulkinta. Puolueen sisäpoliittiseksi linjaksi vastaitsenäistyneessä ja sisällissodan runtelemassa valtiossa muodostui kansallisen eheytymisen edistäminen. Ajatuksen taustalla olivat K. J. Ståhlbergin tulevaisuuden lähtökohtia hahmotelleet artikkelit, jotka julkaistiin Helsingin Sanomissa huhtikuussa 1918 sisällissodan vielä riehuessa. Ståhlbergin mukaan kansalliseen eheytymiseen ei tullut pyrkiä sodan vuoksi vaan siitä huolimatta. Nuorsuomalaiselta puolueelta perityt liberaalit periaatteet täydentyivätkin edistyspuoluelaisessa ajattelussa sisällissodan ja tasavallan puolesta käydyn valtiomuototaistelun avainkokemuksilla. Itsenäisen Suomen ensimmäisiä vuosia hallinneissa keskustahallituksissa kansallista eheytymistä edistettiin sosiaalipoliittisin uudistuksin mm. oppivelvollisuus- ja asutuslakien muodossa. Myös sisällissodan vankien armahdukset olivat osa tätä ohjelmaa. Tutkimus osoittaa, että edistyspuolueen kansallisen eheytymisen politiikan keskeisenä tavoitteena oli poliittisen sovittelun kautta integroida vasemmisto osaksi parlamentaaris-demokraattista järjestelmää. Eheytyspolitiikan todellinen käyttöarvo ja edistyspuolueen poliittiset toimintamahdollisuudet alkoivat kuitenkin heiketä vuoden 1922 eduskuntavaalien jälkeen.Tutkimuksesta käy ilmi, että toteutettu eheytyspolitiikka ja sen osittainen epäonnistuminen näkyivät sekä kommunistien jatkuvana kannatuksena että sisäpoliittisen ilmapiirin oikeistolaistumisena. Tämä kehitys nosti myös edistyspuolueessa esille voimat, jotka suosivat porvariyhteistyötä ohi keskustavasemmistolaisen eheytyspoliittisen linjan. Alkuvuosien jälkeen valtiomuototaistelun koossapitävä voima heikkeni edistyspuolueen sisällä ja 1920-luvun puolivälissä käydyt linjakiistat osoittivat, että osalle puolueen jäsenistä vuoden 1918 puoluevalinnassa keskeisemmässä roolissa oli ollut tasavaltalaisuus kuin vasemmiston integrointi ja kansallinen eheytyminen. Edistyspuolueen johto ei kuitenkaan ollut valmis luopumaan eheytyspoliittisesta linjasta ja sen ympärille luodusta puolueidentiteetistä, joten porvariyhteistyötä kannattanut oikeisto-oppositio päätyi suurelta osin eroamaan puolueesta vuonna 1927. Tutkimus osoittaa, että parlamentarismin rapautuminen ja pienelle yleispuolueelle elintärkeiden yhteistyömahdollisuuksien heikkeneminen luokkapuolueiden puristuksessa johtivat edistyspuolueen kannatuksen alamäkeen sotien välisenä aikana. Se kutistui 26 kansanedustajan keskisuuresta puolueesta vain kuuden edustajan pienpuolueeksi. Puolueidentiteetin vahvuus ja keskeisten toimijoiden puolueen kokoa suurempi poliittinen painoarvo pitivät sen lakkauttamispohdinnoista huolimatta kuitenkin koossa ja kiinni politiikan ytimessä. Oikeistoradikalismin vuodet 1920–1930-lukujen taitteessa olivat edistyspuolueellesekä uhka että mahdollisuus. Tutkimuksessa käy ilmi, että vaikka kommunisminvastaisen kansanliikkeen vaatimukset olivat edistyspuoluelaisten mielestä oikeutettuja, oli kansanliikkeen niiden ajamiseksi omaksumia laittomia ja ulkoparlamentaarisia keinoja vaikea hyväksyä. Eheytyspolitiikan kannalta katsottuna melkotoivottamalta näyttänyt tilanne kääntyi kuitenkin lopulta voitoksi: äärivasemmisto eliminoitiin, äärioikeisto ajautui paitsioon ja tie maltillisen vasemmiston ja keskustan yhteistyölle aukesi jälleen. Tämä johti lopulta vuonna 1937 punamultahallitukseen ja kansanvallan kolmiliittoon Kansallisen Edistyspuolueen, SDP:n ja Maalaisliiton kesken. Kokemus siitä, että itsenäisyys oli alati uhattuna, toi suomalaiseen liberalismiin varsin nationalistisia piirteitä, joita eurooppalaisten veljespuolueiden ohjelmista ei löydy. Liberalismiin usein liitetty mielleyhtymä sen kosmopoliittisesta, kansallisvaltioita ylittävästä luonteesta jäi Suomessa sotien välisenä aikana nationalismin ja itäisen naapurin luoman uhan varjoon. Suomen sisäpoliittinen tilanne ja geopoliittinen asema loivat vaatimuksen vahvasta kansallisesta yhtenäisyydestä. Suomalainen liberalismi määrittyikin eurooppalaisia vastineitaan voimakkaammin nuorta valtiota hallinneen kansallisuusajattelun, itsesäilytysvaiston ja kansallisen eheyden vaatimusten kautta. Tutkimuksessa todetaan, että edistyspuolueen eheytyspoliittisen linjan muotoutumista ja toteutumista vuosien 1919‒1939 aikana voi pitää idealismin voittona realismista. Lukuun ottamatta reformipolitiikan vuosia edistyspuolueen pitäytyminen valitulla linjalla näyttäytyi poliittisten toimintamahdollisuuksien kannalta katsottuna ajoittain jopa epärealistiselta. Koko sotien välistä aikaa tarkastellessa voikin todeta, että se, minkä edistyspuolue poliittisten päämäärien saavuttamisen valossa voitti, sen se menetti kannatusluvuissa.

Corruption, income, and rule of law: empirical evidence from developing and developed economies

This article presents an empirical analysis based on cross-country data concerned with two points regarding corruption: (i) its effects on income; and (ii) how to mitigate corruption. The findings can be highlighted in two points. Firstly the idea that corruption is intrinsically connected with income is confirmed. Secondly, the traditional argument that an increase in rule of law represents a good strategy in the fight against corruption is valid for developing countries. Furthermore, this study reveals that the search for increasing the human development index represents a rule of thumb for high levels of income and to control corruption.

In Search for the European solidarity: The rule of law within the European Union in the framework of constitutional pluralism

The dissertation examines the rule of law within the European Union in the theoretical framework of constitutional pluralism. The leading lines of constitutional pluralism are examined with relation to the traditional and prevailing, monistic and hierarchical conceptions on how to perceive legal orders in Europe. The theoretical part offers also historical perspective by highlighting some of the turning points for the Union constitutional legal order in the framework of European integration. The concept of rule of law is examined in legal terms and its meaning to the Union constitutional constellation as a constitutional principle and a common value is observed. The realization of the rule of law at supranational and national level is explored with a view to discover that recent developments in some of the Member States give rise to concern about the viability of the rule of law within the European Union. It is recognized that the inobservance of the rule of law at national level causes a threat to the supranational constitutional legal order. The relationship between the supranational and national legal orders is significant in this respect and therefore particularly the interaction between the Court of Justice of the European Union (hereinafter the ECJ) and the Member States’ (constitutional/supreme) courts takes focus. It is observed that functioning dialogue between the supranational and national courts based on mutual respect and judicial deference is an important prerequisite for the realization of the rule of law within Europe. In order to afford a concrete example, a recent case C-62/14 Gauweiler v Deutscher Bundestag is introduced and analysed in relation to the notorious relationship between the Federal Constitutional Court of Germany and the ECJ. The implications of the ECJ’s decision in Gauweiler v Deutscher Bundestag is assessed with reference to some of the pressing issues of constitutionalism within Europe and some institutional aspects are also brought forward. Lastly, the feasibility of constitutional pluralism as a theoretical setting is measured against the legal reality of today’s Europe and its many constitutions. The hierarchical idea of one ultimate source of power, stemming from the traditional approaches to legal systems, is then assessed with relation to the requirement of the realization of the rule of law within the European Union from the supranational and national point of view.

Brigadier-général [Dayrell Talbot] Hammond, un des membres influents de la ligue Home Rule arrive à la conférence de Dublin : [photographie de presse] / [Agence Rol]

Référence bibliographique : Rol, 60754

Implicit and explicit functions in the acquisition of a phonics rule in the word recognition of learning disabled and non learning disabled students /

One group of 12 non learning disabled students and two groups of 12 learning disabled students between the ges of 10 and 12 were measured on implicit and explicit knowledge cquisition. Students in each group implicitly cquired knowledge bout I of 2 vocabulary rules. The vocabulary rules governed the pronunciation of 2 types of pseudowords. After completing the implicit acquisition phase, all groups were administered a test of implicit knowledge. The non learning disabled group and I learning disabled group were then asked to verbalize the knowledge acquired during the initial phase. This was a test of explicit knowledge. All 3 groups were then given a postlest of implicit knowledge. This tcst was a measure of the effectiveness of the employment of the verbalization technique. Results indicate that implicit knowledge capabilities for both the learning disabled and non learning disabled groups were intact. However. there were significant differences between groups on explicit knowledge capabilities. This led to the conclusion that implicit functions show little individual differences, and that explicit functions are affected by ability difference. Furthermore, the employment of the verbalization technique significantly increased POStlest scores for learning disabled students. This suggested that the use of metacognitive techniques was a beneficial learning tool for learning disabled students.

Developing and nurturing professional learning communities: principles used by elementary administrators /

This study examined the strategies used by elementary school principals to facilitate and nurture the development of professional learning communities (PLC) within their school settings. Using a reputational sample of administrators whose schools were demonstrating observable characteristics of PLCs, this study documented and described the strategies and actions taken by the principals to move their schools forward. Data collection included the use of open-ended interviews as well as observations capturing the means by which the principals addressed the areas of culture, processes, and structures within their school setting. A grounded theory approach to data analysis uncovered 4 guiding principles used by the principals to facilitate the development of the PLCs within their school: (a) protecting the purpose; (b) attending to relationships; (c) sharing the responsibility; and (d) valuing the journey. The guiding principles were used by each administrator to anchor the decisions they made and develop responsive, contextspecific strategies to support the PLC at their school. The results highlighted the complex role of the principal and the supports required to tackle the difficult work of facilitating PLCs.

Principles and proceedings of the inhabitants of the District of Niagara for addressing His Royal Highness the Prince Regent, respecting claims of sufferers in war, lands to militiamen and the general benefit of Upper Canada. --

Cover title.

Sermon : the question of war with Great Britain, examined upon moral and Christian principles /

Joseph Dana was also considered as the supposed author.

The role of intrapartum intravenous therapy and method of delivery on newborn weight loss : challenging the 7% rule

It is common practice to initiate supplemental feeding in newborns if body weight decreases by 7-10% in the first few days after birth (7-10% rule). Standard hospital procedure is to initiate intravenous therapy once a woman is admitted to give birth. However, little is known about the relationship between intrapartum intravenous therapy and the amount of weight loss in the newborn. The present research was undertaken in order to determine what factors contribute to weight loss in a newborn, and to examine the relationship between the practice of intravenous intrapartum therapy and the extent of weight loss post-birth. Using a cross-sectional design with a systematic random sample of 100 mother-baby dyads, we examined properties of delivery that have the potential to impact weight loss in the newborn, including method of delivery, parity, duration of labour, volume of intravenous therapy, feeding method, and birth attendant. This study indicated that the volume of intravenous therapy and method of delivery are significant predictors of weight loss in the newborn (R2=15.5, p<0.01). ROC curve analysis identified an intravenous volume cut-point of 1225 ml that would elicit a high measure of sensitivity (91.3%), and demonstrated significant Kappa agreement (p<0.01) with excess newborn weight loss. It was concluded that infusion of intravenous therapy and natural birth delivery are discriminant factors that influence excess weight loss in newborn infants. Acknowledgement of these factors should be considered in clinical practice.