Heterogeneous labour and the determination of value

Heterogeneity of labour and its implications for the Marxian theory of value has been one of the most controversial issues in the literature of the Marxist political economy. The adoption of Marx's conjecture about a uniform rate of surplus value leads to a simultaneous determination of the values of common and labour commodities of different types and the uniform rate of surplus value. Determination of these variables can be formally represented as a parametric cigenvalue problem. Morishima's and Bródy's earlier results are analysed and given new interpretations in the light of the suggested procedure. The main questions are addressed in a more general context too. The analysis is extended to the problem of segmented labour market, as well.

A high-resolution sedimentology and age determination of core PS2185 from the central Arctic Ocean

A high-resolution multiparameter stratigraphy allows the identification of late Quaternary glacial and interglacial cycles in a central Arctic Ocean sediment core. Distinct sandy layers in the upper part of the otherwise fine-grained sediment core from the Lomonosov Ridge (lat 87.5°N) correlate to four major glacials since ca. 0.7 Ma. The composition of these ice-rafted terrigenous sediments points to a glaciated northern Siberia as the main source. In contrast, lithic carbonates derived from North America are also present in older sediments and indicate a northern North American glaciation since at least 2.8 Ma. We conclude that large-scale northern Siberian glaciation began much later than other Northern Hemisphere ice sheets.

Stable oxygen isotope record and age determination of benthic foraminiferal faunas of the Norwegian-Greenland Sea

Fluctuations in benthic foraminiferal faunas over the last 130,000 yr in four piston cores from the Norwegian Sea are correlated with the standard worldwide oxygen-isotope stratigraphy. One species, Cibicides wuellerstorfi, dominates in the Holocene section of each core, but alternates downcore with Oridorsalis tener, a species dominant today only in the deepest part of the basin. O. tener is the most abundant species throughout the entire basin during periods of particularly cold climate when the Norwegian Sea presumably was ice covered year round and surface productivity lowered. Portions of isotope Stages 6, 3, and 2 are barren of benthic foraminifera; this is probably due to lowered benthic productivity, perhaps combined with dilution by ice-rafted sediment; there is no evidence that the Norwegian Sea became azoic. The Holocene and Substage 5e (the last interglacial) are similar faunally. This similarity, combined with other evidence, supports the presumption that the Norwegian Sea was a source of dense overflows into the North Atlantic during Substage 5e as it is today. Oxygen-isotope analyses of benthic foraminifera indicate that Norwegian Sea bottom waters warmer than they are today from Substage 5d to Stage 2, with the possible exception of Substage 5a. These data show that the glacial Norwegian Sea was not a sink for dense surface water, as it is now, and thus it was not a source of deep-water overflows. The benthic foraminiferal populations of the deep Norwegian Sea seem at least as responsive to near-surface conditions, such as sea-ice cover, as they are to fluctuations in the hydrography of the deep water. Benthic foraminiferal evidence from the Norwegian Sea is insufficient in itself to establish whether or not the basin was a source of overflows into the North Atlantic at any time between the Substage 5e/5d boundary at 115,000 yr B.P. and the Holocene.

(Table 1) Composition of bottom sediments from the East Pacific

Adsorption of ion, nickel, cobalt, and manganese from ocean water by calcareous sediments, diatomaceous ooze, hydrogenous sediments, and red clay was studied under close to natural conditions using a tracer method. It was found that hydrogenous sediments selectively remove manganese from seawater. This may be associated with formation of chemical compounds between manganese and sediment material. It was also found that nickel, manganese, and iron exist in the ocean in several ionic and neutral forms. Cobalt typically present in only one ionic form Co(2+).

Physical properties and age determination of sediment cores from the Hinlopen/Yermak Megaslide north of Spitsbergen, Arctic Ocean

Integrated interpretation of multi-beam bathymetric, sediment-penetrating acoustic (PARASOUND) and seismic data show a multiple slope failure on the northern European continental margin, north of Spitsbergen. The first slide event occurred during MIS 3 around 30 cal. ka BP and was characterised by highly dynamic and rapid evacuation of ca. 1250 km**3 of sediment from the lower to the upper part of the continental slope. During this event, headwalls up to 1600 m high were created and ca. 1150 km**3 material from hemi-pelagic sediments and from the lower pre-existing trough mouth fan has been entrained and transported into the semi-enclosed Sophia Basin. This megaslide event was followed by a secondary evacuation of material to the Nansen Basin by funnelling of the debris through the channel between Polarstern Seamount and the adjacent continental slope. The main slide debris is overlain by a set of fining-upward sequences as evidence for the associated suspension cloud and following minor failure events. Subsequent adjustment of the eastern headwalls led to failure of rather soft sediments and creation of smaller debris flows that followed the main slide surficial topography. Discharge of the Hinlopen ice stream during the Last Glacial Maximum and the following deglaciation draped the central headwalls and created a fan deposit of glacigenic debris flows.

Pollen profile and age determination for sediment core M72/5_619-1 (22-GC3)

Sediments from the Black Sea, a region historically dominated by forests and steppe landscapes, are a valuable source of detailed information on the changes in regional terrestrial and aquatic environments at decadal to millennial scales. Here we present multi-proxy environmental records (pollen, dinoflagellate cysts, Ca, Ti and oxygen isotope data) from the uppermost 305 cm of the core 22-GC3 (42°13.53' N, 36°29.55' E) collected from a water depth of 838 m in the southern part of the Black Sea in 2007. The records span the last ~ 18 kyr (all ages are given in cal kyr BP). The pollen data reveal the dominance of the Artemisia-steppe in the region, suggesting rather dry/cold environments ~ 18-14.5 kyr BP. Warming/humidity increase during melt-water pulses (~ 16.1-14.5 kyr BP), indicated by d18O records from the 22-GC3 core sediment and from the Sofular Cave stalagmite, is expressed in more negative d13C values from the Sofular Cave, usually interpreted as the spreading of C3 plants. The records representing the interstadial complex (~ 14.5-12.9 kyr BP) show an increase in temperature and moisture, indicated by forest development, increased primary productivity and reduced surface run-off, whereas the switch from primary terrigenous to primary authigenic Ca origin occurs ~ 500 yr later. The Younger Dryas cooling is clearly demonstrated by more negative d13C values from the Sofular Cave and a reduction of pines. The early Holocene (11.7-8.5 kyr BP) interval reveals relatively dry conditions compared to the mostly moist and warm middle Holocene (8.5-5 kyr BP), which is characterized by the establishment of the species-rich warm mixed and temperate deciduous forests in the low elevation belt, temperate deciduous beech-hornbeam forests in the middle and cool conifer forest in upper mountain belt. The border between the early and middle Holocene in the vegetation records coincides with the opening of the Mediterranean corridor at ~ 8.3 kyr BP, as indicated by a marked change in the dinocyst assemblages and in the sediment lithology. Changes in the pollen assemblages indicate a reduction in forest cover after ~ 5 kyr BP, which was likely caused by increased anthropogenic pressure on the regional vegetation.

Kinetic modeling of molecular motors: pause model and parameter determination from single-molecule experiments

Single-molecule manipulation experiments of molecular motors provide essential information about the rate and conformational changes of the steps of the reaction located along the manipulation coordinate. This information is not always sufficient to define a particular kinetic cycle. Recent single-molecule experiments with optical tweezers showed that the DNA unwinding activity of a Phi29 DNA polymerase mutant presents a complex pause behavior, which includes short and long pauses. Here we show that different kinetic models, considering different connections between the active and the pause states, can explain the experimental pause behavior. Both the two independent pause model and the two connected pause model are able to describe the pause behavior of a mutated Phi29 DNA polymerase observed in an optical tweezers single-molecule experiment. For the two independent pause model all parameters are fixed by the observed data, while for the more general two connected pause model there is a range of values of the parameters compatible with the observed data (which can be expressed in terms of two of the rates and their force dependencies). This general model includes models with indirect entry and exit to the long-pause state, and also models with cycling in both directions. Additionally, assuming that detailed balance is verified, which forbids cycling, this reduces the ranges of the values of the parameters (which can then be expressed in terms of one rate and its force dependency). The resulting model interpolates between the independent pause model and the indirect entry and exit to the long-pause state model

Pollen record and age determination of profile CS98-10 at Cape Shpindler, Yugorski Peninsula, northwest Russia

New pollen and radiocarbon data from an 8.6-m coastal section, Cape Shpindler (69°43' N; 62°48' E), Yugorski Peninsula, document the latest Pleistocene and Holocene environmental history of this low Arctic region. Twelve AMS 14C dates indicate that the deposits accumulated since about 13,000 until 2000 radiocarbon years BP. A thermokarst lake formed ca. 13,000-12,800 years BP, when scarce arctic tundra vegetation dominated the area. By 12,500 years BP, a shallow lake existed at the site, and Arctic tundra with Poaceae, Cyperaceae, Salix, Saxifraga, and Artemisia dominated nearby vegetation. Climate was colder than today. Betula nana became dominant during the Early Preboreal period about 9500 years BP, responding to a warm event, which was one of the warmest during the Holocene. Decline in B. nana and Salix after 9500 years BP reflects a brief event of Preboreal cooling. A subsequent increase in Betula and Alnus fruticosa pollen percentages reflects amelioration of environmental conditions at the end of Preboreal period (ca. 9300 years BP). A decline in arboreal taxa later, with a dramatic increase in herb taxa, reflects a short cold event at about 9200 years BP. The pollen data reflect a northward movement of tree birch, peaking at the middle Boreal period, around 8500 years BP. Open Betula forest existed on the Kara Sea coast of the Yugorski Peninsula during the Atlantic period (8000-4500 years BP), indicating that climate was significantly warmer than today. Deteriorating climate around the Atlantic-Subboreal boundary (ca. 4500 years BP) is recorded by a decline in Betula percentages. Sedimentation slowed at the site, and processes of denudation and/or soil formation started at the beginning of the Subatlantic period, when vegetation cover on Yugorski Peninsula shifted to near-modern assemblages.

Stable isotope record, foraminifera and susceptibility determination of sediment core ENAM93-21

A high-resolution piston core, ENAM93-21, from a water depth of 1020 m near the Faeroe-Shetland Channel is investigated for variations in magnetic susceptibility, surface oxygen isotopes, grain size distribution, content of ice-rafted detritus (IRD), and distribution of planktonic and benthic foraminifera. The core, covering the last 58,000 years, is correlated with the Greenland ice cores and compared with paleorecords from the Norwegian Sea and the North Atlantic Ocean. All fifteen Dansgaard-Oeschger climatic cycles recognized from the investigated time period in the Greenland ice cores have been identified in the ENAM93-21 core. Each cycle is subdivided into three intervals on the basis of characteristic benthic and planktonic faunas. Interstadial intervals contain a relatively warm planktonic fauna and a benthic fauna similar to the modern fauna in the Norwegian Sea. This indicates thermohaline convection as at present, with a significant contribution of deep water to the North Atlantic Deep Water (NADW). Transitional cooling intervals are characterized by more cold water planktonic foraminfera and ice-related benthic species. The benthic fauna signifies restricted bottom water conditions and a reduced contribution to the NADW. The peak abundance of N. pachyderma (s.) and the coldest surface water conditions are found in the stadial intervals. The benthic fauna is dominated by species with an association to Atlantic Intermediate Water, suggesting an increased Atlantic influence in the Norwegian Sea, and there was probably no contribution to the NADW through the Faeroe-Shetland Channel. The three different modes of circulation can be correlated to paleoceanographic events in the Norwegian Sea and the North Atlantic Ocean.

Isolation and structural determination of non-racemic tertiary cathinone derivatives

The racemic tertiary cathinones N,N-dimethylcathinone (1), N,N-diethylcathinone (2) and 2-(1-pyrrolidinyl)-propiophenone (3) have been prepared in reasonable yield and characterized using NMR and mass spectroscopy. HPLC indicates that these compounds are isolated as the anticipated racemic mixture. These can then be co-crystallized with (+)-O,O′-di-p-toluoyl-d-tartaric, (+)-O,O′-dibenzoyl-d-tartaric and (-)-O,O′-dibenzoyl-l-tartaric acids giving the single enantiomers S and R respectively of 1, 2 and 3, in the presence of sodium hydroxide through a dynamic kinetic resolution. X-ray structural determination confirmed the enantioselectivity. The free amines could be obtained following basification and extraction. In methanol these are reasonably stable for the period of several hours, and their identity was confirmed by HPLC and CD spectroscopy.

Characterization and age determination of Quaternary volcanism in the southern Ankaratra region (central Madagascar) through novel approaches in luminescence dating

This work introduces two novel approaches for the application of luminescence dating techniques to Quaternary volcanic eruptions: crystalline xenoliths from lava flows are demonstrated to be basically suitable for luminescence dating, and a set of phreatic explosion deposits from the Late Quaternary Vakinankaratra volcanic field in central Madagascar is successfully dated with infrared stimulated luminescence (IRSL). Using a numerical model approach and experimental verification, the potential for thermal resetting of luminescence signals of xenoliths in lava flows is demonstrated. As microdosimetry is an important aspect when using sample material extracted from crystalline whole rocks, autoradiography using image plates is introduced to the field of luminescence dating as a method for detection and assessment of spatially resolved radiation inhomogeneities. Determinations of fading rates of feldspar samples have been observed to result in aberrant g-values if the pause between preheat and measurement in the delayed measurements was kept short. A systematic investigation reveals that the phenomenon is caused by the presence of three signal components with differing individual fading behaviour. As this is restricted to short pauses, it is possible to determine a minimal required delay between preheating and measurement after which the aberrant behaviour disappears. This is applied in the measuring of 12 samples from phreatic explosion deposits from the Antsirabe – Betafo region in the Late Quaternary Vakinankaratra volcanic field. The samples were taken from stratigraphically correlatable sections and appear to represent at least three phreatic events, one of which created the Lac Andraikiba maar near Antsirabe. The obtained ages indicate that the eruptive activity in the region started in the Late Pleistocene between 113.9 and 99.6 ka. A second layer in the Betafo area is dated at approximately 73 ka and the Lac Andraikiba deposits give an age between 63.9 and 50.7 ka. The youngest phreatic layer is dated between 33.7 and 20.7 ka. These ages are the first recorded direct ages of such volcanic deposits, as well as the first and only direct ages for the Late Quaternary volcanism in the Vakinankaratra volcanic field. This illustrates the huge potential of this new method for volcanology and geochronology, as it enables direct numerical dating of a type of volcanic deposit which has not been successfully directly dated by any other method so far.

Removal of BrO3 − from drinking water samples using newly developed agricultural waste-based activated carbon and its determination by ultra-performance liquid chromatography-mass spectrometry

Activated carbon was prepared from date pits via chemical activation with H3PO4. The effects of activating agent concentration and activation temperature on the yield and surface area were studied. The optimal activated carbon was prepared at 450 °C using 55 % H3PO4. The prepared activated carbon was characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, thermogravimetric-differential thermal analysis, and Brunauer, Emmett, and Teller (BET) surface area. The prepared date pit-based activated carbon (DAC) was used for the removal of bromate (BrO3 −). The concentration of BrO3 − was determined by ultra-performance liquid chromatography-mass tandem spectrometry (UPLC-MS/MS). The experimental equilibrium data for BrO3 − adsorption onto DAC was well fitted to the Langmuir isotherm model and showed maximum monolayer adsorption capacity of 25.64 mg g−1. The adsorption kinetics of BrO3 − adsorption was very well represented by the pseudo-first-order equation. The analytical application of DAC for the analysis of real water samples was studied with very promising results.