937 resultados para Star polymers
Resumo:
En este trabajo se estudia el comportamiento de los retornos de los tres principales índices bursátiles de Colombia: el IBB de la Bolsa de Bogotá, el IBOMED de la Bolsa de Medellin, y el IGBC de Bolsa de Valores de Colombia. A través de un modelo STAR GARCH se identifican dos estados o regiones extremos; mientras en el primero los rendimientos de los índices son, en términos absolutos, bajos y los procesos son estacionarios, en el segundo se tienen grandes pérdidas o ganancias, donde los efectos de los choques son permanentes. Aunque en cada uno de los regímenes el efecto del día de la semana es diferente, los resultados indican que para los tres índices existe un efecto del día de la semana en la media, y un efecto del día en la varianza para la Bolsa de Bogotá y Bolsa de Valores de Colombia. Los resultados contradicen la hipótesis de un mercado de acciones efciente en información.
Resumo:
Laura siempre ha querido tener alguien especial para compartir sus secretos. Una noche se encuentra una estrella rota en la acera. Toma la estrella en su mano,la lleva a su habitación, la remienda, y la coloca sobre su almohada. Le cuenta a la estrella todos sus secretos, pero cuando despierta a la mañana siguiente, la estrella ha desaparecido.
Resumo:
Dibújame una estrella, y el artista dibujó una estrella. Dibújame el sol, dijo la estrella, y el artista dibuja el sol. Cada objeto dibujado pide que le dibujen otro objeto y así comienza la creación de todo un universo. Para introducir actividades creativas en la primera infancia .y conceptos como arriba, abajo, derecha e izquierda.
Resumo:
Historia de una niña haciendo lo mejor que puede en un implacable mundo donde las cosas nunca son realmente como deberían ser. Elsa y su familia vivían en una hermosa casa, pero su padrastro perdió su puesto de trabajo y ahora viven en una habitación familiar en el Royal Hotel. Lo que significa que ella, mamá, Mack, y su hermana pequeña Pippa y Hank están abarrotados en la habitación y esto realmente llega a atacar los nervios. Ella cuenta chistes y hace bromas todo el tiempo, para intentar hacer reír a la gente, aunque no siempre es fácil. Pero cuando ocurre un desastre en el hotel, Elsa tiene la oportunidad de ser una verdadera estrella. Para ocho a diez años.
Resumo:
Monogr??fico con el t??tulo: "La Educaci??n Inclusiva: reflexiones y experiencias para la mejora escolar"
Resumo:
La question de la protection des données à caractère personnel posée dans le cadre des activités d’assistance et de soutien des missions civiles de gestion de crise ne semble guère avoir suscité l’intérêt des instances en charge de leur gestion et ce en dépit de son importance majeure au regard des tâches exécutées quotidiennement par les agents de ces missions dans le domaine de la coopération policière et judiciaire en matière pénale. S’appuyant sur une expérience de terrain, l’auteur s’efforcera, dans ces lignes, de démontrer la nécessité d’entamer une réflexion de fond sur ce sujet afin, le cas échéant, de prendre les initiatives utiles destinées à porter remède aux difficultés qui, en ce domaine, pourraient apparaître.
Resumo:
The linear viscoelastic (LVE) spectrum is one of the primary fingerprints of polymer solutions and melts, carrying information about most relaxation processes in the system. Many single chain theories and models start with predicting the LVE spectrum to validate their assumptions. However, until now, no reliable linear stress relaxation data were available from simulations of multichain systems. In this work, we propose a new efficient way to calculate a wide variety of correlation functions and mean-square displacements during simulations without significant additional CPU cost. Using this method, we calculate stress−stress autocorrelation functions for a simple bead−spring model of polymer melt for a wide range of chain lengths, densities, temperatures, and chain stiffnesses. The obtained stress−stress autocorrelation functions were compared with the single chain slip−spring model in order to obtain entanglement related parameters, such as the plateau modulus or the molecular weight between entanglements. Then, the dependence of the plateau modulus on the packing length is discussed. We have also identified three different contributions to the stress relaxation: bond length relaxation, colloidal and polymeric. Their dependence on the density and the temperature is demonstrated for short unentangled systems without inertia.
Resumo:
We demonstrate that it is possible to link multi-chain molecular dynamics simulations with the tube model using a single chain slip-links model as a bridge. This hierarchical approach allows significant speed up of simulations, permitting us to span the time scales relevant for a comparison with the tube theory. Fitting the mean-square displacement of individual monomers in molecular dynamics simulations with the slip-spring model, we show that it is possible to predict the stress relaxation. Then, we analyze the stress relaxation from slip-spring simulations in the framework of the tube theory. In the absence of constraint release, we establish that the relaxation modulus can be decomposed as the sum of contributions from fast and longitudinal Rouse modes, and tube survival. Finally, we discuss some open questions regarding possible future directions that could be profitable in rendering the tube model quantitative, even for mildly entangled polymers
Resumo:
The mechanisms underlying the increase in stress for large mechanical strains of a polymer glass, quantified by the strain-hardening modulus, are still poorly understood. In the present paper we aim to elucidate this matter and present new mechanisms. Molecular-dynamics simulations of two polymers with very different strain-hardening moduli (polycarbonate and polystyrene) have been carried out. Nonaffine displacements occur because of steric hindrances and connectivity constraints. We argue that it is not necessary to introduce the concept of entanglements to understand strain hardening, but that hardening is rather coupled with the increase in the rate of nonaffine particle displacements. This rate increases faster for polycarbonate, which has the higher strain-hardening modulus. Also more nonaffine chain stretching is present for polycarbonate. It is shown that the inner distances of such a nonaffinely deformed chain can be well described by the inner distances of the worm-like chain, but with an effective stiffness length (equal to the Kuhn length for an infinite worm-like chain) that increases during deformation. It originates from the finite extensibility of the chain. In this way the increase in nonaffine particle displacement can be understood as resulting from an increase in the effective stiffness length of the perturbed chain during deformation, so that at larger strains a higher rate of plastic events in terms of nonaffine displacement is necessary, causing in turn the observed strain hardening in polymer glasses.
Resumo:
For the well-known early Mesolithic site of Star Carr, dating of organic artefacts by accelerator mass spectrometry (AMS) has been hampered by treatment of bone and antler recovered during the original excavations with preservatives. Some, untreated, artefacts were, however, collected after Clark's excavation in 1950. Four of these artefacts were AMS dated in 1995, but two of the dates were significantly younger than the others, and were questionable due to their low collagen yields. These suspect samples have now been re-analysed, demonstrating that all four artefacts are of similar date. The significance of these dates for the chronology of Star Carr is discussed.