Physical properties, mineral and chemical compositions, and accumulation rates of Holocene and Upper Pleistocene bottom sediments from the Sea of Okhotsk

Mineral and chemical compositions and physical properties of diatomaceous clayey-siliceous sediments from the Sea of Okhotsk are studied. Accumulation rates of silica are determined. Their compositional model based on silica content is similar to that of Late Jurassic and Olenekian-Middle Anisian cherts from the Sikhote Alin region. Thickness of Holocene siliceous unit and accumulation rates of siliceous deposits depended on bioproductivity in the upper water layer and seafloor topography. Accumulation rates of amorphous SiO2 (0.05-5.7 g/cm**2/ka) and free SiO2 (0.5-11.6 g/cm**2/ka) are minimal on seamounts and maximal in depressions near foothills. These values match accumulation rates of free SiO2 in Triassic and Late Jurassic basins of the Sikhote Alin region (0.33-3 g/cm**2/ka). Comparison of composition and accumulation rates of silica shows that Triassic and Late Jurassic siliceous sequences of Sikhote Alin could accumulate in a marginal marine basin near a continent.

Composition of bottom sediments, rocks, and ores from the Tropical Atlantic

Geological features of some areas of the Tropical Atlantic (stratigraphy, tectonic structure, lithology, distribution of ore components in bottom sediments, petrography of bedrocks, etc.) are under consideration in the book. Regularities of concentration of trace elements in iron-manganese nodules, features of these nodules in bottom sediments, distribution of phosphorite nodules and other phosphorites have been studied. Much attention is paid to rocks of the ocean crust. A wide range of mineralization represented by magnetite, chromite, chalcopyrite, pyrite, pentlandite, and other minerals has been found.

Chemical composition of rocks from the Eastern Indian Ocean

The monograph presents results of comprehensive geological and geophysical studies carried out in 1973 and 1976 during Cruises 54 and 58 of R/V "Vityaz" in the Eastern Indian Ocean. On the base of obtained data a description of topography, magnetic and gravity fields, structure of the sedimentary series and deep crustal structure of the East Indian Ridge, Central, West Australian and Cocos Basins, the Sunda Trench has been done. Materials on petrography, petrochemistry and geochemistry of igneous rocks in the region have been summarized. New geological and geophysical information has been compared with with DSDP materials. Tectonics and geological history of the Eastern Indian Ocean are under consideration.

Chemical composition of Fe-Mn nodule from Station PL70-9

During June-August 1970 geologic investigations were carried out to the west of the Cape Verde Islands. One result of these investigations was a discovery of a new region of distribution of iron-manganese nodules. Data on chemical analysis of the nodules and their morphometric characteristics are presented in this paper. The report is illustrated by bottom-relief profiles, underwater photographs, and tables.

Sulfur and iron speciations in bottom sediments from the southwest Caspian Sea

Speciations of sulfur (sulfide S, pyrite S, sulfate S) and of reactive iron (Fe3+, Fe2+, sulfide Fe) in bottom sediments have been studied in gravity cores and drill cores collected on the shelf of the southwest Caspian Sea. It has been shown that intensity of reduction processes, in particular sulfate reduction, as well as speciations of S and reactive Fe reflect the change of transgressive and regressive stages of the Caspian basin. Characteristic features for the investigated area are high sedimentation rate and high reactivity of organic matter entering bottom sediments.

Geochemical parameters of bottom sediments from the Stromboli Canyon

In recent sediments of the Stromboli Canyon sides features of mineral and grain size compositions, redox conditions, behavior of Fe, Mn, organic carbon, Mo, and W in an environment of active input of pyroclastic material are considered. Differences in conditions of sedimentation and early diagenesis in the east and west sides of the canyon depending on position of the prevailing direction of drift and steepness of the slopes, as well as types of differentiation of detrital material in sediments under conditions of permanent vibrations are specified.

Concentrations of organic compounds in suspended matter from surface waters and surface layer bottom sediments of the Obskay Guba (Ob River estuary) and the Kara Sea

Data are presented on concentrations of aliphatic and polycyclic aromatic hydrocarbons (AHC and PAH) in interstitial waters and bottom sediments of the Kara Sea compared to distribution of particulate matter and organic carbon. It was found that AHC concentrations within the water mass (aver. 16 µg/l) are mainly formed by natural processes. Distribution of AHC represents variability of hydrological and sedimentation processes in different regions of the sea. The widest ranges of the concentrations occurred in the Obskaya Guba - Kara Sea section: in water (10-310 µg/l for AHC and 0.4-7.2 ng/l for PAH) and in the surface layer of the bottom sediments (8-42 µg/l for AHC and 9-94 ng/g for PAH). Differentiation of hydrocarbons (HC) in different media follows regularities typical for marginal filters; therefore no oil and pyrogenic compounds are supplied to the open sea. In sediments contents of HC depend on variations in redox conditions in sediments and on their composition.

Geochemical and biogeochemical parameters of bottom sediments from the area of the Spitsbergen (Svalbard) Archipelago

Quantitative characteristics for rates of diagenetic processes in the upper (0-30 cm) layer of sedimentary deposits in the area of the Spitsbergen (Svalbard) Archipelago (78°-80°N) were obtained by lithologo-geochemical, radioisotope (35S, 14C), and stable isotope (d34S, d13C) studies. It was proved that rates of diagenetic processes in polar deposits at 123-395 m depth affected by the East Spitsbergen ''warm'' current are mostly determined by bioproductivity and are commensurate with rates of processes in shelf deposits of temperate latitudes. High contents of migratory methane (up to 263 ml/dm**3) and isotopically-light organic carbon (Corg, d13C = -30 per mil PDB) were found in the 1 m layer of shelf deposits (at 123 m sea depth) with low bacterial in situ production of methane. It was shown that methane is not utilized in the deposits by the methanotrophic bacterial community and it may be supplied to the water mass and, probably, to the atmosphere.

Chemical composition of waters, suspended matter, bottom sediments, and benthic organisms along a section from the Ob River estuary (Obskaya Guba) to the central Kara Sea

Biogeochemical behavior of a group of heavy metals and metalloids in water (including their dissolved and suspended particulate forms), bottom sediments, and zoobenthos was studied in the Ob River estuary (Obskaya Guba) - Kara Sea section on the basis of data obtained during Cruise 54 of R/V Akademik Mstislav Keldysh in September-October 2007. Changes in ratios of dissolved and particulate forms of Fe, Mn, Zn, Cu, Pb, Cd, and As were shown, as well as growth of adsorbed fractions of the elements in near-bottom suspended matter under mixing of riverine and marine waters. Features of chemical element accumulation in typical benthic organisms of the Obskaya Guba and the Kara Sea were revealed, and their concentrating factors were calculated based on specific conditions of the environment. It was shown that shells of bivalves possessing higher biomass compared to other groups of organisms in the Obskaya Guba play an important role in deposition of heavy metals. In the Obskaya Guba mollusks accumulate Cd and Pb at the background level, whereas Cu and Zn contents appear to be higher than the background level.