Efeito da Gália como aditivo de sinterização em eletrólitos cerâmicos à base de céria sintetizados pelo método de complexação de cátions

Fuel cells are considered one of the most promising ways of converting electrical energy due to its high yield and by using hydrogen (as fuel) which is considered one of the most important source of clean energy for the future. Rare earths doped ceria has been widely investigated as an alternative material for the electrolyte of solid oxide fuel cells (SOFCs) due to its high ionic conductivity at low operating temperatures compared with the traditional electrolytes based on stabilized zirconia. This work investigates the effect of gallium oxide (Gallia) as a sintering aid in Eu doped ceria ceramic electrolytes since this effect has already been investigated for Gd, Sm and Y doped ceria electrolytes. The desired goal with the use of a sintering aid is to reduce the sintering temperature aiming to produce dense ceramics. In this study we investigated the effects on densification, microstructure and ionic conduction caused by different molar fraction of the dopants europium (10, 15 and 20%) and gallium oxide (0.3, 0.6 and 0.9%) in samples sintered at 1300, 1350 and 1450 0 C. Samaria (10 and 20%) doped ceria samples sintered between 1350 and 1450 °C were used as reference. Samples were synthesized using the cation complexation method. The ceramics powders were characterized by XRF, XRD and SEM, while the sintered samples were investigated by its relative density, SEM and impedance spectroscopy. It was showed that gallia contents up to 0.6% act as excellent sintering aids in Eu doped ceria. Above this aid content, gallia addition does not promote significant increase in density of the ceramics. In Ga free samples the larger densification were accomplished with Eu 15% molar, effect expressed in the microstructure with higher grain growth although reduced and surrounded by many open pores. Relative densities greater than 95 % were obtained by sintering between 1300 and 1350 °C against the usual range 1500 - 1600 0 C. Samples containing 10% of Sm and 0.9% of Ga reached 96% of theoretical density by sintering at 1350 0 C for 3h, a gain compared to 97% achieved with 20% of Sm and 1% of Ga co-doped cerias sintered at 1450 0 C for 24 h as described in the literature. It is found that the addition of gallia in the Eu doped ceria has a positive effect on the grain conductivity and a negative one in the grain boundary conductivity resulting in a small decrease in the total conductivity which will not compromise its application as sintering aids in ceria based electrolytes. Typical total conductivity values at 600 and 700 °C, around 10 and 30 mS.cm -1 respectively were reached in this study. Samples with 15% of Eu and 0.9 % of Ga sintered at 1300 and 1350 °C showed relative densities greater than 96% and total conductivity (measured at 700 °C) between 20 and 33 mS.cm -1 . The simultaneous sintering of the electrolyte with the anode is one of the goals of research in materials for SOFCs. The results obtained in this study suggest that dense Eu and Ga co-doped ceria electrolytes with good ionic conductivity can be sintered simultaneously with the anode at temperatures below 1350 °C, the usual temperature for firing porous anode materials

Biological activity of astilbin from Dimorphandra mollis against Anticarsia gemmatalis and Spodoptera frugiperda

Astilbin was isolated in high yield from Dimorphandra mollis, and its insecticidal and growth inhibiting activity by stomach ingestion were evaluated against Anticarsia gemmatalis and Spodoptera frugiperda. The insecticidal activity of astilbin, the weight reduction of the larval phase and the prolongation of the larval and pupal phases were verified for both species. Astilbin was identified on the base of its NMR, MS and physical data. (C) 2002 Society of Chemical Industry.

Produtividade, eficiência agronômica, características nutricionais e tecnológicas do feijão adubado com nitrogênio em plantio direto e convencional

Altas produtividades do feijoeiro são obtidas sob condições tecnológicas adequadas, destacando-se o uso de sistemas de manejos de solo e a adubação nitrogenada, porém, há pouco conhecimento sobre tais técnicas culturais interferindo nas características nutricionais e tecnológicas de grãos. Desse modo, o trabalho teve como objetivo verificar a interferência da adubação nitrogenada em cobertura (0, 40, 80, 120 e 160 kg ha-1 de N) no feijoeiro, cultivar Pérola, cultivado no preparo convencional do solo e no plantio direto e suas relações com a produtividade, eficiência agronômica, características nutricionais e tecnológicas do grão. O delineamento experimental empregado foi o de blocos ao acaso em esquema de parcelas subdivididas, com quatro repetições, onde as parcelas foram constituídas pelos sistemas de manejo de solo e as subparcelas pelas doses de N em cobertura. A produtividade do feijoeiro é influenciada positivamente pela adubação nitrogenada em cobertura, com maior necessidade de fertilizante no plantio direto. A eficiência agronômica é superior no sistema de preparo convencional do solo. O aumento do teor de proteína bruta é em função das doses crescentes de N em cobertura nos sistemas de plantio direto e de preparo convencional do solo. O tempo para cozimento dos grãos é diminuido em função das doses de N empregadas no sistema de plantio direto em relação ao preparo convencional. Há aumento no tempo para a máxima hidratação dos grãos até a aplicação de 120 kg ha-1 de N no sistema de plantio direto e no preparo convencional do solo.

Quantitative and qualitative characteristics of the non-carcass components and the meat of lambs fed sunflower seeds and vitamin E

The objective of this investigation was to evaluate the weight and percentage of the non-carcass components and the mineral content (macro minerals and trace minerals), crude protein, ether extract, moisture and vitamin E of the heart, liver, tongue, lungs, reticulum, kidneys and meat from the longissimus dorsi of lambs in feedlot finishing. Thirty-two non-castrated Ile de France male lambs, fed diets containing sunflower seeds and vitamin E from 15 to 32 kg of body weight were allotted in a completely randomized design in a 2 × 2 factorial arrangement. The weight of the gastrointestinal tract was higher in the lambs fed diets containing vitamin E (10%). No difference was observed in the liver as to the mineral matter, crude protein, ether extract, moisture (2.01; 20.03; 2.39 and 74.78 g/100 g, respectively), the macro minerals and trace minerals, except iron. In the tongue, lungs, reticulum, kidneys and meat there was no in fluence of diets in the studied variables. The liver and the meat presented different values of crude protein (20.01 and 18.34 g/100 g, respectively), and the heart (1.03 mg/100 g) showed a higher content of vitamin E. High contents of manganese, zinc and copper were observed in the liver. The evaluated non-carcass components were nutritionally equal to the sheep meat, once, in addition to their high yield in relation to the body weight at slaughter, the non-carcass components are sources of nutrients.

Análise de crescimento do crisântemo de vaso, cultivar Puritan, irrigado em diferentes tensões de água em ambiente protegido

A irrigação é prática fundamental para o cultivo de crisântemo, porém seu manejo adequado tem sido negligenciado pelos produtores, resultando em prejuízos no crescimento vegetal e conseqüentes decréscimos na produtividade e na qualidade do produto final. Para melhorar a representatividade dos dados obtidos, o experimento foi desenvolvido na propriedade de um produtor tradicional, no Distrito de Holambra II, município de Paranapanema-SP (23º4'S e 49º00'W). O objetivo principal do trabalho foi identificar a tensão de água no substrato (potencial matricial) que resultasse em melhor crescimento e desenvolvimento do crisântemo em vaso, cultivar Puritan. Os tratamentos foram definidos por seis níveis de tensão de água no substrato: -2, -3, -4,- 6,-10 e -30 kPa. Conclui-se, que a melhor qualidade do crisântemo em vaso foi obtida nos potenciais de água no substrato de -2, -6 e -10 kPa e que a tensão de -30 kPa, embora tenha levado à redução na qualidade comercial do crisântemo, resultou em maior durabilidade pós- colheita.

Produção de pepino de plantas enxertadas cultivadas em soluções nutritivas com diferentes teores de potássio

O experimento foi conduzido em estufa tipo arco de 50 m² na Faculdade de Ciências Agronômicas da UNESP em Botucatu. Plantas de pepino (Cucumis sativus L.) não enxertadas e enxertadas em abóbora (Cucurbita sp.) foram cultivadas em sistema hidropônico para estudar o efeito de níveis de potássio (45; 90; 180 e 360 mg.L-1 de K) na altura da planta e produção de número de frutos/m². A condução das plantas foi em vasos de 28 L de capacidade contendo 20% vermiculita + 80% casca de arroz + solução nutritiva fornecida a partir de galões individuais contendo 20 litros de solução. O delineamento experimental foi blocos casualizados, com oito tratamentos (fatorial 4 x 2) e três repetições. Não houve efeito da enxertia e das doses de K sobre a altura da planta, porém, os níveis de potássio independente da enxertia alteraram o início da floração. A enxertia potencializou a produção aumentando em 39% o número de frutos/m² quando fornecido na solução nutritiva 45 mg.L-1 de K e 144% com 360 mg.L-1 de K. O menor teor de potássio, 45 mg.L-1, foi suficiente para atingir alta produção.

Adubação com boro em batata-doce: efeito das fontes, doses e modos de aplicação

Boron (B) fertilization can result in high yield and better sweet potato storage roots quality. However, there is few works about this subject. The objective was to evaluate the yield of sweet potato crops in response to B sources, rates and application form. The experimental design was complete randomized blocks, in factorial outline ((2x2x2)+1), with three replications, which resulted of the combination of sources of B (boric acid and borax), application form (via soil and via foliar) and doses of B (1 and 2 kg ha(-1)) and a control treatment (without B). There was no interaction between the factors studied for the commercial yield of sweet potato. No significant differences was found between B sources and application form, but they showed higher yield than the control treatment. Additionally, sweet potato yield increade with application of 2 kg ha(-1) of B.

Formação de particulas submicrometricas de pmma por cristalização termica de solução polimérica

Polymer particles in the nanometer range are of fundamental interest today, especially when used as carrier systems in the controlled release of drugs, cosmetics and nutraceuticals, as well as in coating materials with magnetic properties. The main objective of the present study concerns the production of submicron particles of poly (methyl methacrylate) (PMMA) by crystallization of a polymer solution by thermally controlled cooling. In this work, PMMA solutions in ethanol and 1-propanol were prepared at different concentrations (1% to 5% by weight) and crystallized at different cooling rates (0.2 to 0.8 ° C / min) controlled linearly. Analysis of particle size distribution (DLS / CILAS) and scanning electron microscopy (SEM) were performed in order to evaluate the morphological characteristics of the produced particles. The results demonstrated that it is possible to obtain submicron polymer perfectly spherical particles using the technique discussed in this study. It was also observed that, depending on the cooling rate and the concentration of the polymer solution, it is possible to achieve high yield in the formation of submicron particles. In addition, preliminary tests were performed in order to verify the ability of this technique to form particulated carrier material with magnetic properties. The results showed that the developed technique can be an interesting alternative to obtain polymer particles with magnetic properties

Nitrogênio no feijoeiro em sistema de plantio direto sobre gramíneas

An adequate supply of nitrogen is essential for high yield of common bean seeds; however, the responses to this nutrient in no-tillage systems can vary in function of the species and the amount of straw present. The aim of this research was to evaluate response of the common bean to N in no-tillage systems over maize, millet and Brachiaria brizantha crop residues. Three experiments were conducted, one for each gramineous species. The experimental design was a randomized block in a 5x2x2 factorial scheme, with five N doses (0, 30, 60, 90, 120 kg ha(-1)), in two distinct stadia during the vegetative development (3(rd) and 6(th) trifoliate leaf) and two common bean cultivars (IPR Juriti and Perola), with four replications. The IPR Juriti produced a greater number of pods per plant and showed lower mass per 100 seeds than Perola. It did not show variation in bean yield when the sidedressing N application was carried out in the 3(rd) or 6(th) trifoliate leaf stadia. Based on the obtained results, one concludes that the seed productivity of common beans increases linearly with N doses in a no-tillage system over maize residues.

Avaliação de uma fração polissacaridica da alga Lobophora variegata (Lamouroux) em modelo de artrite induzida em ratos por Zymosan

Fucans seaweed Lobophora variegata estructures are known for their chemical and biological properties. In this study, we analyzed, the action of fucans L. variegata and the fractions purified with acetone in Zymosan-induced arthritis. After differential fractionation with acetone, six fractions were obtained and named F0.3, F0.5, F0.8, F1, F1.5 and F2. The results showed that the fraction F1 showed high yield (51.9%) and was chosen for studies of antioxidant activity and induced arthritis. Nuclear magnetic resonance (NMR) of 13C showed signals at 103.3 and 15.78 ppm that are assigned to links β13 galactose and of the C6 methyl fucose, respectively. The infrared (IR) showed absorbance at 1238 and 850 cm-1 which are attributed to sulfate. The fraction F1 showed antioxidant activities in vitro. For analysis of inflammatory parameters chosen the polysaccharide was administered in different doses (25, 50 and 75 mg / kg ip, per body weight) and diclofenac sodium (5 mg / kg ip) and L-NAME (25 mg / kg ip) in groups of animals (n = 6). After 6 h, were analyzed for cellular influx and levels of nitrite. In experiment five days, were made analysis of swelling and serum TNF-α. Histopathological analysis were performed for confirmation of results. The fraction F1 (25, 50 and 75 mg / kg ip) reduced the cellular influx (52.1 to 96.7%) and nitric oxide levels (27.2 - 39%) compared to control group. The reduction of edema (63.4 - 100%) and serum TNF-α (p <0.001) were observed when the polysaccharide F1 administered at a dose (50 mg / kg) These results suggest that these heterofucanas of Lobophora variegata have besides the activity antioxidant and potential anti-inflammatory activity in arthritis induced by zymosan

Síntese hidrotermal assistida por micro-ondas como metodologia sintética eficiente para obtenção da rede metalorgânica [ZN(BDC)(H2O)2]n

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Comparação de métodos de adaptabilidade e estabilidade relacionados à produtividade de grãos de cultivares de milho

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Morfoanatomia do sistema subterrâneo de Smallanthus sonchifolius (Poepp. & Endl.) H. Robinson (Asteraceae)

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Efeito da densidade populacional e época de colheita na produção de raízes de mandioca de mesa

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Crescimento e qualidade de crisântemo cultivado em vaso sob ambiente protegido

O crisântemo (Dendranthema grandiflora) é uma planta ornamental com grande demanda pelo mercado consumidor. Apesar de haver poucas informações sobre a sua exigência hídrica, sabe-se que irrigações deficitárias ou excessivas prejudicam seu desenvolvimento, reduzindo a produtividade e a qualidade. Considerando-se a importância da qualidade para a venda dos produtos florícolas o objetivo desse trabalho foi identificar a tensão de água no substrato (potencial matricial) com melhor crescimento e desenvolvimento do crisântemo, cultivar Rage, em vaso. Os tratamentos foram definidos por 6 níveis de tensão de água no substrato: -2; -3; -4; -6; -10 e -30 kPa. Concluiu-se que a melhor qualidade do crisântemo em vaso pode ser obtida com a tensão de -4 kPa e que, embora a tensão de -30 kPa tenha levado a uma drástica redução na qualidade comercial do crisântemo, a mesma pode ter um efeito benéfico na durabilidade pós- colheita.