CHARACTERISTICS OF ZINC-BINDING TO HUMAN RED-BLOOD-CELL MEMBRANES

The objective of the present study was to standardize the analysis of zinc binding on human red blood cell (RBC) membranes in 20 normal adults. The displacement studies revealed that at the maximal stable zinc concentration tested (600 muM), 57% (mean) of the bound Zn-65 was displaced and to displace half maximal Zn-65, the stable zinc concentration was 300 muM. Scatchard plots revealed two classes of binding sites for zinc on RBC membranes: one with higher affinity, Kd = 1.20 x 10(-5) M (site I), and the other with lower affinity, Kd = 2.77 x 10(-4) M (site II). Binding sites occupancy was 97% means and 58.5% means for sites I and 11, respectively. The displacement was affected by temperature, membrane protein concentration, freezing, thawing, and dialysis. Other metal cations, including Co++, Fe++, and Mn++, had very little effect on Zn-65 displacement, in contrast copper displaced Zn-65 from its binding sites on RBC membranes. Zinc binding to RBC membranes was rapid and readily reversible in a dynamic equilibrium with its binding sites. It is anticipated that this method will be applicable to studies of a wide variety of diseases specifically related to zinc metabolism in humans as well as in animals. (C) 1994 Wiley-Liss, Inc.

Nonlinear electrical behaviour of the Cr2O3, ZnO, CoO and Ta2O5-doped SnO2 varistors

The effects of Cr2O3 on the properties of (Zn, Co, Ta)-doped SnO2 varistors were investigated in this study. The samples with different Cr2O3 concentrations were sintered at 1400 degrees C for 2 h. The properties of (Zn, Co, Ta, Cr)-doped SnO2 varistors were evaluated by XRD. dilatornetry, SEM, I-V and impedance spectroscopy. DC electrical characterization showed a dramatic increase ill the breakdown electrical field and in the nonlinear coefficient with the increase in Cr2O3 concentration. The grain size was found to decrease from 13 to 5 mu m with increasing the Cr2O3 content. The impedance data, represented by means of Nyquist diagrams, show two time constants, one at low frequencies and the other at high frequencies. (c) 2005 Elsevier Ltd and Techna Group S.r.l. All rights reserved.

Podolsky's higher-order electromagnetism from first principles

Podolsky's higher-order field equations are obtained by generalizing the laws of Podolsky's electrostatics, which follow from Coulomb's generalized law and superposition, to be consistent with special relativity. In addition, it is necessary to take into account the independence of the observed charge of a particle on its speed. It is also shown that the gauge-independent term concerning the Feynman propagator for Podolsky's generalized electrodynamics has a good ultraviolet behaviour at the expense of a negative metric massive ghost which, contrary to what is currently assumed in the literature, is non-tachyonic. A brief discussion on Podolsky's characteristic length is presented as well.

Investigation of the electrical properties of SnO2 varistor system using impedance spectroscopy

The electrical properties of tin oxide varistors doped with CoO, Nb2O5 and Cr2O3, were investigated using the impedance spectroscopy technique with the temperature ranging from 25 to 400 degrees C. The impedance data, represented by means of Nyquist diagrams, show two time constants with different activation energies, one at low frequencies and the other at high frequencies. These activation energies were associated with the adsorption and reaction of O-2 species at the grain boundary interface. The Arrhenius plots show two slopes with a turnover at 200 degrees C for both the higher and lower frequency time constants. This behavior can be related with the decrease of minor charge carrier density. The barrier formation mechanism was associated with the presence of Cr-Sn at the surface, which promotes the adsorption of the O' and O species which are in turn proposed as being responsible for the barrier formation. (C) 1998 American Institute of Physics. [S0021-8979(98)04719-7]

SELF-CONSISTENT SOLUTION OF THE SCHWINGER-DYSON EQUATIONS FOR THE NUCLEON AND MESON PROPAGATORS

The Schwinger-Dyson equations for the nucleon and meson propagators are solved self-consistently in an approximation that goes beyond the Hartree-Fock approximation. The traditional approach consists in solving the nucleon Schwinger-Dyson equation with bare meson propagators and bare meson-nucleon vertices; the corrections to the meson propagators are calculated using the bare nucleon propagator and bare nucleon-meson vertices. It is known that such an approximation scheme produces the appearance of ghost poles in the propagators. In this paper the coupled system of Schwinger-Dyson equations for the nucleon and the meson propagators are solved self-consistently including vertex corrections. The interplay of self-consistency and vertex corrections on the ghosts problem is investigated. It is found that the self-consistency does not affect significantly the spectral properties of the propagators. In particular, it does not affect the appearance of the ghost poles in the propagators.

Piezoelectric properties of Bi4Ti3O12 thin films annealed in different atmospheres

Bismuth titanate (Bi4Ti3O12-BIT) films were evaluated for use as lead-free piezoelectric thin-films in micro-electromechanical systems. The films were grown by the polymeric precursor method on Pt/Ti/SiO2/Si (1 0 0) (Pt) bottom electrodes at 700 degrees C for 2 h in static air and oxygen atmospheres. The domain structure was investigated by piezoresponse force microscopy (PFM). Annealing in static air leads to better ferroelectric properties, higher remanent polarization, lower drive voltages and higher piezoelectric coefficient. on the other hand, oxygen atmosphere favors the imprint phenomenon and reduces the piezoelectric coefficient dramatically. Impedance data, represented by means of Nyquist diagrams, show a dramatic increase in the resistivity for the films annealed in static air atmopshere. (c) 2006 Elsevier Ltd. All rights reserved.

Nonlinear characteristics of Cr2O3, WO3, ZnO and CoO doped SnO2 varistors

SnO2 based ceramics doped with 1.0 mol% ZnO, 1.0 mol% CoO, 0.1 mol% WO3 and 0.05 mol% Cr2O3 show varistor behavior with nonlinear coefficient alpha = 33, breakdown electric field E-B = 12.5 kV/cm, leakage current I = 0.63 mA/cm(2) and average grain size of 1.52 mu m. Experimental evidence shows that the addition of Cr2O3 improves the nonlinear properties of the samples significantly, the impedance data, represented by means of Nyquist diagrams, show a dramatic increase in the resistivity for the samples doped with Cr2O3. (C) 2005 Elsevier B.V. All rights reserved.

Structure and properties of conducting bacterial cellulose-polyaniline nanocomposites

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Extra dimensions in superstring theory

It was earlier shown that an SO(9,1) θα spinor variable can be constructed from RNS matter and ghost fields. θα has a bosonic world-sheet super-partner λα which plays the role of a twistor variable, satisfying λΓμ λ = ∂xμ + iθΓμ ∂θ. For Type IIA superstrings, the left-moving [θL α, λL α] and right-moving [θRα, λRα] can be combined into 32-component SO(10,1) spinors [θA, λA]. This suggests that λAΓAB 11 λB = 2λL αλRα can be interpreted as momentum in the eleventh direction. Evidence for this interpretation comes from the zero-momentum vertex operators of the Type IIA superstring and from consideration of DD-branes. As in the work of Bars, one finds an SO(10,2) structure for the Type IIA superstring and an SO(9, 1) × SO(2, 1) structure for the Type IIB superstring. © 1997 Elsevier Science B.V.

On the picture dependence of Ramond-Ramond cohomology

Closed string physical states are BRST cohomology classes computed on the space of states annihilated by b- 0. Since b- 0 does not commute with the operations of picture changing, BRST cohomologies at different pictures need not agree. We show explicitly that Ramond-Ramond (RR) zero-momentum physical states are inequivalent at different pictures, and prove that non-zero-momentum physical states are equivalent in all pictures. We find that D-brane states represent BRST classes that are non-polynomial on the superghost zero-modes, while RR gauge fields appear as polynomial BRST classes. We also prove that in x-cohomology, the cohomology where the zero-mode of the spatial coordinates is included, there is a unique ghost-number one BRST class responsible for the Green-Schwarz anomaly, and a unique ghost number minus one BRST class associated with RR charge. © 1998 Elsevier Science B.V.

Covariant quantization of the superstring

After reviewing the Green-Schwarz superstring using the approach of Siegel, the superstring is covariantly quantized by constructing a BRST operator from the fermionic constraints and a bosonic pure spinor ghost variable. Physical massless vertex operators are constructed and, for the first time, N-point tree amplitudes are computed in a manifestly ten-dimensional super-Poincaré covariant manner. Quantization can be generalized to curved supergravity backgrounds and the vertex operator for fluctuations around AdS 5 x S 5 is explicitly constructed.

Relating the RNS and pure spinor formalisms for the superstring

Recently, the superstring was covariantly quantized using the BRST-like operator Q = ∮ λαdα where λα is a pure spinor and dα are the fermionic Green-Schwarz constraints. By performing a field redefinition and a similarity transformation, this BRST-like operator is mapped to the sum of the Ramond-Neveu-Schwarz BRST operator and η0 ghost. This map is then used to relate physical vertex operators and tree amplitudes in the two formalisms. Furthermore, the map implies the existence of a b ghost in the pure spinor formalism which might be useful for loop amplitude computations.

A method for the digital image analysis of ceramic grains based on shape factor segmentation

A very simple and robust method for ceramics grains quantitative image analysis is presented. Based on the use of optimal imaging conditions for reflective light microscopy of bulk samples, a digital image processing routine was developed for shading correction, noise suppressing and contours enhancement. Image analysis was done for grains selected according to their concavities, evaluated by perimeter ratio shape factor, to avoid consider the effects of breakouts and ghost boundaries due to ceramographic preparation limitations. As an example, the method was applied for two ceramics, to compare grain size and morphology distributions. In this case, most of artefacts introduced by ceramographic preparation could be discarded due to the use of perimeter ratio exclusion range.

Covariant quantization of the superstring

After constructing a BRST operator from the fermionic Green-Schwarz constraints and a bosonic pure spinor ghost variable, the superstring is covariantly quantized and N-point tree amplitudes are computed in a manifestly ten-dimensional super-Poincaré covariant manner. © 2004 Published by Elsevier B.V.

Can one cure the nonunitarity of three-dimensional quadratic gravity using a topological Chern-Simons term?

Quadratic gravity in (2+1)D is nonunitarity at the tree level. When a topological Chern-Simons term is added to this theory, the harmless massive scalar mode of the former gives rise to a troublesome massive spin-0 ghost, while the massive spin-2 ghost is replaced by two massive physical particles both of spin-2. Therefore, unlike what it is claimed in the literature, quadratic Chern-Simons gravity in (2+1)D is nonunitary at the tree level. © 2004 Published by Elsevier B.V.