888 resultados para MECANISMO REED
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Pós-graduação em Agronomia (Proteção de Plantas) - FCA
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The need for renewal and a more efficient use of energy resources has provided an increased interest in studies of methane activation processes in the gas phase by transition metal oxides. In this respect, the present work is an effort to assess , by means of a computational standpoint, the reactivity of NbOm n+ and FeOm n+ (m = 1, 2, n = 0, 1, 2) oxides in the activation process of the methane C-H bond, which corresponds to the first rate limiting step in the process of converting methane to methanol. These oxides are chosen, primarily, because the iron oxides are the most experimentally studied, and iron ions are more abundant in biological mediums. The main motive for choosing niobium oxides is the abundance of natural reserves of this mineral in Brazil (98%), especially in Minas Gerais. Initially, a thorough investigation was conducted, using different theoretical methods, to analyze the structural and electronic properties of the investigated oxides. Based on these results, the most reliable methodology was selected to investigate the activation process of the methane C-H bond by the series of iron and niobium oxides, considering all possible reaction mechanisms known to activate the C-H bond of alkanes. It is worth noting that, up to this moment and to our knowledge, there are no papers, in literature , investigating and comparing all the mechanisms considered in this work. I n general, the main results obtained show different catalytic tendencies and behaviors throughout the series of monoxides and dioxides of iron and niobium. An important and common result found in the two studies is that the increase in the load on the metal center and the addition of oxygen atoms to the metal, clearly favor the initial thermodynamics of the reaction, i.e., favor the approach of the metal center to methane, distorting its electron cloud and, thereby, decreasing its inertia. Comparing the two sets of oxides, we conclude that the iron oxides are the most efficient in activating the methane C-H bond. Among the iron oxides investigated, FeO + showed better kinetic and thermodynamic performance in the reaction with methane, while from the niobium oxides and ions NbO 2+ and NbO2 2+, showed better catalytic efficiency in the activation of the methane C-H bond.
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The Agroindustrial System coffee after decades of state regulation has become a decentralized economic activity. This situation compelled most of the actors in the production chain to resort to self r egulatory systems offered by certification agencies, which have specific criteria and procedures. However the diversity criteria of the agencies do not offer resources able to ensure efficient management of the governance structure. There is a need to reduce the asymmetry of information, which is possible through the sharing of data compatible with the production tracking feature. This work is supported in this contextualized problem, based on Transaction Cost Theory and the use of qualitative and quantitative research methodologies. The first part of the work seeks to know the procedures required by leading regulatory agencies in Brazil, with perspective to emphasize the similarities and compatibilities between them, which was reached after analysis of standards and comparison of similarities. Next is registered the operation and the coffee traceability of the structure, in order to identify, through observation, documental and bibliographical analysis, the systems in place and traceable information in line with the recommendations of the coffee certification. Finally, he sought to create a labeling model that allows to generate and share information about the product from the field to the sale for consumption. The information obtained in the previous steps were the basis for data collection with the production chain agents through a structured questionnaire administered to 618 agents of the production chain, whose answers were treated by multivariate methods of statistical analysis. The results showed that actors in the chain are in favor of inclusion and sharing information related to rural production and economic and environmental data. This knowledge enabled develop a labeling model where the information sharing agents is an efficient mechanism to mitigate the governance problems identified.
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El objetivo del presente documento es brindar una panorámica de la participación de los paÃses de América Latina y el Caribe en el Mecanismo de Solución de Diferencias (MSD) de la Organización Mundial del Comercio en sus primeros veinte años de existencia (1995-2014). Se constata que la región como un todo ha sido una activa usuaria de este mecanismo, e incluso algunos paÃses latinoamericanos figuran entre los principales usuarios a nivel mundial. De hecho, los paÃses de la región frecuentemente han recurrido al MSD pese a disponer de foros alternativos para zanjar sus controversias comerciales. Este es el caso de numerosas diferencias entre paÃses de la región que han sido sometidas al MSD en vez de buscar una resolución en el marco de los acuerdos de integración o comerciales vigentes entre dichos paÃses.
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Conselho Nacional de Desenvolvimento CientÃfico e Tecnológico (CNPq)
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Coordenação de Aperfeiçoamento de Pessoal de NÃvel Superior (CAPES)
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Pós-graduação em Ciências Sociais - FFC
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Pós-graduação em Letras - IBILCE
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Conselho Nacional de Desenvolvimento CientÃfico e Tecnológico (CNPq)
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Conselho Nacional de Desenvolvimento CientÃfico e Tecnológico (CNPq)
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Pós-graduação em Genética - IBILCE
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Este estudo, de relevância econômico-ambiental, parte do problema do aquecimento global para analisar o Mecanismo de Desenvolvimento Limpo (MDL) como uma ferramenta capaz de contribuir para a mitigação dos gases de efeito estufa (GEE) por meio do cumprimento de metas de redução de emissões pré estabelecidas pelo Protocolo de Quioto. Examina-se e participação do Brasil como paÃs hospedeiro dos projetos do MDL. Conclui-se que, embora a implementação do MDL diminua o custo global de redução de emissões de gases estufa pelos paÃses desenvolvidos e apóie iniciativas que promovam o desenvolvimento sustentável, a falta de maior especificidade nas regras do mecanismo pode abrir precedentes ao direito de poluir. Entende-se que o mecanismo não deve restringir-se somente ao cumprimento de meta, mas é fundamental que atue como desestimulante da poluição em sua origem, conforme a proposta de sustentabilidade, norte da polÃtica ambiental climática.
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Coordenação de Aperfeiçoamento de Pessoal de NÃvel Superior (CAPES)