Developing molecular identification numbers by an all-paths method

A new topological index is devised from an all-paths method. This molecular topological index has highly discriminating power for various kinds of organic compounds such as alkane trees, complex cyclic or polycyclic graphs, and structures containing heteroatoms and thus can be used as a Molecular IDentification number (MID) for chemical documentation. Some published MIDs derived from an all-paths method and their structural selectivity for alkane trees are also reviewed.

Copolymerization of styrene with butadiene and isoprene using a rare earth catalyst

In the copolymerization of styrene-butadiene and styrene-isoprene, a novel rare earth catalyst system (CF3CO2)(3)Ln/R(3-n)AlH(n)/(CH3)(3)CCH2Br (Ln = Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu; R = Me-, Et-, i-Bu-, and Oct-; n = 0 and 1) has been studied. The 1, 4 unit contents in the copolymers obtained are found to range from 64.4 to 99.6% with St contents of 5.2 to 59.9%, and intrinsic viscosities of 0.1 to 0.5 dl g(-1) measured by i.r., H-1 n.m.r. and C-13 n.m.r. spectra. From the calculated data of linked ratios, a change in the microstructure is induced by the styrene unit, probably adjacent to the butadiene or isoprene unit. An interesting result is that the ratios of styrene unit linked with 1, 2 or 3,4 units in the copolymers are far higher than in copolymers obtained with the nickel catalyst. The experimental results are discussed in terms of rare earth pi-allyl coordination and back-biting mechanism.

VOLTAMMETRY OF CYTOCHROME-C ENTRAPPED IN HYDROGEL MEMBRANE ON GRAPHITE ELECTRODE

The voltammetric behavior of cytochrome c entrapped in hydrogel membranes at paraffin wax-impregnated spectroscopic graphite electrodes (WISGE) was studied in this paper. A pair of well-defined peaks appeared at +70 mV (vs. Ag/AgCl). Beside these two peaks, another pair of peaks emerged at around +225 mV. Further investigations suggested that at least three states of cytochrome c existed in the membranes due to the special structure of the hydrogel. The native conformation of cytochrome c molecules was stabilized by the hydrophilic environment that was formed by the hydroxyl structure of the membranes and facilitated the cytochrome c electron transfer reaction at +70 mV. The molecules directly adsorbed on the surface of the graphite electrode were responsible for the redox peaks at around +225 mV. Whether the adsorption peaks were detectable or not was related to the thickness of membranes and the pre-retaining time before the formation of membranes.

Analysis of diets of upland buzzards using stable carbon and nitrogen isotopes

We measured the stable carbon and nitrogen isotope ratios for muscles of the upland buzzards (Buteo hemilasius) and their potential food sources, plateau pikas (Ochotona curzoniae), Qinghai voles (Lasiopodomys fuscus), plateau zokors (Myospalax fontanierii), and several passerine bird species at the alpine meadow in Maduo county, Guoluo prefecture of Qinghai province, People's Republic of China, to provide diet information of upland buzzards, highlighting different diet composition of upland buzzards exposed to different locations. The results demonstrated that stable carbon isotope ratios of upland buzzards, passerine birds, plateau pikas, plateau zokors, and Qinghai voles were -24.42 +/- 0.25parts per thousand, -22.89 +/- 1.48parts per thousand, -25.30 +/- 1.47parts per thousand, -25.78 +/- 0.22parts per thousand, and -25.41 +/- 0.01parts per thousand, respectively, and stable nitrogen isotope ratios were 7.89 +/- 0.38parts per thousand, 8.37 +/- 2.05parts per thousand, 5.83 +/- 1.10parts per thousand, 5.23 +/- 0.34parts per thousand, and 8.86 +/- 0.06parts per thousand, respectively. Fractionation of stable carbon and nitrogen isotope ratios between upland buzzards and their food were 1.03parts per thousand and 2.11parts per thousand, respectively. Based on mass balance principle of stable isotopes and the Euclidean distance mixing model, upland buzzards depended mainly on plateau pikas as food (74.56%). Plateau zokors, Qinghai voles, and passerine birds only contributed a small proportion (25.44%) to diets of upland buzzards. The results were closely accordant with analyses of stomach contents and food pellets, which firmly supported the feasibility of using stable carbon and nitrogen isotope ratios to investigate diet information of upland buzzards. Another study based on stable carbon isotopes showed that upland buzzards living in the Haibei prefecture (another prefecture located in the southeast Qinghai province) mainly preyed on passerine birds (64.96% or more) as food supply. We were alarmed by the preliminary results that widespread poisoning activities of small mammals could reshape the food composition of upland buzzards, influencing the stability and sustainability of the alpine meadow. Bio-control on rodent pests should be carried out rather than the chemical measures.

基于测量数据反演并联机床非线性位姿误差模型

利用最小二乘技术识别模型参数 ,将非线性问题作线性化处理 ,提出了一种基于测量数据反演非线性误差模型的建模方法。结合算例 ,指出了此类模型设计应注意的问题。五轴并联机床约束机构误差模型仿真结果表明 ,由此得到的误差模型精度高。利用所得模型对机床位姿进行补偿 ,即可提高机床沿该位姿方向的定位精度

湘中锡矿山式锑矿成矿地质条件分析

湘中锡矿山式锑矿彤成于晚白垩一古新世，空间上与岩脉关系密切．各锑矿床、 矿化点都伴有或附近发育有煌斑岩盟中一酸性岩脉群．在锑矿成矿同期地质事件中，还有周缘一些中一新生代红色盆地的形成及基性火l JI岩喷发，据之，提出湘中锡矿山式锑矿成矿与燕山晚期拉张构造一岩浆活化作用有关 锑矿床(点)基车七都产}ij于两组或两组以卜断裂的交汇点附近，3组断裂的交汇部位对应于最主要的锑矿床(点)。矿体具体受断裂交汇部位附近的次级短轴背斜轴部、倾伏背斜的倾伏端及其翼部被纵向陡倾角断裂构造所切穿的部位控制，是断裂导矿与背斜构造圈闭的体现。岩性组合控矿表现为易于硅化蚀变交代的砂质碳酸盐岩与隔挡层泥质岩所构成的岩性圈闭=根据包裹体均一温度和盐度澳l定成果．推算成矿压力为(200～300)×1旷Pa，成矿深度约为1km 。

地质样品中Mo同位素测定的前处理方法研究

通过对地质样品中Mo同位素测试前的处理方法的比较，对传统的阴、阳离子树脂交换法进行了改进研究。经改进后的方法实用范围较宽，Mo的回收率达到97．49％±0．27％，Mo同位素质谱分析过程中可能的同重干扰元素Zr、Fe、Mn等的去除效果理想，其它金属元素的去除效果也较理想，且在阴离子交换柱洗脱Mo的过程中总计约需的提取液（盐酸和硝酸）体积只有75mL，只需文献报道用量的45％，从而减少了试剂对样品，特别是对低含量地质样品可能带来的潜在污染.

北京市中学生考试焦虑状况及其相关因素分析

In order to analyze the test anxiety of Beijing's high school students, relevant factors affecting test anxiety and how those factors have effect on the test anxiety of those high school students, a cross-sectional study had been conducted among 2,089 students randomly selected from 15 high schools in Beijing, using the Test Anxiety Scale（TAS）, Parenting Style Scale (PSS) and Academic Aggregate Graphic (AAG). Five months later, 194 students from one of those high schools were retested with TAS with students remaining anonymous. In the retest, the classes and birth dates of those students were strictly matched. This paper is composed of three parts to examine the issue. The first part examines the test anxiety among high school students in Beijing and establishes the model; the second part conducts a comparative study of issues related to test anxiety and academic performance; the third part examines the factors affecting test anxiety and establishes the model. Results showed that: 1. The reliability and validity of TAS are satisfied and can meet survey requirement. The 25-item version of TAS turned out to have equal or even better performance compared with the original 37-item version. 2. Incidence of test anxiety in high schools of Beijing: 57.9 percent of samples have an overall score at or higher 15. 55 percent of male student samples have a score at or higher than 15 while that for female student samples is 61 percent. A score of 20 refers to fairly serious test anxiety and 31.9 percent of samples have a score over 20. 28.1 percent of the male student samples have a score of over 20 while that for female student samples is 35.9 percent. 3. The effect of grade and sex and the interaction between the two factors are statistically significant. Female students have higher test anxiety than male students and the level of test anxiety varies from grade to grade. 4. Samples are divided into two groups, one with test anxiety and the other without. The academic performance gap between the two groups is very significant. There is a significant negative correlation between academic score and test anxiety. 5. There is a negative correlation between test anxiety and mastery goal orientation and a positive correlation between test anxiety and performance goal orientation. Students with higher academic self-efficiency have lower test anxiety. The more one thinks study is valuable, the lower his/her test anxiety is. Those whose parents communicate smoothly with them have lower test anxiety. Those whose parents have an inconsistent communication style have higher test anxiety. 6. Achievement goal is mediate variable for the effect of lack of values on test anxiety. 7. The indirect effect of introduction of achievement goal and parenting style, including communication, monitoring and communication consistence, on test anxiety is significant. Key words: Test anxiety，reliability, validity, self-efficiency，parenting style，achievement goal orientation, academic values, academic score

Competitiveness in a globalised world: Michael Porter on the microeconomic foundations of the competitiveness of nations, regions, and firms.

In this paper, we provide the text of an interview with Professor Michael Porter discussing his research and ideas relating to the microeconomic foundations of global competitiveness. The discussion provides a microeconomic perspective on some of the key issues relating to recent research on competitiveness, productivity, clusters, US economic leadership, economic growth and development.

Estudo da prevalência da discrepância anterior de Bolton numa população ortodôntica portuguesa

Projeto de Pós-Graduação/Dissertação apresentado à Universidade Fernando Pessoa como parte dos requisitos para obtenção do grau de Mestre em Medicina Dentária

Metacognition in monkeys during an oculomotor task.

This study investigated whether rhesus monkeys show evidence of metacognition in a reduced, visual oculomotor task that is particularly suitable for use in fMRI and electrophysiology. The 2-stage task involved punctate visual stimulation and saccadic eye movement responses. In each trial, monkeys made a decision and then made a bet. To earn maximum reward, they had to monitor their decision and use that information to bet advantageously. Two monkeys learned to base their bets on their decisions within a few weeks. We implemented an operational definition of metacognitive behavior that relied on trial-by-trial analyses and signal detection theory. Both monkeys exhibited metacognition according to these quantitative criteria. Neither external visual cues nor potential reaction time cues explained the betting behavior; the animals seemed to rely exclusively on internal traces of their decisions. We documented the learning process of one monkey. During a 10-session transition phase, betting switched from random to a decision-based strategy. The results reinforce previous findings of metacognitive ability in monkeys and may facilitate the neurophysiological investigation of metacognitive functions.