Study of a vapor-compression air-conditioning system for jetliners

Most modern passenger aeroplanes use air cycle cooling. A high-speed air cycle is a reliable and light option, but not very efficient. This thesis presents research work done to design a novel vapour cooling cycle for aeroplanes. Due to advancements in high-speed permanent magnet motors, the vapour cycle is seen as a competitive option for the air cycle in aeroplanes. The aerospace industry places tighter demands on the weight, reliability and environmental effects of the machinery than those met by conventional chillers, and thus modifications to conventional design are needed. The thesis is divided into four parts: the initial screening of the working fluid, 1-D design and performance values of the compressor, 1-D off-design value predictions of the compressor and the 3-D design of the compressor. The R245fa was selected as the working fluid based the study. The off-design range of the compressor was predicted to be wide and suitable for the application. The air-conditioning system developed is considerably smaller than previous designs using centrifugal compressors.

Ydinvoimalaitoksen vuosihuoltoajankohdan optimointi

Viimeaikoina ydinvoima on ollut vahvasti esillä mediassa. Keskustelut lisäydinvoimasta, sähköntuotantomuodoista, Olkiluodon kolmannen ydinvoimalaitosyksikön rakennustöistä, sähkön kulutuksen tulevaisuudesta ja nykyisestä taloustilanteesta ovat vaikuttaneet tarpeeseen tutkia sähkön tuotantokustannuksia ydinvoiman osalta. Tutkimuksessa keskitytään erityisesti ydinvoimalaitosyksiköiden vuosihuolto- ja polttoainekustannuksiin, jotka muodostavat suurimman suunnitellun yksittäisen kustannuserän ydinvoiman käyttöön liittyen. Työ tehdään Teollisuuden Voima Oyj:lle, joka pääsääntöisesti toimii Eurajoen Olkiluodossa. Työssä optimoidaan jokaiselle Olkiluodon ydinvoimalaitosyksikölle mahdollisimman edullinen vuosihuoltoajankohta. Optimaalisin ajankohta määrittyy edullisimman sähkön hinnan, ihanteellisimman käyttöjakson pituuden sekä resurssien saatavuuden perusteella. Ydinvoimalaitosyksiköiden vuosihuoltoajankohdat suunnitellaan siten, että vuosihuollot ovat kokonaisuudessaan ja laitosyksikkökohtaisesti optimaaliset. Työn lopputuloksena on esitys Olkiluodon ydinvoimalaitosyksiköiden optimaalisista vuosihuoltoajankohdista. Työn tuloksien myötä Teollisuuden Voima Oyj:llä on mahdollisuus pienentää vuosihuoltokustannuksiaan ja osaltaan vaikuttaa ydinvoimalla tuotetun sähkön kannattavuuteen. Vuosihuoltoajankohdan optimointi palvelee myös Teollisuuden Voima Oyj:n osakkaiden vaatimuksia.

Suomen ydinpolttoainekierto

Suomessa on nykyisin käytössä avoimen ydinpolttoainekierron politiikka missä käytetty polttoaine loppusijoitetaan suoraan ilman jälleenkäsittelyä. Nykyisin kehitteillä olevat uuden sukupolven ydinreaktorit ovat kuitenkin pääosin suunniteltu osittain tai kokonaan suljetuille polttoainekierroille, joissa käytetty polttoaine jälleenkäsitellään ja osa materiaaleista kierrätetään. Tässä tutkimusraportissa on tarkoitus arvioida Suomen ydinvoimakapasiteetin ja ydinpolttoainekierron kehitystä tulevina vuosikymmeninä sekä arvioida käytetyn polttoaineen jälleenkäsittelyn, kierrätyksen ja nopeiden reaktoreiden käyttöönoton vaikutusta muun muassa uraanin kulutukseen, syntyvän käytetyn polttoaineen määrään sekä polttoainekierron taloudellisuuteen. Lisäksi työssä arvioidaan Talvivaaran ja Soklin sivutuotteena saatavan uraanin riittävyyttä Suomen uraanintarpeen kattamiseksi. Työssä arvioitiin ensin oletuksien ja nykyisen tilanteen avulla Suomen ydinvoimakapasiteetin kehitys tuleville vuosille. Perustuen tähän kehitykseen nykyistä polttoainekiertoa verrattiin tämän jälkeen kahteen kehittyneempään polttoainekiertoversioon, joissa käytetty polttoaine jälleenkäsitellään, plutonium kierrätetään uudelleen polttoaineeksi ja osa termisistä reaktoreista korvataan nopeilla. Polttoainekiertoversioiden massavirtojen määrittämisessä käytettiin apuna kansainvälisen atomienergiajärjestön kehittämää Nuclear Fuel Cycle Simulation System -ohjelmaa. Nykyisellä polttoainekierrolla uraanintarve oli laskelmien perusteella noin 100 tuhatta tonnia vuoteen 2100 mennessä. Jälleenkäsittelyn ja plutoniumin kierrätyksen avulla uraanin tarve saatiin pudotettua noin 75 tuhanteen tonniin. Korvaamalla puolet ydinvoimakapasiteetista nopeilla reaktoreilla vuosina 2074 ja 2080 vähentäisi uraanintarvetta edelleen noin 66 tuhanteen tonniin. Kerääntyneen käytetyn polttoaineen määräksi arvioitiin nykyisen kaltaisella polttoainekierrolla noin 11900 tonnia vuoteen 2100 mennessä. Nopeiden reaktoreiden käyttöönoton myötä kerääntyneen käytetyn polttoaineen määrä vähenisi edelleen noin 11200 tonniin vuoteen 2100 mennessä. Talvivaaran ja Soklin uraanintuotanto riittäisi laskelmien mukaan kattamaan Suomen uraanintarpeen nykyisellä polttoainekierrolla vuoteen 2070 asti ja kehittyneemmillä polttoainekierroilla vuosiin 2089 ja 2106 asti riippuen polttoainekierrosta. Polttoainekierron kustannukset nousivat polttoaineen jälleenkäsittelyn ja kierrätyksen myötä noin 50-67 % suuremmiksi nykyiseen polttoainekiertoon verrattuna. Investointi- sekä käyttö- ja kunnossapitokustannuksien erot olivat eri versioiden välillä pienet, mistä johtuen myös kokonaiskustannuksien erot jäivät pieniksi.

An eclectic morphostratigraphic model for the sedimentary response to Holocene sea-level rise in northwest Europe

The improved empirical understanding of silt facies in Holocene coastal sequences provided by such as diatom, foraminifera, ostracode and testate amoebae analysis, combined with insights from quantitative stratigraphic and hydraulic simulations, has led to an inclusive, integrated model for the palaeogeomorphology, stratigraphy, lithofacies and biofacies of northwest European Holocene coastal lowlands in relation to sea-level behaviour. The model covers two general circumstances and is empirically supported by a range of field studies in the Holocene deposits of a number of British estuaries, particularly, the Severn. Where deposition was continuous over periods of centuries to millennia, and sea level fluctuated about a rising trend, the succession consists of repeated cycles of silt and peat lithofacies and biofacies in which series of transgressive overlaps (submergence sequences) alternate with series of regressive overlaps (emergence sequences) in association with the waxing and waning of tidal creek networks. Environmental and sea-level change are closely coupled, and equilibrium and secular pattern is of the kind represented ideally by a closed limit cycle. In the second circumstance, characteristic of unstable wetland shores and generally affecting smaller areas, coastal erosion ensures that episodes of deposition in the high intertidal zone last no more than a few centuries. The typical response is a series of regressive overlaps (emergence sequence) in erosively based high mudflat and salt-marsh silts that record, commonly as annual banding, exceptionally high deposition rates and a state of strong disequilibrium. Environmental change, including creek development, and sea-level movement are uncoupled. Only if deposition proceeds for a sufficiently long period, so that marshes mature, are equilibrium and close coupling regained. (C) 2002 Elsevier Science B.V. All rights reserved.

Modelo bioeconômico para cálculo de custos e receitas em sistemas de produção de gado de corte visando à obtenção de valores econômicos de características produtivas e reprodutivas

Foi desenvolvido um modelo bioeconômico para o cálculo do desempenho, dos custos e das receitas para obtenção de valores econômicos de características de interesse econômico em sistemas de produção de gado de corte no Brasil. As informações de desempenho e de parâmetros biológicos e econômicos foram obtidas em uma propriedade de gado Nelore que realiza ciclo completo com venda de reprodutores. O modelo é determinístico e estático e foram usadas planilhas Excel para a realização dos cálculos. Com base nas informações originais, foram simulados dois sistemas de produção, um fazendo o ciclo completo com venda de reprodutores (CcoR) e o outro, de cria (Cc). Foram calculados os custos e as receitas para esses dois sistemas e, a partir disto, foram obtidos seus lucros anuais. Para o cálculo dos valores econômicos foram escolhidas as características peso à desmama (PD), peso adulto da vaca (PAV), taxa de prenhez (TP) e taxa de desmama (TD), que são de interesse nos dois sistemas de produção. Para avaliar o impacto das mudanças no desempenho das características sobre o lucro anual do sistema de produção, os valores iniciais das características foram aumentados em 1%. Esse aumento resultou em mudanças positivas no lucro, observando-se que a TD foi a característica que apresentou maior impacto nos dois sistemas. Para o CcoR, os valores econômicos para PD, PAV, TP e TD foram, respectivamente, R$ 0,40/kg, R$ 0,09/kg, R$ 3,20/1% e R$ 10,15/1%. Para Cc, estes valores foram, respectivamente, de R$ 1,31/kg, R$ 0,09/kg, R$ 2,41/1% e R$ 3,36/1%. O modelo foi capaz de reproduzir satisfatoriamente o sistema de produção de gado de corte estudado e pode ser adaptado para outras circunstâncias de produção.

Determination of ecological efficiency in internal combustion engines: The use of biodiesel

This paper evaluates and quantifies the environmental impact from the use of some renewable fuels and fossils fuels in internal combustion engines. The following fuels are evaluated: gasoline blended with anhydrous ethyl alcohol (anhydrous ethanol), conventional diesel fuel, biodiesel in pure form and blended with diesel fuel, and natural gas. For the case of biodiesel, its complete life cycle and the closed carbon cycle (photosynthesis) were considered. The ecological efficiency concept depends on the environmental impact caused by CO(2), SO(2), NO(x) and particulate material (PM) emissions. The exhaust gases from internal combustion engines, in the case of the gasoline (blended with alcohol), biodiesel and biodiesel blended with conventional diesel, are the less polluting; on the other hand, the most polluting are those related to conventional diesel. They can cause serious problems to the environment because of their dangerous components for the human, animal and vegetable life. The resultant pollution of each one of the mentioned fuels are analyzed, considering separately CO(2), SO(2), NO(x) and particulate material (PM) emissions. As conclusion, it is possible to calculate an environmental factor that represents, qualitatively and quantitative, the emissions in internal combustion engines that are mostly used in urban transport. Biodiesel in pure form (B100) and blended with conventional diesel as fuel for engines pollute less than conventional diesel fuel. The ecological efficiency for pure biodiesel (B100) is 86.75%: for biodiesel blended with conventional diesel fuel (B20, 20% biodiesel and 80% diesel), it is 78.79%. Finally, the ecological efficiency for conventional diesel, when used in engines, is 77.34%; for gasoline, it is 82.52%, and for natural gas, it is 91.95%. All these figures considered a thermal efficiency of 30% for the internal combustion engine. Crown Copyright (C) 2008 Published by Elsevier Ltd. All rights reserved.

Biodiesel CO2 emissions: A comparison with the main fuels in the Brazilian market

The use of biodiesel is increasing as an attractive fuel due to the depleting fossil fuel resources and environmental degradation. This paper presents results of an investigation on the potentials of biodiesel as an alternative fuel and main substitute of diesel oil, comparing the CO2 emissions of the main fuels in the Brazilian market with those of biodiesel, in pure form or blended in different proportions with diesel oil (2%, 5%, and 20%, called B2, B5, and B20, respectively). The results of the study are shown in ton CO2 per m(3) and ton CO2 per year of fuel. The fuels were analyzed considering their chemical composition, stoichiometric combustion parameters and mean consumption for a single vehicle. The fuels studied were: gasoline, diesel oil, anhydrous ethyl alcohol (anhydrous ethanol), and biodiesel from used frying oil and from soybean oil. For the case of biodiesel, its complete life cycle and the closed carbon cycle (photosynthesis) were considered. With data provided by the Brazilian Association of Automotive Vehicle Manufacturers (ANFAVEA) for the number of vehicles produced in Brazil, the emissions of CO2 for the national fleet in 2007 were obtained per type of fuel. With data provided by the Brazilian Department of Transit (DENATRAN) concerning the number of diesel vehicles in the last five years in Brazil, the total CO2 emissions and the percentage that they would decrease in the case of use of pure biodiesel, B100, or several mixtures, B2, B5 and B20, were calculated. Estimates of CO2 emissions for a future scenario considering the mixtures B5 and B20 are also included in this article. Crown Copyright (C) 2008 Published by Elsevier B.V. All rights reserved.

Influência da temperatura no desempenho mecânico de compósitos PEI/fibras de vidro

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Damage to the central amygdala produces differential encephalic c-fos expression in the water deprivation-partial rehydration protocol

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Avaliação da promiscuidade catalítica de soroalbuminas em sínteses orgânicas

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

New measurement of the B-11(p,alpha(0))Be-8 bare-nucleus S(E) factor via the Trojan horse method

A new measurement of the B-11(p,alpha(0))Be-8 has been performed applying the Trojan horse method (THM) to the H-2(B-11,alpha Be-8(0))n quasi-free reaction induced at a laboratory energy of 27 MeV. The astrophysical S(E) factor has been extracted from similar to 600 keV down to zero energy by means of an improved data analysis technique and it has been compared with direct data available in the literature. The range investigated here overlaps with the energy region of the light element LiBeB stellar burning and with that of future aneutronic fusion power plants using the B-11+p fuel cycle. The new investigation described here confirms the preliminary results obtained in the recent TH works. The origin of the discrepancy between the direct estimate of the B-11(p,alpha(0))Be-8 S(E)-factor at zero energy and that from a previous THM investigation is quantitatively corroborated. The results obtained here support, within the experimental uncertainties, the low-energy S(E)-factor extrapolation and the value of the electron screening potential deduced from direct measurements.

New DAG-dependent mechanisms modulate cell cycle progression

Through the years, several studies reported the involvement of nuclear lipid signalling as highly connected with cell cycle progression. Indeed, nuclear Phosphatidylinositol-4,5-Biphosphate (PIP2) hydrolisis mediated by Phospholipases C (PLC), which leads to production of the second messengers Diacylglycerol (DAG) and Inositol-1,4,5-Triphosphate (IP3), is a fundamental event for both G1/S and G2/M checkpoints. In particular, we found that nuclear DAG production was mediated by PLCbeta1, enzyme mainly localized in the nucleus of K562 human erythroleukemia cells. This event triggered the activation and nuclear translocation of PKCalpha, which, in turn, resulted able to affect cell cycle via modulation of Cyclin D3 and Cyclin B1, two important enzymes for G1/S transition and G2/M progression respectively.

LIFE CYCLE ASSESSMENT OF BIOFUEL PRODUCED FROM ALGAE

Algae are considered a promising source of biofuels in the future. However, the environmental impact of algae-based fuel has high variability in previous LCA studies due to lack of accurate data from researchers and industry. The National Alliance for Advanced Biofuels and Bioproducts (NAABB) project was designed to produce and evaluate new technologies that can be implemented by the algal biofuel industry and establish the overall process sustainability. The MTU research group within NAABB worked on the environmental sustainability part of the consortium with UOP-Honeywell and with the University of Arizona (Dr. Paul Blowers). Several life cycle analysis (LCA) models were developed within the GREET Model and SimaPro 7.3 software to quantitatively assess the environment viability and sustainability of algal fuel processes. The baseline GREET Harmonized algae life cycle was expanded and replicated in SimaPro software, important differences in emission factors between GREET/E-Grid database and SimaPro/Ecoinvent database were compared, and adjustments were made to the SimaPro analyses. The results indicated that in most cases SimaPro has a higher emission penalty for inputs of electricity, chemicals, and other materials to the algae biofuels life cycle. A system-wide model of algae life cycle was made starting with preliminary data from the literature, and then progressed to detailed analyses based on inputs from all NAABB research areas, and finally several important scenarios in the algae life cycle were investigated as variations to the baseline scenario. Scenarios include conversion to jet fuel instead of biodiesel or renewable diesel, impacts of infrastructure for algae cultivation, co-product allocation methodology, and different usage of lipid-extracted algae (LEA). The infrastructure impact of algae cultivation is minimal compared to the overall life cycle. However, in the scenarios investigating LEA usage for animal feed instead of internal recycling for energy use and nutrient recovery the results reflect the high potential variability in LCA results. Calculated life cycle GHG values for biofuel production scenarios where LEA is used as animal feed ranged from a 55% reduction to 127% increase compared to the GREET baseline scenario depending on the choice of feed meal. Different allocation methods also affect LCA results significantly. Four novel harvesting technologies and two extraction technologies provided by the NAABB internal report have been analysis using SimaPro LCA software. The results indicated that a combination of acoustic extraction and acoustic harvesting technologies show the most promising result of all combinations to optimize the extraction of algae oil from algae. These scenario evaluations provide important insights for consideration when planning for the future of an algae-based biofuel industry.

Evidence from the real world: N-15 natural abundances reveal enhanced nitrogen use at high plant diversity in Central European grasslands

Complementarity that leads to more efficient resource use is presumed to be a key mechanism explaining positive biodiversity–productivity relationships but has been described solely for experimental set-ups with controlled environmental settings or for very short gradients of abiotic conditions, land-use intensity and biodiversity. Therefore, we analysed plant diversity effects on nitrogen dynamics across a broad range of Central European grasslands. The 15N natural abundance in soil and plant biomass reflects the net effect of processes affecting ecosystem N dynamics. This includes the mechanism of complementary resource utilization that causes a decrease in the 15N isotopic signal. We measured plant species richness, natural abundance of 15N in soil and plants, above-ground biomass of the community and three single species (an herb, grass and legume) and a variety of additional environmental variables in 150 grassland plots in three regions of Germany. To explore the drivers of the nitrogen dynamics, we performed several analyses of covariance treating the 15N isotopic signals as a function of plant diversity and a large set of covariates. Increasing plant diversity was consistently linked to decreased δ15N isotopic signals in soil, above-ground community biomass and the three single species. Even after accounting for multiple covariates, plant diversity remained the strongest predictor of δ15N isotopic signals suggesting that higher plant diversity leads to a more closed nitrogen cycle due to more efficient nitrogen use. Factors linked to increased δ15N values included the amount of nitrogen taken up, soil moisture and land-use intensity (particularly fertilization), all indicators of the openness of the nitrogen cycle due to enhanced N-turnover and subsequent losses. Study region was significantly related to the δ15N isotopic signals indicating that regional peculiarities such as former intensive land use could strongly affect nitrogen dynamics. Synthesis. Our results provide strong evidence that the mechanism of complementary resource utilization operates in real-world grasslands where multiple external factors affect nitrogen dynamics. Although single species may differ in effect size, actively increasing total plant diversity in grasslands could be an option to more effectively use nitrogen resources and to reduce the negative environmental impacts of nitrogen losses.

Impact radiologique liés au transport de matières radioactives par route en Espagne / Radiological impact associated with the transport by road of radioactive material in Spain

Questions relating to the transport of radioactive materials are very much an issue of current interest due to the increasing mobility of the materials involved in the nuclear fuel cycle, commitment to the environment, the safety and protection of persons and the corresponding regulatory legal framework. The radiological impact associated with this type of transport was assessed by means of a new data-processing tool that may be of use and serve as complementary documentation to that included in transport regulations. Thus, by determining the level of radiation at a distance of one metre from the transport vehicle and by selecting a route, the associated impacts will be obtained, such as the affected populations, the dose received by the most highly exposed individual, the overall radiological impact, the doses received by the population along the route and the possible detriment to their health. The most important conclusion is that the emissions of ionising radiation from the transport of radioactive material by road in Spain are not significant as regards the generation of adverse effects on human health, and that their radiological impact may be considered negligible.