935 resultados para First and Second Order Directional Derivatives
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Pós-graduação em Educação Matemática - IGCE
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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Pós-graduação em Ciência dos Materiais - FEIS
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Pós-graduação em Matemática - IBILCE
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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The main goal of this bachelor work is the study of the physical properties of solids by thermal expansion coefficient measurements, which allows the exploration of various aspects of phase transitions. In this study, some theoretical aspects were focused, for example the first and second order phase transitions, Landau theory for phase transition and the volumetric thermal expansion coefficient. Furthermore, on the origin of the thermal expansion from the Lennard-Jones potential, that contains the anharmonic terms, which give rise to the phononic thermal expansion in solids
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Pós-graduação em Física - IFT
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High pressure NMR spectroscopy has developed into an important tool for studying conformational equilibria of proteins in solution. We have studied the amide proton and nitrogen chemical shifts of the 20 canonical amino acids X in the random-coil model peptide Ac-Gly-Gly-X-Ala-NH2, in a pressure range from 0.1 to 200 MPa, at a proton resonance frequency of 800 MHz. The obtained data allowed the determination of first and second order pressure coefficients with high accuracy at 283 K and pH 6.7. The mean first and second order pressure coefficients <B-1(15N)> and <B-2(15N)> for nitrogen are 2.91 ppm/GPa and -2.32 ppm/GPa(2), respectively. The corresponding values <B-1(1H)> and <B-2(1H)> for the amide protons are 0.52 ppm/GPa and -0.41 ppm/GPa(2). Residual dependent (1)J(1H15N)-coupling constants are shown.
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Die Flachwassergleichungen (SWE) sind ein hyperbolisches System von Bilanzgleichungen, die adäquate Approximationen an groß-skalige Strömungen der Ozeane, Flüsse und der Atmosphäre liefern. Dabei werden Masse und Impuls erhalten. Wir unterscheiden zwei charakteristische Geschwindigkeiten: die Advektionsgeschwindigkeit, d.h. die Geschwindigkeit des Massentransports, und die Geschwindigkeit von Schwerewellen, d.h. die Geschwindigkeit der Oberflächenwellen, die Energie und Impuls tragen. Die Froude-Zahl ist eine Kennzahl und ist durch das Verhältnis der Referenzadvektionsgeschwindigkeit zu der Referenzgeschwindigkeit der Schwerewellen gegeben. Für die oben genannten Anwendungen ist sie typischerweise sehr klein, z.B. 0.01. Zeit-explizite Finite-Volume-Verfahren werden am öftersten zur numerischen Berechnung hyperbolischer Bilanzgleichungen benutzt. Daher muss die CFL-Stabilitätsbedingung eingehalten werden und das Zeitinkrement ist ungefähr proportional zu der Froude-Zahl. Deswegen entsteht bei kleinen Froude-Zahlen, etwa kleiner als 0.2, ein hoher Rechenaufwand. Ferner sind die numerischen Lösungen dissipativ. Es ist allgemein bekannt, dass die Lösungen der SWE gegen die Lösungen der Seegleichungen/ Froude-Zahl Null SWE für Froude-Zahl gegen Null konvergieren, falls adäquate Bedingungen erfüllt sind. In diesem Grenzwertprozess ändern die Gleichungen ihren Typ von hyperbolisch zu hyperbolisch.-elliptisch. Ferner kann bei kleinen Froude-Zahlen die Konvergenzordnung sinken oder das numerische Verfahren zusammenbrechen. Insbesondere wurde bei zeit-expliziten Verfahren falsches asymptotisches Verhalten (bzgl. der Froude-Zahl) beobachtet, das diese Effekte verursachen könnte.Ozeanographische und atmosphärische Strömungen sind typischerweise kleine Störungen eines unterliegenden Equilibriumzustandes. Wir möchten, dass numerische Verfahren für Bilanzgleichungen gewisse Equilibriumzustände exakt erhalten, sonst können künstliche Strömungen vom Verfahren erzeugt werden. Daher ist die Quelltermapproximation essentiell. Numerische Verfahren die Equilibriumzustände erhalten heißen ausbalanciert.rnrnIn der vorliegenden Arbeit spalten wir die SWE in einen steifen, linearen und einen nicht-steifen Teil, um die starke Einschränkung der Zeitschritte durch die CFL-Bedingung zu umgehen. Der steife Teil wird implizit und der nicht-steife explizit approximiert. Dazu verwenden wir IMEX (implicit-explicit) Runge-Kutta und IMEX Mehrschritt-Zeitdiskretisierungen. Die Raumdiskretisierung erfolgt mittels der Finite-Volumen-Methode. Der steife Teil wird mit Hilfe von finiter Differenzen oder au eine acht mehrdimensional Art und Weise approximniert. Zur mehrdimensionalen Approximation verwenden wir approximative Evolutionsoperatoren, die alle unendlich viele Informationsausbreitungsrichtungen berücksichtigen. Die expliziten Terme werden mit gewöhnlichen numerischen Flüssen approximiert. Daher erhalten wir eine Stabilitätsbedingung analog zu einer rein advektiven Strömung, d.h. das Zeitinkrement vergrößert um den Faktor Kehrwert der Froude-Zahl. Die in dieser Arbeit hergeleiteten Verfahren sind asymptotisch erhaltend und ausbalanciert. Die asymptotischer Erhaltung stellt sicher, dass numerische Lösung das &amp;quot;korrekte&amp;quot; asymptotische Verhalten bezüglich kleiner Froude-Zahlen besitzt. Wir präsentieren Verfahren erster und zweiter Ordnung. Numerische Resultate bestätigen die Konvergenzordnung, so wie Stabilität, Ausbalanciertheit und die asymptotische Erhaltung. Insbesondere beobachten wir bei machen Verfahren, dass die Konvergenzordnung fast unabhängig von der Froude-Zahl ist.
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The Multiple Affect Adjective Check List (MAACL) has been found to have five first-order factors representing Anxiety, Depression, Hostility, Positive Affect, and Sensation Seeking and two second-order factors representing Positive Affect and Sensation Seeking (PASS) and Dysphoria. The present study examines whether these first- and second-order conceptions of affect (based on R-technique factor analysis) can also account for patterns of intraindividual variability in affect (based on P-technique factor analysis) in eight elderly women. Although the hypothesized five-factor model of affect was not testable in all of the present P-technique datasets, the results were consistent with this interindividual model of affect. Moreover, evidence of second-order (PASS and Dysphoria) and third-order (generalized distress) factors was found in one data set. Sufficient convergence in findings between the present P-technique research and prior R-technique research suggests that the MAACL is robust in describing both inter- and intraindividual components of affect in elderly women.
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Focusing optical beams on a target through random propagation media is very important in many applications such as free space optical communica- tions and laser weapons. Random media effects such as beam spread and scintillation can degrade the optical system's performance severely. Compensation schemes are needed in these applications to overcome these random media effcts. In this research, we investigated the optimal beams for two different optimization criteria: one is to maximize the concentrated received intensity and the other is to minimize the scintillation index at the target plane. In the study of the optimal beam to maximize the weighted integrated intensity, we derive a similarity relationship between pupil-plane phase screen and extended Huygens-Fresnel model, and demonstrate the limited utility of maximizing the average integrated intensity. In the study ofthe optimal beam to minimize the scintillation index, we derive the first- and second-order moments for the integrated intensity of multiple coherent modes. Hermite-Gaussian and Laguerre-Gaussian modes are used as the coherent modes to synthesize an optimal partially coherent beam. The optimal beams demonstrate evident reduction of scintillation index, and prove to be insensitive to the aperture averaging effect.
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Jakobshavn Isbrae is a major ice stream that drains the west-central Greenland ice sheet and becomes afloat in Jakobshavn Isfiord (69degreesN, 49degreesW), where it has maintained the world's fastest-known sustained velocity and calving rate (7 km a(-1)) for at least four decades. The floating portion is approximately 12 km long and 6 km wide. Surface elevations and motion vectors were determined photogrammetrically for about 500 crevasses on the floating ice, and adjacent grounded ice, using aerial photographs obtained 2 weeks apart in July 1985. Surface strain rates were computed from a mesh of 399 quadrilateral elements having velocity measurements at each corner. It is shown that heavy crevassing of floating ice invalidates the assumptions of linear strain theory that (i) surface strain in the floating ice is homogeneous in both space and time, (ii) the squares and products of strain components are nil, and (iii) first- and second-order rotation components are small compared to strain components. Therefore, strain rates and rotation rates were also computed using non-linear strain theory. The percentage difference between computed linear and non-linear second invariants of strain rate per element were greatest (mostly in the range 40-70%) where crevassing is greatest. Isopleths of strain rate parallel and transverse to flow and elevation isopleths relate crevassing to known and inferred pinning points.
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Ocean Drilling Program Legs 127 and 128 in the Japan Sea have revealed the existence of numerous dark-light rhythms of remarkable consistency in sediments of late Miocene, latest Pliocene, and especially Pleistocene age. Light-colored units within these rhythms are massive or bioturbated, consist of diatomaceous clays, silty clays, or nannofossil-rich clays, and are generally poor in organic matter. Dark-colored units are homogeneous, laminated, or thinly bedded and include substantial amounts of biogenic material such as well-preserved diatoms, planktonic foraminifers, calcareous nannofossils, and organic matter (maximum 7.4 wt%). The dark-light rhythms show a similar geometrical pattern on three different scales: First-order rhythms consist of a cluster dominated by dark-colored units followed by a cluster dominated by light-colored units (3-5 m). Spectral analysis of a gray-value time series suggests that the frequencies of the first-order rhythms in sediments of latest Pliocene and Pleistocene age correlate to the obliquity and the eccentricity cycles. The second-order dark-light rhythms include a light and a dark-colored unit (10-160 cm). They were formed in time spans of several hundred to several ten thousand years, with variance centering around 10,500 yr. This frequency may correspond to half the precessional cycle. Third-order rhythms appear as laminated or thinly bedded dark-light couplets (2-15 mm) within the dark-colored units of the second-order rhythms and may represent annual frequencies. In interpreting the rhythms, we have to take into account that (1) the occurrence of the first- and second-order rhythms is not necessarily restricted to glacial or interglacial periods as is shown by preliminary stable-isotope analysis and comparison with the published d18O record; (2) they appear to be Milankovitch-controlled; and (3) a significant number of the rhythms are sharply bounded. The origin of the dark-light rhythms is probably related to variations in monsoonal activity in the Japan Sea, which show annual frequencies, but also operates in phase with the orbital cycles.
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The aim of the present work is to provide an in-depth analysis of the most representative mirroring techniques used in SPH to enforce boundary conditions (BC) along solid profiles. We specifically refer to dummy particles, ghost particles, and Takeda et al. [Prog. Theor. Phys. 92 (1994), 939] boundary integrals. The analysis has been carried out by studying the convergence of the first- and second-order differential operators as the smoothing length (that is, the characteristic length on which relies the SPH interpolation) decreases. These differential operators are of fundamental importance for the computation of the viscous drag and the viscous/diffusive terms in the momentum and energy equations. It has been proved that close to the boundaries some of the mirroring techniques leads to intrinsic inaccuracies in the convergence of the differential operators. A consistent formulation has been derived starting from Takeda et al. boundary integrals (see the above reference). This original formulation allows implementing no-slip boundary conditions consistently in many practical applications as viscous flows and diffusion problems.
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No tenemos conocimiento de ninguna red de caminos prerromanos que sirvieran como base de una posible malla territorial de España. Sin embargo, una sociedad prerromana sin caminos, por muy fragmentada y aislada que fuera, es algo improbable y mucho menos en la Edad del Hierro. Por eso en época prerromana existían infinidad de caminos, muchos de los cuales hoy han desaparecido y otros han sobrevivido, casi siempre con sus recorridos mejorados. Los pueblos prerromanos aprovecharon vías naturales de comunicación (ríos, vados, valles, puertos naturales, llanuras, etc.) para tender sus caminos. En sus orígenes no siguieron pautas concretas, si no que los caminos se originaban por el tránsito (de personas, ganados, mercancías, etc.) de un lugar a otro. De este modo la red viaria prerromana era caótica y anárquica: todo camino tenía numerosos ramales y variantes, según las necesidades. Pendientes excesivas, anchuras variables, etc., en decir eran vías espontáneas, surgidas sin ninguna planificación aparente. Los recorridos en general eran cortos, aunque algunas investigaciones actuales están demostrando que algunas de las cañadas ganaderas más importantes, como la Galiana, y de largo recorrido, eran de origen prerromano. En el caso de la península Ibérica, y más concretamente en el caso de la Meseta, el territorio estaba fragmentado en diversos pueblos y tribus, agrupados según criterios étnicos y culturales y con contactos con los pueblos próximos que motivan la preponderancia de caminos de recorrido cortos. Solo la necesidad de llevar los rebaños (de cabras y ovejas sobre todo) desde las serranías en verano a las llanuras en invierno, motivaría viajes más largos en los que algunas cañadas ganaderas jugarían un papel más importante. Con la llegada de los romanaos, se implantó en Hispania una densa red viaria, cuya construcción se prolongó durante toda la dominación romana, siendo reparadas muchas calzadas y vías en varias ocasiones. En época romana la red caminera era variada y estaba constituida por “las calzadas” que comunicaban puntos importantes, eran muy transitadas, de ahí que la administración romana las mantuviera siempre en buen estado, para asegurar el intercambio comercial entre zonas distintas, cobro de impuestos, etc. “Los caminos de tierra (viae terrenae)” que además de las calzadas, que podemos asemejar a las actuales carreteras de primer y segundo orden, constituían la infinidad de caminos locales y comarcales. Los trazados se realizaron unos en época romana, y otros muchos apoyándose en los caminos de la época prerromana, éstas vías no se realizaban buscando el recorrido más corto entre dos puntos, ni tampoco el más cómodo y con un firme estructural de menor importancia que en las calzadas. Tampoco estaban hechos para un tipo concreto de transporte, por lo que nos encontraríamos algunos que por su anchura permitían el paso de carros, y otros que sólo permitirían el paso a pie, a caballo o en burro. Solían ser, como hemos indicado, caminos de tierra con acabados en zahorras y recorridos en su mayor parte cortos y medianos. Dentro de la malla territorial de España las calzadas constituirían las denominadas “viae publicae” que constituían la red principal y esqueleto vertebrador de Hispania. Los caminos de tierra constituirían los denominados “actus” caminos de carácter regional que configuraban la mayor parte de la red. Muchas de las “viae publicae” y de los “actus” tendrían su origen en las “viae militares” que habrían sido los primeros construidos, apoyándose en muchas ocasiones en los caminos prerromanos, por los romanos para realizar la conquista de Hispania y que luego con la Paz romana habrían tenido otro tipo de uso. Dentro de estas “viae militares” tuvieron una importancia relevancia aquellas que se utilizaron en la conquista de la Celtiberia, culminada con la caída de Numantia. Dentro de ellas tuvo una importancia fundamental la vía romana del río Alhama, objeto de esta Tesis, que facilitaría el desplazamiento de los ejércitos romanos desde Graccurris, primera ciudad romana fundada en el Ebro medio, hasta Numantia. Desde la época Augusta, la vía romana del río Alhama, pasaría a formar parte de los denominados “actus” formando parte de la malla territorial de la Península Ibérica como vía de comunicación entre la Meseta y el Ebro Medio. We do not have knowledge of any network of ways prerromanos that were serving as base of a possible territorial mesh of Spain. Nevertheless, a company prerromana without ways, for very fragmented and isolated that was, is something improbable and great less in the Age of the Iron. Because of it in epoch prerromana existed infinity of ways, many of which today have disappeared and others have survived, almost always with his improved tours. The people prerromanos took advantage of natural routes of communication (rivers, fords, valleys, natural ports, plains, etc.) to stretch his ways. In his origins concrete guidelines did not continue, if not that the ways were originating for the traffic (of persons, cattle, goods, etc.) to and from. Thus the network viaria prerromana was chaotic and anarchic: all way had numerous branches and variants, according to the needs. Excessive slopes, variable widths, etc., in saying were spontaneous routes arisen without no apparent planning. The tours in general were short, though some current investigations are demonstrating that some of the most important cattle glens, as the Galiana, and of crossed length, were of origin prerromano. In case of the Iberian Peninsula, and more concretely in case of the Plateau, the territory was fragmented in diverse peoples and tribes, grouped according to ethnic and cultural criteria and with contacts with the near peoples that motivate the prevalence of short ways of tour. Only the need to take the flocks (of goats and sheeps especially) from the mountainous countries in summer to the plains in winter, would motivate longer trips in which some cattle glens would play a more important paper. With the arrival of the romanos, a dense network was implanted in Roman Spain viaria, whose construction extended during the whole Roman domination, being repaired many causeways and routes in several occasions. In Roman epoch the pertaining to roads network was changed and constituted by " the causeways " that were communicating important points, they were very travelled, of there that the Roman administration was supporting always in good condition, to assure the commercial exchange between different zones, collection of taxes, etc. "The dirt tracks (viae terrenae)" that besides the causeways, which we can make alike to the current roads of the first and second order, were constituting the infinity of local and regional ways. The tracings were realized some in Roman epoch, and great others resting on the ways of the epoch prerromana, these routes were not realized looking for the most short tour neither between points, two nor neither most comfortable and with a structural road surface of minor importance that in the causeways. They were not also done for a concrete type of transport, for what some of us would think that for his width they were allowing the step of cars, and others that only would allow the step afoot, astride or in donkey. They were in the habit of being, since we have indicated, dirt tracks with ended in zahorras and tours in his most short and medium. Inside the territorial mesh of Spain the causeways would constitute the called ones "viae publicae" that constituted the principal network and skeleton vertebrador of Roman Spain. The dirt tracks would constitute the "actus” called ways of regional character that were forming most of the network. Many of "viae publicae" and of the "actus" they would have his origin in " viae military" that would have been the first ones constructed, resting on many occasions on the ways prerromanos, for the Romans to realize the conquest of Roman Spain and that then with the Roman Peace they would have had another type of use. Inside these "viae military" had an importance relevancy those that were in use in the conquest of the Celtiberia, reached with Numantia's fall. Inside them a fundamental importance had the Roman route of the river Alhama, object of this Thesis, which would facilitate the displacement of the Roman armies from Graccurris, the first Roman city been founded on the average Ebro, up to Numantia. From the August epoch, the Roman route of the river Alhama, would happen to form a part of the "actus” forming a part of the territorial mesh of the Iberian Peninsula as road link between the Plateau and the Average Ebro.