ANALYSIS, MODIFICATION, AND EVALUATION OF THE COLD FLOW PROPERTIES OF VEGETABLE OILS AS BASE OIL FOR INDUSTRIAL LUBRICANTS

Poor cold flow properties of vegetable oils are a major problem preventing the usage of many abundantly available vegetable oils as base stocks for industrial lubricants. The major objective of this research is to improve the cold flow properties of vegetable oils by various techniques like additive addition and different chemical modification processes. Conventional procedure for determining pour point is ASTM D97 method. ASTM D97 method is time consuming and reproducibility of pour point temperatures is poor between laboratories. Differential Scanning Calorimetry (DSC) is a fast, accurate and reproducible method to analyze the thermal activities during cooling/heating of oil. In this work coconut oil has been chosen as representative vegetable oil for the analysis and improvement cold flow properties since it is abundantly available in the tropics and has a very high pour point of 24 °C. DSC is used for the analysis of unmodified and modified vegetable oil. The modified oils (with acceptable pour points) were then subjected to different tests for the valuation of important lubricant properties such as viscometric, tribological (friction and wear properties), oxidative and corrosion properties.A commercial polymethacrylate based PPD was added in different percentages and the pour points were determined in each case. Styrenated phenol(SP) was added in different concentration to coconut oil and each solution was subjected to ASTM D97 test and analysis by DSC. Refined coconut oil and other oils like castor oil, sunflower oil and keranja oil were mixed in different proportions and interesterification procedure was carried out. Interesterification of coconut oil with other vegetable oils was not found to be effective in lowering the pour point of coconut oil as the reduction attained was only to the extent of 2 to 3 °C.Chemical modification by acid catalysed condensation reaction with coconut oil castor oil mixture resulted in significant reduction of pour point (from 24 ºC to -3 ºC). Instead of using triacylglycerols, when their fatty acid derivatives (lauric acid- the major fatty acid content of coconut oil and oleic acid- the major fatty acid constituents of monoand poly- unsaturated vegetable oils like olive oil, sunflower oil etc.) were used for the synthesis , the pour point could be brought down to -42 ºC. FTIR and NMR spectroscopy confirmed the ester structure of the product which is fundamental to the biodegradability of vegetable oils. The tribological performance of the synthesised product with a suitable AW/EP additive was comparable to the commercial SAE20W30 oil. The viscometric properties (viscosity and viscosity index) were also (with out additives) comparable to commercial lubricants. The TGA experiment confirmed the better oxidative performance of the product compared to vegetable oils. The sample passed corrosion test as per ASTM D130 method.

Thermal Processing of Smoked Yellowfin Tuna (Thunnus albacares) in Flexible Pouches

This study is the first of its kind in India, where in smoked and thermal processed products have been developed using locally available wood as the source of wood smoke and flavoring and a shelf life of one year has been achieved. Retortable pouches of three layers, both imported and indigenous were found suitable to store thermal processed products. Heat penetration rate is quicker in retort pouches due to their thin profile in comparison to cans and hence the total process time is lesser. The nutritional and sensory attributes of the pouch products are better retained during processing. Hence these products are more acceptable than canned products. lndian vegetarian food products and fish curry products are available in the ready to eat form in the markets. Smoked and thermal processed products have not gained an entry to the market and hence this study will pave an opening for such products. Currently trade in tuna products from India is meager compared to the global trade. ln India proper utilization of tuna resources is yet to be achieved due to the lack of infrastructure for handling and knowledge of value addition. The raw material cost is also less due to the poor quality of the fish when landed. Hence, the availability of such products will help in the trade of tuna products, improving the quality of raw material landing and ultimately realizing a better value to the fishermen and processors.

The Cold Tongue in the South China Sea during Boreal Winter and Its Interaction with the Atmosphere

A distinct cold tongue has recently been noticed in the South China Sea during the winter monsoon, with the cold tongue temperature minimum occurring in the January or February. This cold tongue shows signi¯cant links with the Maritime Continent's rainfall during the winter period. The cold tongue and its interaction with the Maritime Continent's weather were studied using Reynolds SST data, wind ¯elds from the NCEP{NCAR reanalysis dataset and the quikSCAT dataset. In addition, rainfall from the GOES Precipitation Index (GPI) for the periods 2000 to 2008 was also used. The propagation of the cold tongue towards the south is explained using wind dynamics and the western boundary current. During the period of strong cold tongue, the surface wind is strong and the western boundary current advects the cold tongue to the south. During the period of strong winds the zonal gradient of SST is high [0.5±C (25 km)¡1]. The cold tongue plays an important role in regulating the climate over the Maritime Continent. It creates a zonal/meridional SST gradient and this gradient ultimately leads in the formation of convection. Hence, two maximum precipitation zones are found in the Maritime Continent, with a zone of relatively lower precipitation between, which coincides with the cold tongue's regions. It was found that the precipitation zones have strong links with the intensity of the cold tongue. During stronger cold tongue periods the precipitation on either side of the cold tongue is considerably greater than during weaker cold tongue periods. The features of convection on the eastern and western sides of the cold tongue behave di®erently. On the eastern side convection is preceded by one day with SST gradient, while on the western side it is four days.

Characterisation and bioprospecting of cold adapted yeast from water samples of kongsfjord ,Norwegian Artic

A total of 34 yeast isolates were characterized from 4 water samples collected from Kongsfjord at Ny Alseund region of Norwegion Artic during the Indian Artic summer expedition of 2009.They were studied for the effect of tempereture and salt concentration on growth as well as for their ability to produce various hydrolytic enzymes at two different temperatures. Result showed that 5 out of 8 genera were common to all the stations. Cryptococcus was the predominant genera folowed by Trichosporan and Rhodotorula 82% of the yeast isolates were oxidative in nature and except filobasidium all the isolates used nitrate as a nitrogen source for growth. Yeast isolates from all the ststions showed growth at 4 and 20 degree centigarade. These temperatures were chosen as most of the bacterial and yeast isolates showed psychrotrop[hic nature. 94% of the yeast isolates showed growth at 2.0M and lipolytic activity were marginally less than 4.None of the isolates produced amylase enzymes when incubated at 4 and 20. The present study highlights the wide tolerence of the psychrotrophic yeast isolates to temperature and salinity as well as their potential in biotechnology

The Political Ecology of Salmon Aquaculture in Chile

Every German consumes per year, 15% is salmon, which is the third most popular fish in Germany after Alaska-Seelachs and Hering (Keller/Kress 2013: 9). But where does the salmon that ends up on our plates every 6th time we eat fish come from? There's no obligation for producers to declare the origin of their fish products, but if they do so, the latin name of the fish, catching method and catch area should be declared. Salmon, of which about 40% are captured in the wild and the rest brought up in aquacultures, could then be declared as follows: Salmon (salmo salar), aquaculture from Chile. Without any doubt, this makes consumption more transparent, but the standards of production – both, social and ecological ones – and the ecological impacts are still kept in the dark.

Femtosecond wavepacket interferometry using the rotational dynamics of a trapped cold molecular ion

A Ramsey-type interferometer is suggested, employing a cold trapped ion and two time-delayed offresonant femtosecond laser pulses. The laser light couples to the molecular polarization anisotropy, inducing rotational wavepacket dynamics. An interferogram is obtained from the delay dependent populations of the final field-free rotational states. Current experimental capabilities for cooling and preparation of the initial state are found to yield an interferogram visibility of more than 80%. The interferograms can be used to determine the polarizability anisotropy with an accuracy of about ±2%, respectively ±5%, provided the uncertainty in the initial populations and measurement errors are confined to within the same limits.

Cold mountain : filme y novela. La tradición clásica en una historia de la Guerra de Secesión.

Resumen en inglés

Hot and cold.

Se explican las causas de la energía térmica. Se introducen temas como la fricción, las reacciones químicas, la temperatura, el termómetro, las escalas Fahrenheit y Celsius y se explican los conductores, aisladores, y la radiación. Para aprender cómo el Sol calienta la Tierra, la forma en que afecta a nuestro clima, y cómo las plantas y los animales necesitan este calor. Ofrece tres experimentos con explicaciones paso a paso para el aprendizaje por descubrimiento. Los experimentos hacen hincapié en la necesidad del niño de investigar. Hay glosario, bibliografía y direcciones de páginas webs para ampliar información.

Hot and cold poems.

Esta selección de poesía se ha elegido para que coincida con temas de interés para el grupo de edad: caliente y frío. Aunque los poemas son completamente independientes de otras historias, pueden ser introducidos junto con libros de cuentos. Destinado a escuelas infantiles, puede utilizarse para el trabajo curricular transversal, así como para la enseñanza de la lectura y el disfrute de la poesía, ritmo y rima. Desarrolla en los niños habilidades fonológicas y el conocimiento de la rima y los introduce en la poesía desde las primeras etapas de la lectura. Ofrece orientación para hablar y escuchar, con especial atención a la lectura en voz alta.

I wonder why the Sahara is cold at night : and other questions about deserts.

Trata de despertar la curiosidad de los jóvenes lectores al ofrecer una pequeña introducción sobre el desierto y sus características climáticas y físicas, así como sobre la flora y la fauna que vive en este medio tan adverso.También, se habla de curiosidades relacionados con el desierto:los pueblos que lo habitan y sus construcciones y ciudades; así como, el tipo de energía que proporciona.

The cold war : superpower relations, 1945-1989.

Desde el final de la Segunda Guerra Mundial y hasta 1990, las relaciones internacionales estuvieron dominadas por este peligroso conflicto, durante el cual tanto los países comunistas como no comunistas luchaban por el dominio del mundo. Para conseguirlo, desarrollaron armas nucleares de destrucción masiva. En varias ocasiones, esta amenaza de guerra fría se intensificó y, dio lugar a episodios críticos en diferentes países, que pudieron iniciar una tercera guerra. Incluye fragmentos de fuentes históricas originales, así como, material de aprendizaje activo: ejercicios, preguntas, y pruebas.

Cold war : 1945-1991.

Se estudian los orígenes de la Guerra Fría, iniciada tras la conferencia de Yalta en 1945. Fue un conflicto entre Estados Unidos y sus aliados, por una parte y la URSS (Unión de Repúblicas Socialistas Soviéticas) y sus aliados, por otra. No supusó un enfrentamiento directo entre los dos países, sino un período sostenido de tensión internacional, que finalizó con la caída de la URRS en 1991. Durante este tiempo, los dos países eran potencias económicas, a nivel mundial y, superpotencias por su inmensa fuerza militar. Incluye prácticas adecuadas para exámenes del General Certificate Secondary Education (GCSE) en sus especificaciones para AQA, EDEXCEL y OCR.

The USA and the Cold War in Asia, 1945-75.

Cumple con los requisitos para la especificación OCR AS de Historia, unidad F964 sobre 'Investigaciones', opción A. Su contenido examina el papel cambiante, las políticas y estrategias de Estados Unidos durante la Guerra Fría en el Sudeste asiático, las cuales no pueden entenderse sin establecer un trasfondo histórico marcado por la alianza de las dos superpotencias durante la Segunda Guerra Mundial, que después se convirtieron en enemigas en Europa y Asia. Cada capítulo contiene actividades para ayudar a la comprensión del tema y desarrollar habilidades con la historia, análisis de acontecimientos relevantes, de debates y controversias, breves biografías de personas clave de la época y definiciones de palabras nuevas.

M??s all?? del modelo de Salmon : puesta en pr??ctica de estrategias de planificaci??n y moderaci??n de foros de debate

Monogr??fico con el t??tulo: 'Tutor??a virtual y e-moderaci??n en red'. Resumen basado en el de la publicaci??n