地震采集观测系统的共聚焦分析

Focal beam analysis is a method for assessment of acquisition geometries that is directly linked to pre-stack migration. About dealing with the complex subsurface structures, the conventional survey design methods which do not take into account the subsurface are no longer valid. Based on the Fourier finite-difference (FFD) large-step wave field extrapolation and Born-Kirchhoff (BK) small-step wavefield interpolation, the thesis presents a rapid resolution analysis of 3D seismic survey design by focal beams in complicated media. Subsequently, The SEG/EAEG salt model is used to illustrate the method. Based on the focal beam resolution definition, each kind of influence factor is discussed. The focal beam analysis usually is carried out in a single frequency, but the actual seismic waves always contain a frequency bandwidth. In this thesis, theoretical relationship between focal beam analysis and frequency is derived. Since the effects of focal beam analysis are linear with frequency simply, the multi-frequency focal beam analysis using interpolation is developed. At the same time, the resolution of different frequency bandwidth is interconvertible in accordance with Signal uncertainty principle. The resolution of all frequency bands can be calculated by using only a few focal beam analysis for a seismic survey. In the last section of this thesis, I propose a new approach to predicting acquisition footprint, based on the assumption of Common-Middle-Point stack without constructing a special velocity model. The approach is a simplistic analytical method in which the acquisition footprint pattern is a weighted, linear summation of limited-offset fold-of-stack plots. Because the value of acquisition can be got by quantificational and rapidly calculating, we can exactly do a comparative analysis among different plans of seismic survey by this method.

块体理论赤平投影解析法与关键块体滑落概率研究—以锦屏二级水电站皮带机隧道为例

Block theory is an effective method on stability analysis of fractured rigid rock mass. There are a lot of discontinuous planes developed in rock mass of Jinping II hydropower station conveyor tunnel, so the stability of conveyor tunnel is related with whether there are unstable blocks on excavation planes. This paper deals with the stability of conveyor tunnel with stereo-analytical method for block theory on the basis of detailed investigation of rock mass data, and makes judgements on the movable blocks sliding types which are induced by all rock discontinuous planes and every excavation plane of conveyor tunnel. A conclusion is obtained that the sliding type of blocks is mainly single sliding, and a relatively few sliding types of double-sided sliding and vertical block falling; Also, the obvious statistical distribution result on movable blocks in conveyor tunnel indicates that there are a bit more instability blocks in left wall, left and right arches than right wall. In this paper, the stochastic probability model is drawn into block theory to study the sliding probability of key block on the basis of detailed investigation of its rock mass data and the development of the discontinuous planes in rock mass of Jinping II hydropower station conveyor tunnel. And some following conclusions are obtained. The relationship between trace length and the probability of instability of key block is inverse ratio. The probability of 1-3m primary joints are relatively higher. Key block containing joints J2 is relatively stable and the reinforcement of the arch would be crucial in the conveyor tunnel. They are all useful to offer effective reinforcement design and have important engineering values.

软土亚塑性模型与一维非线性固结理论研究

With the great development of Tianjing New Coastal District economy, people need more land to build and live. Land subsidence, which is caused by its special engineering geological conditions, has restricted the further development in the district. Soft soil consolidation is main factor of land subsidence ;thus , on the basis of consolidation theory, the paper make further study on soft soils one-dimension nonlinear consolidation which contains two parts:(1) the nonlinear consolidation of permeability coefficient and compressibility coefficient changing with time and depth, which means real one-dimension nonlinear consolidation;(2) the non-homogeneous consolidation of permeability coefficient and compressibility coefficient only changing with depth. Firstly, nonlinear characteristics of soft soils are elaborated. Hypoplastic theory is introduced to establish a modified soft soils nonlinear constitutive model; the nonlinear governing equation of compressibility coefficient is built, and the nonlinear characteristics of compressibility coefficient are analyzed. Secondly, Considering Load Fluctuation and soil thickness changing ,the consolidation characteristics of single layer is discussed in the paper; meanwhile, on the basis of the Davis and Raymond’s hypothesis and single layer nonlinear consolidation equation, the doubled-layer one-dimension nonlinear consolidation equation is also derived. The solution of the equation is obtained by analytical method, and the consolidation characteristics of doubled-layer soft soil nonlinear theory is also analyzed. Finally, based on assumption that permeability coefficient and compressibility coefficient is varying along depth, single layer soil one-dimension non-homogeneous consolidation differential equation is derived; and the approximate solution is obtained. Furthermore, the single layer non-homogeneous consolidation is extended to double layer non-homogeneous consolidation theory. By using parabolic differential scheme, the matrix equation is established; and the solution of the matrix equation is obtained by chase method. Consolidation characteristics of soil soft single (double) layer non-homogeneous consolidation theory and Terzaghi’s theory are also discussed.

铂族元素分析方法研究及其在有关地质问题中的应用

Characterization of Platinum Group Elements (PGE) has been applied to earth, space and environmental sciences. However, all these applications are based on a basic prerequisite, i.e. their concentration or ratio in the research objects can be accurately and precisely determined. In fact, development in these related studies is a great challenge to the analytical chemistry of the PGE because their content in the geological sample (non-mineralized) is often extremely low, range from ppt (10~(-12)g/g) to ppt (10~(-9)g/g). Their distribution is highly heterogeneous, usually concentrating in single particle or phase. Therefore, the accurate determination of these elements remains a problem in analytical chemistry and it obstructs the research on geochemistry of PGE. A great effort has been made in scientific community to reliable determining of very low amounts of PGE, which has been focused on to reduce the level of background in used reagents and to solve probable heterogeneity of PGE in samples. Undoubtedly, the fire-assay method is one of the best ways for solving the heterogeneity, as a large amount of sample weight (10-50g) can be hold. This page is mainly aimed at development of the methodology on separation, concentration and determination of the ultra-trace PGE in the rock and peat samples, and then they are applied to study the trace of PGE in ophiolite suite, in Kudi, West Kunlun and Tunguska explosion in 1908. The achievements of the study are summarized as follows: 1. A PGE lab is established in the Laboratory of Lithosphere Tectonic Evolution, IGG, CAS. 2. A modified method of determination of PGE in geological samples using NiS Fire-Assay with inductively coupled plasma-mass spectrometry (ICP-MS) is set up. The technical improvements are made as following: (1) investigating the level of background in used reagents, and finding the contents of Au, Pt and Pd in carbonyl nickel powder are 30, 0.6 and 0.6ng/g, respectively and 0.35, 7.5 and 6.4ng, respectively in other flux, and the contents of Ru, Rh, Os in whole reagents used are very low (below or near the detection limits of ICP-MS); (2) measuring the recoveries of PGE using different collector (Ni+S) and finding 1.5g of carbonyl nickel is effective for recovering the PGE for 15g samples (recoveries are more than 90%), reducing the inherent blank value due to impurities reagents; (3) direct dissolving nickel button in Teflon bomb and using Te-precipitation, so reducing the loss of PGE during preconcentration process and improving the recoveries of PGE (above 60% for Os and 93.6-106.3% for other PGE, using 2g carbonyl nickel); (4) simplifying the procedure of analyzing Osmium; (5)method detection limits are 8.6, 4.8, 43, 2.4, 82pg/g for 15g sample size ofRu, Rh, Pd, Ir, Pt, respectively. 3. An analytical method is set up to determine the content of ultra-trace PGE in peat samples. The method detection limits are 0.06, 0.1, 0.001, 0.001 and 0.002ng/mL for Ru, Rh, Pd, Ir and Pt, respectively. 4. Distinct anomaly of Pd and Os are firstly found in the peat sampling near the Tunguska explosion site, using the analytical method. 5. Applying the method to the study on the origin of Tunguska explosion and making the following conclusions: (1) these excess elements were likely resulted from the Tunguska Cosmic Body (TCB) explosion of 1908. (2) The Tunguska explosive body was composed of materials (solid components) similar to C1 chondrite, and, most probably, a cometary object, which weighed more than 10~7 tons and had a radius of more than 126 m. 6. The analysis method about ultra-trace PGE in rock samples is successfully used in the study on the characteristic of PGE in Kudi ophiolite suite and the following conclusions are made: (1) The difference of the mantle normalization of PGE patterns between dunite, harzburgite and lherzolite in Kudi indicates that they are residual of multi-stage partial melt of the mantle. Their depletion of Ir at a similar degree probably indicates the existence of an upper mantle depleted Ir. (2) With the evolution of the magma produced by the partial melt of the mantle, strong differentiation has been shown between IPGE and PPGE; and the differentiation from pyroxenite to basalt would have been more and more distinct. (3) The magma forming ophiolite in Kudi probably suffered S-saturation process.

水库滑坡复活机理及其发展趋势预测研究

Various numbers of ancient landslides of various scales are frequently distributed on both banks of reservoirs, especially large reservoirs, both in China and abroad. During inundation and operation of theses reservoirs, some of the landslides are reactivated, which caused losses of people's lives and properties to various extents, some even disasters. Systematic studies are, however, very few on the reservoir-induced reactivation mechanism and development tendency prediction. Based on investigation of reservoir-induced reactivation phenomena of ancient landslides and relevant existing research problems, a systematic study is carried out on the field identification, induced reactivation mechanism, development tendency prediction, risk decision-making and treatment of reservoir-related ancient landslides, through analysis of large numbers of engineering geological investigation results, scientific experimental and research results, in combination with prevention and treatment practices of reservoir-related landslides both in China and abroad, and a series of research results have been obtained. 1. On the basis of study of the distribution features, genesis mechanism of ancient landslides on river banks, a set of scientific methods are summarized on field identification of ancient landslides, and a significant method named "lithologic sequence method" or "indicator layer method", is proposed, which is proved to be very useful. 2. A detail study is made on the reservoir-induced hydraulic effects and material mechanic effects (or softening effects) on the ancient landslide through model and case studies, which concludes that the magnitude and properties of reservoir-induced hydraulic effects are related to the shapes of sliding planes, water content and permeability of landslide materials and variation rate and magnitude of reservoir levels; the magnitude of material mechanic effects are related to the material composition (including mineral composition and grain size), natural water content and saturation state of sliding zones. Also a sensitive analysis is made on the factors that are related to the stabilities of the landslides, which indicate that the stability of a landslide is more sensitive to the groundwater head h_w in the slides and the inner friction angleψof sliding zones than others. 3. The joint inducing mechanism of rainfall and reservoir is also discussed in the paper through model analysis and case study, which proves that reservoir inundation increases firstly the sensitivity of a landslides to rainfall through reduction of its stability or cracking deformation which will increase the rainfall infiltration to the slide body, and then rainfall triggers reactivation or intensifies the reservoir-induced deformation of a landslide. 4. Based on rheologic test results of sliding zones of several reservoir-related ancient landslides, the rheologic characteristics of sliding zones have been discussed in detail and several typical rheologic models have been set up, which well explains the dynamic process of slide deformation. The response types to reservoir inundation and development tendency of reservoir -related ancient landslide are discussed in the paper based on field investigation results. And prediction methods for reservoir-related landslides have been studied based on the Mate-Synthetic principle of quantitative and qualitative analysis, as well as combination of computation and internal mechanism analysis, and a rheologic analytical method is proposed which is proved very useful for prediction of the landslide development tendency. 6. In disaster-prevention and treatment of reservoir-related landslides, risk decision-making has been proved very significant both in engineering and economics. Based on the practices in disaster-prevention and treatment of reservoir-related landslides both in China and abroad, the disaster-prevention risk decision-making for reservoir-related landslides has been proposed in terms of philosophy, methods and procedures, and well put into practice. A summary is also made through case study of the experiences of treatment of reservoir-related landslides both in China and abroad in terms of principle, methods and technical lines. 7 A detail study is made as a case study of the reactivated Maoping ancient landslide on the left bank of the Geheyan Reservoir on Qingjiang river in Hubei province, China, including its field identification features, reservoir-induced reactivation characteristics and mechanism, development tendency prediction and proposed counter measures based on risk analysis.

Prediction of GC retention values under various column temperature conditions from temperature programmed data

A numerical approach has been developed for the correlation of retention limes (total retention lime) with temperature in gas chromatography, which allows the calculation of retention parameters including retention index from data acquired under two or more different temperature program conditions. By using this procedure the optimization of temperature condition can be further achieved, especially when a temperature-programmed run is the most suitable mode in the preliminary development of an analytical method for the analysis of an unknown sample.

Molecular dynamics-based approach to study the anisotropic self-diffusion of molecules in porous materials with multiple cage types: Application to H-2 in losod

Van den Berg, A. W. C., Flikkema, E., Lems, S., Bromley, S. T., Jansen, J. C. (2006). Molecular dynamics-based approach to study the anisotropic self-diffusion of molecules in porous materials with multiple cage types: Application to H-2 in losod. Journal of physical chemistry b, 110 (1), 501-506. RAE2008

Spatial distribution of upland beetles in relation to landform, vegetation and grazing management

Dennis, P., Aspinall, R. J., Gordon, I. J. (2002). Spatial distribution of upland beetles in relation to landform vegetation and grazing management. Basic and Applied Ecology, 3 (2), 183?193. Sponsorship: SEERAD RAE2008

A importância clínica da vitamina D

Projeto de Pós-Graduação/Dissertação apresentado à Universidade Fernando Pessoa como parte dos requisitos para obtenção do grau de Mestre em Ciências Farmacêuticas

Towards Eco-Dharma: The Contribution of Gandhian Thought to Ecological Ethics in India

Ecological concern prompts poor and indigenous people of India to consider how a society can ensure both protection of nature and their rightful claim for a just and sustainable future. Previous discussions defended the environment while ignoring the struggles of the poor for sustenance and their religious traditions and ethical values. Mohandas Karamchand Gandhi addressed similar socio-ecological concerns by adopting and adapting traditional religious and ethical notions to develop strategies for constructive, engaged resistance. The dissertation research and analysis verifies the continued relevance of the Gandhian understanding of dharma (ethics) in contemporary India as a basis for developing eco-dharma (eco-ethics) to link closely development, ecology, and religious values. The method of this study is interpretive, analytical, and critical. Françoise Houtart’s social analytical method is used to make visible and to suggest how to overcome social tensions from the perspective of marginalized and exploited peoples in India. The Indian government's development initiatives create a nexus between the eco-crisis and economic injustice, and communities’ responses. The Chipko movement seeks to protect the Himalayan forests from commercial logging. The Narmada Bachao Andolan strives to preserve the Narmada River and its forests and communities, where dam construction causes displacement. The use of Gandhian approaches by these movements provides a framework for integrating ecological concerns with people's struggles for survival. For Gandhi, dharma is a harmony of satya (truth), ahimsa (nonviolence), and sarvodaya (welfare of all). Eco-dharma is an integral, communitarian, and ecologically sensitive ethical paradigm. The study demonstrates that the Gandhian notion of dharma, implemented through nonviolent satyagraha (firmness in promoting truth), can direct community action that promotes responsible economic structures and the well-being of the biotic community and the environment. Eco-dharma calls for solidarity, constructive resistance, and ecologically and economically viable communities. The dissertation recommends that for a sustainable future, India must combine indigenous, appropriate, and small- or medium-scale industries as an alternative model of development in order to help reduce systemic poverty while enhancing ecological well-being.

Differentiated Control of Web Traffic: A Numerical Analysis

Internet measurements show that the size distribution of Web-based transactions is usually very skewed; a few large requests constitute most of the total traffic. Motivated by the advantages of scheduling algorithms which favor short jobs, we propose to perform differentiated control over Web-based transactions to give preferential service to short web requests. The control is realized through service semantics provided by Internet Traffic Managers, a Diffserv-like architecture. To evaluate the performance of such a control system, it is necessary to have a fast but accurate analytical method. To this end, we model the Internet as a time-shared system and propose a numerical approach which utilizes Kleinrock's conservation law to solve the model. The numerical results are shown to match well those obtained by packet-level simulation, which runs orders of magnitude slower than our numerical method.

Development of large-scale colloidal crystallisation methods for the production of photonic crystals

Colloidal photonic crystals have potential light manipulation applications including; fabrication of efficient lasers and LEDs, improved optical sensors and interconnects, and improving photovoltaic efficiencies. One road-block of colloidal selfassembly is their inherent defects; however, they can be manufactured cost effectively into large area films compared to micro-fabrication methods. This thesis investigates production of ‘large-area’ colloidal photonic crystals by sonication, under oil co-crystallization and controlled evaporation, with a view to reducing cracking and other defects. A simple monotonic Stöber particle synthesis method was developed producing silica particles in the range of 80 to 600nm in a single step. An analytical method assesses the quality of surface particle ordering in a semiquantitative manner was developed. Using fast Fourier transform (FFT) spot intensities, a grey scale symmetry area method, has been used to quantify the FFT profiles. Adding ultrasonic vibrations during film formation demonstrated large areas could be assembled rapidly, however film ordering suffered as a result. Under oil cocrystallisation results in the particles being bound together during film formation. While having potential to form large areas, it requires further refinement to be established as a production technique. Achieving high quality photonic crystals bonded with low concentrations (<5%) of polymeric adhesives while maintaining refractive index contrast, proved difficult and degraded the film’s uniformity. A controlled evaporation method, using a mixed solvent suspension, represents the most promising method to produce high quality films over large areas, 75mm x 25mm. During this mixed solvent approach, the film is kept in the wet state longer, thus reducing cracks developing during the drying stage. These films are crack-free up to a critical thickness, and show very large domains, which are visible in low magnification SEM images as Moiré fringe patterns. Higher magnification reveals separation between alternate fringe patterns are domain boundaries between individual crystalline growth fronts.

Plasmonic Nanoparticles and Nanowires: Design, Fabrication and Application in Sensing.

This study involves two aspects of our investigations of plasmonics-active systems: (i) theoretical and simulation studies and (ii) experimental fabrication of plasmonics-active nanostructures. Two types of nanostructures are selected as the model systems for their unique plasmonics properties: (1) nanoparticles and (2) nanowires on substrate. Special focus is devoted to regions where the electromagnetic field is strongly concentrated by the metallic nanostructures or between nanostructures. The theoretical investigations deal with dimers of nanoparticles and nanoshells using a semi-analytical method based on a multipole expansion (ME) and the finite-element method (FEM) in order to determine the electromagnetic enhancement, especially at the interface areas of two adjacent nanoparticles. The experimental study involves the design of plasmonics-active nanowire arrays on substrates that can provide efficient electromagnetic enhancement in regions around and between the nanostructures. Fabrication of these nanowire structures over large chip-scale areas (from a few millimeters to a few centimeters) as well as FDTD simulations to estimate the EM fields between the nanowires are described. The application of these nanowire chips using surface-enhanced Raman scattering (SERS) for detection of chemicals and labeled DNA molecules is described to illustrate the potential of the plasmonics chips for sensing.

Separating the scattering and absorption coefficients using the real and imaginary parts of the refractive index with low-coherence interferometry.

We present an analytical method that yields the real and imaginary parts of the refractive index (RI) from low-coherence interferometry measurements, leading to the separation of the scattering and absorption coefficients of turbid samples. The imaginary RI is measured using time-frequency analysis, with the real part obtained by analyzing the nonlinear phase induced by a sample. A derivation relating the real part of the RI to the nonlinear phase term of the signal is presented, along with measurements from scattering and nonscattering samples that exhibit absorption due to hemoglobin.

Modelling of dosator operation for improved manufacturing performance

Purpose: To develop an improved mathematical model for the prediction of dose accuracy of Dosators - based upon the geometry of the machine in conjunction with measured flow properties of the powder. Methods: A mathematical model has been created, based on a analytical method of differential slices - incorporating measured flow properties. The key flow properties of interest in this investigation were: flow function, effective angle of wall friction, wall adhesion, bulk density, stress ratio K and permeability. To simulate the real process and (very importantly) validate the model, a Dosator test-rig has been used to measure the forces acting on the Dosator during the filling stage, the force required to eject the dose and the dose weight. Results: Preliminary results were obtained from the Dosator test-rig. Figure 1 [Omitted] shows the dose weight for different depths to the bottom of the powder bed at the end of the stroke and different levels of pre-compaction of the powder bed. A strong influence over dose weight arising from the proximity between the Dosator and the bottom of the powder bed at the end of the stroke and the conditions of the powder bed has been established. Conclusions: The model will provide a useful tool to predict dosing accuracy and, thus, optimise the future design of Dosator based equipment technology – based on measured bulk properties of the powder to be handled. Another important factor (with a significant influence) on Dosator processes, is the condition of the powder bed and the clearance between the Dosator and the bottom of the powder bed.