Journal of the convention of the state of North-Carolina ...

[v. 1] Session of 1865.--[v. 2] Adjourned session of 1866.

Alabama as it is: or, The immigrant's and capitalist's guide book to Alabama. Furnishing the most accurate and detailed information concerning the varied elements of wealth in Alabama, whether of mine, field or forest, together with carefully prepared maps and charts illustrative of the numerous advantages possessed by the state.

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Proceedings of the Convention called for the Purpose of Organizing the New York State Bar Association

"Also, constitution and by-laws, rules and regulations of Executive Committee, act of incorporation, and list of members elect."

United States statutes at large : containing the laws and concurrent resolutions ... and reorganization plan, amendment to the Constitution, and proclamations.

Beginning in 1950 treaties and international agreements issued by the Secretary of State as United States treaties and other international agreements.

The Constitution of Subject Slave in the Journal: “Dezenove de Dezembro"

  ABSTRACT: This article is based on the contributions of discourse analysis from French orientation, which combines the linguistic aspect to the socio-historical, it understands, therefore, that the speech is the place of ideological manifestations (ORLANDI, 1984) and can not be dissociated from its production condition, that is, of all his surroundings and constituent: who, when, where. Starting with four announcement on runaway slaves and two missing pets, published in the Journal: Dezenove de Dezembro, in circulation in the State of Paraná, in the nineteenth century, we analyze the position of the press at the time to refer to the runaway slave. The appreciation of the words used by the enunciator has revealed that he had the intention to highlight the condition of "object" of the black slave, limiting his identity to their physical particulars, referring to aspects found in the missing pets announcements. Thereby, we find, in these analyzed announcements, which the formation of the subject slave in the Paraná society of the nineteenth century is subjected, and it can not be disconnected of ideological and historical instances.

Time-Dependent Density Functional Molecular Orbital and Excited State Calculations on Bis(porphyrinyl)butadiynes in the Monocationic, Neutral, Monoanionic, and Dianionic Oxidation States

We report a theoretical study of the multiple oxidation states (1+, 0, 1−, and 2−) of a meso,meso-linked diporphyrin, namely bis[10,15,20-triphenylporphyrinatozinc(II)-5-yl]butadiyne (4), using Time-Dependent Density Functional Theory (TDDFT). The origin of electronic transitions of singlet excited states is discussed in comparison to experimental spectra for the corresponding oxidation states of the close analogue bis{10,15,20-tris[3‘,5‘-di-tert-butylphenyl]porphyrinatozinc(II)-5-yl}butadiyne (3). The latter were measured in previous work under in situ spectroelectrochemical conditions. Excitation energies and orbital compositions of the excited states were obtained for these large delocalized aromatic radicals, which are unique examples of organic mixed-valence systems. The radical cations and anions of butadiyne-bridged diporphyrins such as 3 display characteristic electronic absorption bands in the near-IR region, which have been successfully predicted with use of these computational methods. The radicals are clearly of the “fully delocalized” or Class III type. The key spectral features of the neutral and dianionic states were also reproduced, although due to the large size of these molecules, quantitative agreement of energies with observations is not as good in the blue end of the visible region. The TDDFT calculations are largely in accord with a previous empirical model for the spectra, which was based simplistically on one-electron transitions among the eight key frontier orbitals of the C4 (1,4-butadiyne) linked diporphyrins.