Educação física na 4ª série do ensino fundamental das escolas Governador Freitas Neto e Colégio Lerote da cidade de Teresina-PI : a relação entre leitura e expressão corporal

RESUMO:O hábito de ler é decorrente do exercício e nem sempre se constitui num ato prazeroso, porém, sempre necessário. Por este motivo se deve recorrer a estímulos para criar o hábito de leitura em nossos alunos. Desta forma, a disciplina de Educação Física pode também contribuir para este processo. Por ser uma disciplina que envolve a dimensão motora, cognitiva e expressionista, a sua relação com a leitura é quase que intrínseca, porém, viabilizada de formas diferentes. É certo que a criança não conseguirá na sua totalidade, uma absorção intelectual explícita da leitura para construir uma realidade virtual e representar em gestos corporais, a partir de um conjunto léxico de significantes e significados correspondentes à postura física. No entanto, o exercício da leitura desenvolve na criança capacidades cognitivas de mais valia que lhe possibilita níveis satisfatórios de representatividade corporal. As atividades recreativas oferecem, sem dúvida, um processo excepcional para fazer as crianças tomarem parte ativamente no processo do ensino, como participantes, em vez de meros espectadores. A proposta deste trabalho de intervenção busca auxiliar o professor de Educação Física no campo de atuação profissional do pesquisador, tendo como delimitação do campo de investigação o Centro de Educação Básica Governador Freitas Neto, escola da rede municipal de Educação de Teresina e, Colégio Lerote, da rede particular de Teresina. Deste modo, os objetivos do presente estudo consistem em analisar as contribuições da disciplina de Educação Física para a aprendizagem do ensino da prática de leitura com crianças do Ensino Fundamental, nas séries iniciais com escolas da rede municipal e particular da cidade de Teresina – Piauí. Concluiu-se que com um trabalho integrado da Educação Física com o processo de alfabetização nas primeiras séries do Ensino Fundamental, essa etapa pode ser vista de forma rica e ampla. Assim, com essa contribuição, aprender a ler e escrever pode, pois, se tornar mais natural e mais divertido. ABSTRACT: The habit of reading is a result of exercise and is not always a pleasurable act, but always necessary. For this reason one should resort to incentives to create the reading habit in our students. Thus, the discipline of Physical Education can also contribute to this process. Because it is a discipline that involves the size motor, cognitive and expressionistic, their relationship with reading that is almost inherent, however, made possible in different ways. It is true that the child can not in its entirety, an explicit intellectual absorption of reading to construct a virtual reality and represented body gestures from a whole lexicon of signifiers and meanings corresponding to the physical posture. However, the exercise of reading the child develops cognitive abilities that enables him to gain more satisfactory levels of representative body. The recreational activities offer, no doubt, an exceptional procedure to make the children take part actively in the process of education, as participants rather than spectators. The purpose of this intervention work intends to help the physical education teacher in the professional field of research, with the delimitation of the field of research the Centre for Basic Education Governador Freitas Neto, the municipal school of Teresina and Education, College Lerote, from private Teresina. Thus, the objectives of this study are to analyze the contributions of physical education for learning the practice of teaching reading with children of elementary school, in the early grades with municipal schools and particularly the city of Teresina - Piauí. It was concluded that with an integrated physical education with the acquisition of literacy in the early grades of elementary school, this step can be seen in a rich and broad. So, with this contribution, learning to read and write may therefore become more natural and fun.

Orientação sexual como tema transversal em escolas públicas de Curralinhos-PI

Este estudo objetivou analisar a prática docente relacionada à orientação sexual enquanto tema transversal em escolas públicas no munícipio de Curralinhos-PI, e neste encalço, identificar as formas de práticas docentes relacionadas à orientação sexual enquanto tema transversal; caracterizar os fatores condicionantes para a realização da abordagem da orientação sexual em sala de aula; verificar a contribuição das oficinas do Programa Saúde e Prevenção na Escola (SPE) na formação continuada da prática docente e, a percepção de professores e alunos, quanto à relevância da abordagem do tema em questão de forma sistemática e transversal nas referidas escolas. Trata-se de um estudo com abordagem qualitativa e quantitativa com função de complementaridade, realizada em duas escolas públicas (X e Y) do município de Curralinhos-PI, de ensino fundamental e ensino médio, respectivamente, envolvendo uma amostra de 8 (oito) professores, que participaram das oficinas do SPE e 116 alunos, sendo 54 da escola X e 62 da escola Y. Os instrumentos da coleta de dados foram a entrevista e o questionário semiestruturados, originários de um roteiro de questões-guia. A coleta de dados foi realizada no segundo semestre de 2011, nos meses de agosto a setembro. Os resultados apontaram que é grande a necessidade de se discutir e implementar a orientação sexual no espaço escolar, pois embora a maioria dos professores entrevistados reconheçam a importância de se trabalhar a orientação sexual como tema transversal e demonstrarem conhecer esta proposta dos Parâmetros Curriculares Nacionais (PCNs), ainda são difusas as práticas incorporadas em suas atividades pedagógicas. Quanto aos alunos, evidenciaram que ainda se fazem presentes dúvidas e angústias, assim como dificuldades para a lida com o tema da sexualidade.

Phosphoinositide (PI) 3-kinase assays

The regulation of phosphoinositide (PI) 3-kinase activities has been linked to many normal and disease-related processes, including cell survival, cell growth and proliferation, cell differentiation, cell motility, and intracellular vesicle trafficking. However, as the family of enzymes has now grown to include eight true members, in three functional classes, plus several related protein kinases that are also inhibited by the widely used PI 3-kinase selective inhibitors, wortmannin and LY294002, extended methodologies are required to identify which type of kinase is involved in a particular cellular process, or protein complex, under study. A robust in vitro PI 3-kinase assay, suitable for use with immunoprecipitates, or purified proteins, is described here together with a series of modifications of substrate and assay conditions that will aid researchers in the identification of the particular class and isoform of PI 3-kinase that is involved in a signaling process under investigation.

Anion-pi, Lone-Pair-pi, pi-pi and Hydrogen-Bonding Interactions in a Cu-II Complex of 2-Picolinate and Protonated 4,4 '-Bipyridine: Crystal Structure and Theoretical Studies

A Cu-II complex of protonated 4,4'-bipyridine (Hbyp) and 2-picolinate (pic), [Cu-2(pic)(3)(Hbyp)(H2O)(ClO4)(2)], has been synthesised and characterised by single-crystal X-ray analysis. The structure consists of two copper atoms that have different environments, bridged by a carboxylate group. The equatorial plane is formed by the two bidentate picolinate groups in one Cu-II, and one picolinate, one monodentate 4,4'-bipyridyl ligand and a water molecule in the other. Each copper atom is also weakly bonded to a perchlorate anion in an axial position. One of the coordinated perchlorate groups displays anion-pi interaction with the coordinated pyridine ring. The noncoordinated carboxylate oxygen is involved in lone-pair (l.p.)-pi interaction with the protonated pyridine ring. In addition there are pi-pi and H-bonding interactions in the structure. Bader's theory of "atoms in molecules" (AIM) is used to characterise the anion-pi and l.p.-pi interactions observed in the solid state. A high-level ab initio study (RI-MP2/aug-cc-pVTZ level of theory) has been performed to analyse the anion-pi binding affinity of the pyridine ring when it is coordinated to a transition metal and also when the other pyridine ring of the 4,4'-bipyridine moiety is protonated. Theoretical investigations support the experimental findings of an intricate network of intermolecular interactions, which is characterised in the studied complex, and also indicate that protonation as well as coordination to the transition metal have important roles in influencing the pi-binding properties of the aromatic ring. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

A self-repairing, supramolecular polymer system: healability as a consequence of donor-acceptor pi-pi stacking interactions

A novel supramolecular polymer system, in which the terminal pyrenyl groups of a polyamide intercalate into the chain-folds of a polyimide via electronically-complementary pi-pi stacking, shows both enhanced mechanical properties relative to those of its individual components and facile healing characteristics as a result of the thermoreversibility of non-covalent interactions.

A general synthesis of macrocyclic pi-electron-acceptor systems

Cyclocondensations of aromatic diamines with 1,1'-bis(2,4-dinitrophenyl)-4,4'-bipyridinium salts afford doubly or quadruply charged, macrocyclic, N,N'-diarylbipyridinium cations. These are tolerant of a wide range of acids, bases, and nucleophiles, although they appear to undergo reversible, one-electron reduction by tertiary amines. Single-crystal X-ray analysis demonstrates the presence of a macrocycle conformation in which the 4,4'-bipyridinium and 4,4'-biphenylenedisulfonyl residues are suitably spaced and aligned for complexation with pi-donor arenes, and NMR studies in solution indeed confirm binding to 1,5-bis[hydroxy(ethoxy)ethoxy]naphthalene.

Observation of carbonyl oxygen-pi interaction in a metal complex

X-ray crystallography shows that [Ag2L2(H2O)(2)](BF4)(2) where L is a 1:1 condensate of 1,2-diphenylethane-1,2-dione and 2-(2-aminoethyl pyridine), contains an Ag(I)-Ag(I) bond of length 2.979(2) angstrom and an angular, intraligand interaction of the keto O with the pi cloud of the pyridine moiety (O-pyridine centroid = 3.12 angstrom). Model MP2/6-311++G(d,p) calculations indicate that the observed lone pair-pi type interaction is stabilising and not merely a tolerated short contact. (C) 2008 Elsevier B.V. All rights reserved.

4,4 '-Dipyridyl-N,N '-dioxide complexes of metal-thiocyanate/selenocyanate: pi-stacked molecular rods as three-dimensional support for two-dimensional polymeric sheets and intra/interchain S center dot center dot center dot S interaction dependent architecture of the R-2(2)(8) synthon driven assembly of one-dimensional polymeric chains

Three supramolecular complexes of Co(II) using SCN-/SeCN- in combination with 4,4'-dipyridyl-N,N'-dioxide (dpyo), i.e., {[Co(SCN)(2)(dpyo)(2)].(dpyo)}(n) ( 1), {[Co(SCN)(2)(dpyo)(H2O)(2)].(H2O)}(n) ( 2), {[Co(SeCN)(2)(dpyo)(H2O)(2)]center dot(H2O)}(n) ( 3), have been synthesized and characterized by single-crystal X-ray analysis. Complex 1 is a rare example of a dpyo bridged two-dimensional (2D) coordination polymer, and pi-stacked dpyo supramolecular rods are generated by the lattice dpyo, passing through the rhombic grid of stacked layers, resulting in a three-dimensional (3D) superstructure. Complexes 2 and 3 are isomorphous one-dimensional (1D) coordination polymers [-Co-dpyo-Co-] that undergo self-assembly leading to a bilayer architecture derived through an R-2(2)(8) H-bonding synthon between coordinated water and dpyo oxygen. A reinvestigation of coordination polymers [Mn(SCN)(2)(dpyo)( H2O)(MeOH)](n) ( 4) and {[Fe(SCN)(2)(dpyo)(H2O)(2)]center dot(H2O)}(n) ( 5) reported recently by our group [ Manna et al. Indian J. Chem. 2006, 45A, 1813] reveals brick wall topology rather than bilayer architecture is due to the decisive role of S center dot center dot center dot S/Se center dot center dot center dot Se interactions in determining the helical nature in 4 and 5 as compared to zigzag polymeric chains in 2 and 3, although the same R-2(2)(8) synthon is responsible for supramolecular assembly in these complexes.

Thallium pi-cation complexation by calix[4]tubes: Tl-205 NMR and X-ray evidence

Thallium cation complexation by calix[4]tubes has been investigated by a combination of (TI)-T-205, H-1 NMR and ES MS demonstrating the solution formation of a dithallium complex in which the cations are held in the calix[4]arene cavities. In addition, the structure of the complex has been determined in the solid state revealing the cations to be held exclusively by pi-cation interactions. Furthermore, this crystal structure has been used as the basis for molecular dynamics simulations to confirm that binding of the smaller K+ cation in the calix[4]tube cryptand like array occurs via the axial route featuring a g-cation intermediate.