120keV的N~+注入SiC薄膜的光谱特性研究

文中主要研究了 12 0keV的N+ 注入后SiC薄膜样品的光致发光谱 (PL)和傅立叶红外光谱(FTIR)特性 .从红外光谱可以看到有明显得碳氮单键、双键、三键等新结构生成 .从PL光谱则发现 36 5nm处的发光峰明显增强 ,这表明N+ 注入使得带隙中深的能级辐射中心复合的效率大幅度提高

黄土高原沟壑区苹果园土壤重金属含量特征研究

以黄土高原沟壑区的苹果园为研究对象,对6~36 a苹果园土壤重金属含量状况进行研究,结果发现,该区苹果园的高投入种植管理模式,能够影响重金属在土壤中的迁移与富集,使土壤重金属含量发生明显变化。土壤Cu含量随树龄增加而增加,20 a以上的土壤-果树系统对土壤Cu的输入与输出趋于平衡,Cu含量变化不大,且耕层土壤Cu含量较高。Cr含量随树龄线性递增,36 a果园0~20 cm,20~40 cm和40~60 cm土层Cr含量分别比6 a果园增加27.14%,17.09%和19.17%。Cd含量随树龄增加先增加后减少,长期大量施用磷肥是土壤Cd的主要来源,果园生态系统深层土壤Cd含量的峰值比耕层提前出现。Pb含量以15~26 a果园含量最高,树龄<15 a和>26 a时Pb含量较低。Hg含量则以15 a为转折点,在不同土层上呈现出不同的变化趋势。As含量在树龄<15 a时逐渐降低,15~20 a时逐渐增加,20 a以后果园土壤As含量趋于不变,且各土层之间差异不显著。

Nanoparticle-amplified Surface Plasmon Resonance Study of Protein Conformational Change at Interface

This paper reports the study of protein conformational change by Au nanoparticles (AUNPs)-amplified surface plasmon resonance (SPR) spectroscopy. Taking cytochrome c (Cyt c) as an example, this paper gives a detailed description of the construction of metal-protein-metal sandwich nanostructure consisting of an Au film underlayer, a cytochrome c intermediate layer and an AuNPs upper layer. The incorporation of AuNPs into SPR biosensing results in increased SPR sensitivity to protein conformational change as demonstrated by acid denaturation of Cyt c. It suggests the conformational change of surface-confined Cyt c leads to the distance and electromagnetic coupling variations of Au film-AuNPs.

A electrochemiluminescence aptasensor for detection of thrombin incorporating the capture aptamer labeled with gold nanoparticles immobilized onto the thio-silanized ITO electrode

A novel electrochemiluminescence (ECL) aptasensor was proposed for sensitive and cost-effective detection of the target thrombin adopted an aptamer-based sandwich format. To detect thrombin, capture aptamers; labeled with gold nanoparticles (AuNPs) were first immobilized onto the thio-silanized ITO electrode surface through strong Au-S bonds. After catching the target thrombin, signal aptamers; tagged with ECL labels were attached to the assembled electrode surface. As a result, an AuNPs-capture-aptamer/thrombin/ECL-tagged signal-aptamer sandwich type was formed.

Characterization of the Microstructure of Bimodal HDPE Resin

In this work, two industrial bimodal high density polyethylene resins, resin A and resin B having similar molecular weight (M-w), molecular weight distribution (M-wD), and short-chain branching (SCB) content but different mechanical properties, were fractionated through cross-fractionation. The fractions were further, characterized by GPC, C-13 NMR, DSC AND FT IR techniques. These two resins were firstly fractionated into two franctions, i.e. high-temperature and low temperature fractions, via preparative solution crystallization fractionation. Resin A with much better mechanical properties contains more high-temperature fractions with longer crystalizable sequences. The SCB content in the low temperature fraction of resin A is lower than the of resin B. Both low-temperature fractions were then further fractionated using solvent gradient fractionation (SGF). The characterization of SGF fraction indicates that most of the branches fall into the high molecular weight chain in both low-temperature fractions.

"Green synthesis" of monodisperse Pt nanoparticles and their catalytic properties

A green synthetic strategy to prepare monodisperse Pt nanoparticles was reported. Aminodextran acted as the reductive and protective agents, and Pt nanoparticles were characterized by UV/vis spectroscopy (UV-vis), Pt nanoparticles were conveniently obtained at one step. transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), and X-ray photoelectron spectroscopy (XPS). By changing the initial molar ratio of arninodextran to platinum precursor, Pt nanoparticles with different size were obtained. Amino groups of aminodextran could absorb on Pt nanoparticles surfaces and serve as a very good stabilizer. However, dextran without amino groups could not effectively stabilize Pt nanoparticles and aggregation of Pt nanoparticles were obtained. Catalytic activity of these Pt nanoparticles for the electron-transfer reaction between hexacyanoferrate (III) ions and thiosulfate ions was also studied, and they showed good catalytic efficiency.

Catalytic ring hydrogenation of benzoic acid with supported transition metal catalysts in scCO(2)

The ring hydrogenation of benzoic acid to cyclohexanecarboxylic acid over charcoal-supported transition metal catalysts in supercritical CO2 medium has been studied in the present work. The cyclohexanecarboxylic acid can be produced efficiently in supercritical CO2 at the low reaction temperature of 323 K. The presence of CO2 increases the reaction rate and several parameters have been discussed.