The effects of carbonized buffer layer on the growth of SiC on Si

Carbonized buffer layers were formed with C2H4 on Si(100) and Si(111) substrates using different methods and SIC epilayers were grown on each buffer layer at 1050 degrees C with simultaneous supply of C2H4 and Si2H6. The structure of carbonized and epitaxy layers was analyzed with in situ RHEED. The buffer layers formed at 800 degrees C were polycrystalline on both Si(100) and Si(111) substrates whereas they were single crystals, with twins on Si(100) and without tu ins on Si(111)substrates. when formed with a gradual rise in substrate temperature from 300 degrees C to growth temperature. Raising the substrate temperature slowly results in the formation of more twins. Epilayers grown on carbonized polycrystalline lavers are polycrystalline. Single crystal epilayers without twins grow on single crystalline buffer layers without twins or with a few twins. (C) 1999 Elsevier Science B.V. All rights reserved.

Boron diffusion in Ge+ premorphized and BF2+ implanted Si(001)

The annealing behavior of Si implanted with Ge and then BF2 has been characterized by double crystal X-ray diffraction (DCXRD) and secondary ion mass spectroscopy (SIMS). The results show that annealing at 600 degrees C for 60 minutes can only remove a little damage induced by implantation and nearly no redistribution of Ge and B atoms has occurred during the annealing. The initial crystallinity of Si is fully recovered after annealing at 950 degrees C for 60 minutes and accompanied by Ge diffusion. Very shallow boron junction depth has been formed. When annealing temperature rises to 1050 degrees C, B diffusion enhances, which leads to a deep diffusion and good distribution of B atoms into the Si substrate. The X-ray diffraction (004) rocking curves from the samples annealed at 1050 degrees C for 60 minutes display two SiGe peaks, which may be related to the B concentration profiles.

我国部分地区土壤环境背景值历史动态变化规律研究

以我国南方经济开发区。东北重工业区以及内蒙古草原区主要土壤类型为研究对象，分析近半个世纪以来不同历史时期土壤中Cu、Ni、Pb、Zn、Cd、As、Hg元素的背景值及其变化规律。结果表明，近半个世纪凤来，土壤金属元素背景值普遍存在变化。海拉尔草原区暗栗钙土近30年来Cu、Pb、Cd浓度相对稳定。As浓度有增加，而Ni、Zn、Hg浓度降低。上海郊区水稻土近10年As、Pb、Hg浓度呈现降低。南京东郊黄棕壤近50年来Cd、Hg浓度降低。Zn、Ni、Pb、As浓度升高。沈阳郊区草甸土，草甸棕壤及棕壤近30年来Pb、Zn、Cd、Cu浓度多呈升高，Hg浓度下降。各地区10—50年间土壤表层金属元素年变化率以上海、沈阳地区较大，海拉尔草原区相对较小。在2Km * 2Km面积上，草甸棕壤表土17个采样点间，7种金属元素浓度变异系数（%）分别为：Cd(33.1) > Hg(31.2) > Pb(11.3) > As(8.5) > Cu(8.3) > Zn(8.1) > Ni(7.2)。距该中心处不同距离的采样点间，各元素测定结果无显著差异（α = 0.01）。

CaⅢ等核及等电子系列离子3d波函数塌缩研究

利用HFR和LS-dependent(LS-D)的HFR自洽场方法,系统地计算了CaⅢ等核及等电子系列离子的3d电子径向波函数,分析了3d波函数的塌缩规律,揭示了3d波函数的塌缩与谱项的强烈依赖关系,并进一步讨论了由于3d波函数的塌缩引起的3p6→3p53d跃迁能和振子强度的变化.

The influence and chronological uncertainties of the 8.2 ka cooling event on continental climate records in China

IEECAS SKLLQG

改进的Glauber模型对奇异核反应总截面数据的拟合

利用Glauber模型对奇异核的反应总截面进行计算时 ,对模型进行了有限程修正和库仑修正 ,并对奇异核输入的密度采用了核芯加价核子的形式 ,使得理论与实验在中高能下都得到了很好的符合 .

过去2000年中国东部地区的极端旱涝事件变化

利用据历史文献中汉代以来的旱涝灾害记载重建的逐年旱涝等级,结合已重建的东部地区干湿指数序列,通过定义判别历史时期极端旱涝事件的标准,分华北、江淮和江南3个区域辨识了过去2000年的重大旱涝事件。结果表明,各个区域的重大旱、涝多发时段分别是:华北地区出现在100～150年、550～650年、1050～1100年与1850～1900年;江淮地区出现在250～450年与1600～1850年;江南出现在350～400年、1100～1200年与1900～1950年。整个东部地区则出现在100～150年、250～35

Crystallization of mechanically alloyed amorphous W-Mg alloy under high pressure

Pure metal powder mixtures of W and Mg at the desired composition were milled in conventional high-energy ball mill, and amorphous alloy W50Mg50 was obtained after milling for 20 h. The structure evolution of elemental powder mixtures was studied following milling and subsequent high pressure and high temperature treatment. The amorphous alloy transform into a nanocrystalline material below 1050 degreesC at 4.0 GPa. On increasing the temperature, it transforms into a mixture of several new crystal phases under high-pressure condition. It also found that both mechanical alloying and high pressure treatment are the two necessary processes to form the nanocrystalline and the new phases.

Long-lasting properties of rare earth-doped Y2O2S phosphors

The aim of this presentation is to report a new result of afterglow materials. The Y2OS: Ln(3+) (Ln = Sm, Tm) phosphors show bright reddish orange and orange-yellow colors when excited by UV or visible light. The main spectroscopic characterizations of Sin(3+) and Tin(3+) in yttrium oxysulfide and their long-lasting phosphorescence were measured and discussed in this presentation. Their long-lasting phosphorescence can be seen by the naked eyes clearly for about one hour in the dark room after the Irradiation light sources were removed. XRD and photoluminescence (PL) spectra as well as the luminance decay were used to characterize these long-lasting phosphorescence phosphors. The results of XRD indicate that the products synthesized through the flux fusion method tinder 1050 degreesC, for 6 It have a good crystallization without any detectable amount of impurity phase. Both the PL spectra and luminance decay results reveal that these phosphors have efficient luminescent and good long-lasting properties. We believe that the experimental data gathered in our present work will be. useful in finding some new long-lasting phosphors with different colors.

Luminescence properties of rare earth ions in cadmium metasilicate

The luminescence properties of CdSio(3):RE3+ phosphors doped with various rare earth ions are reported. The series of rare earth ions doped CdSiO3 phosphors are prepared by the conventional high-temperature solid-state method, and characterized by XRD and photoluminescence (PL) spectra. The results of XRD measurement indicate that the products fired under 1050 degreesC for 3 h have a good crystallization without any detectable amount of impure phase. The PL spectra measurement results show that CdSiO3 is a novel self-activated luminescent matrix. When rare earth ions such as Y3+, La3+, Gds(3+), Lus(3+), Ce3+, Nd3+, Ho3+, Era(3+), Tm3+ and Yb3+ are introduced into the CdSi03 host, one broadband centered at about 420 nm resulted from traps can be observed. In the case of other earth ions which show emissions at the visible spectrum region, such as Pr3+, Sm3+, Eu3+, Tb3+ and Dy3+, the mixture of their characteristic line emissions with the similar to 420 nm strong broadband luminescence results in various emitting colors. As a consequence, different emitting colors can be attairied via introducing certain appropriate active ions into the CdSiO3 matrix. In additional, this kind of phosphors shows good long-lasting properties when excited by UV light. All the results show that CdSiO3 is a potential luminance matrix.

Tunable photoluminescent and cathodoluminescent properties of ZnO and ZnO : Zn phosphors

ZnO and ZnO: Zn powder phosphors were prepared by the polyol-method followed by annealing in air and reducing gas, respectively. The samples were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), X-ray photoelectron spectra (XPS), electron paramagnetic resonance (EPR), and photoluminescence (PL) and cathodoluminescence ( CL) spectra, respectively. The results indicate that all samples are in agreement with the hexagonal structure of the ZnO phase and the particle sizes are in the range of 1-2 mu m. The PL and CL spectra of ZnO powders annealed at 950 degrees C in air consist of a weak ultraviolet emission band ( similar to 390 nm) and a broad emission band centered at about 527 nm, exhibiting yellow emission color to the naked eyes. When the sample was reduced at the temperatures from 500 to 1050 degrees C, the yellow emission decreased gradually and disappeared completely at 800 degrees C, whereas the ultraviolet emission band became the strongest. Above this temperature, the green emission ( similar to 500 nm) appeared and increased with increasing of reducing temperatures.