Single particle characterization using the soot particle aerosol mass spectrometer (SP-AMS)

Understanding the impact of atmospheric black carbon (BC) containing particles on human health and radiative forcing requires knowledge of the mixing state of BC, including the characteristics of the materials with which it is internally mixed. In this study, we demonstrate for the first time the capabilities of the Aerodyne Soot-Particle Aerosol Mass Spectrometer equipped with a light scattering module (LS-SP-AMS) to examine the mixing state of refractory BC (rBC) and other aerosol components in an urban environment (downtown Toronto). K-means clustering analysis was used to classify single particle mass spectra into chemically distinct groups. One resultant cluster is dominated by rBC mass spectral signals (C+1 to C+5) while the organic signals fall into a few major clusters, identified as hydrocarbon-like organic aerosol (HOA), oxygenated organic aerosol (OOA), and cooking emission organic aerosol (COA). A nearly external mixing is observed with small BC particles only thinly coated by HOA ( 28% by mass on average), while over 90% of the HOA-rich particles did not contain detectable amounts of rBC. Most of the particles classified into other inorganic and organic clusters were not significantly associated with BC. The single particle results also suggest that HOA and COA emitted from anthropogenic sources were likely major contributors to organic-rich particles with low to mid-range aerodynamic diameter (dva). The similar temporal profiles and mass spectral features of the organic clusters and the factors from a positive matrix factorization (PMF) analysis of the ensemble aerosol dataset validate the conventional interpretation of the PMF results.

ARM processor modeling at a cycle accurate level in systemC

Mémoire numérisé par la Direction des bibliothèques de l'Université de Montréal.

(Table 1) AMS 14C dates from sediment cores RC12-10 and GYRE97-6PV-20

Proxy records from two piston cores in the Gulf of Mexico (GOM) provide a detailed (50-100 year resolution) record of climate variability over the last 14,000 years. Long-term (millennial-scale) trends and changes are related to the transition from glacial to interglacial conditions and movement of the average position of the Intertropical Convergence Zone (ITCZ) related to orbital forcing. The d18O of the surface-dwelling planktic foraminifer Globigerinoides ruber show negative excursions between 14 and 10.2 ka (radiocarbon years) that reflect influx of meltwater into the western GOM during melting of the Laurentide Ice Sheet. The relative abundance of the planktic foraminifer Globigerinoides sacculifer is related to transport of Caribbean water into the GOM. Maximum transport of Caribbean surface waters and moisture into the GOM associated with a northward migration of the average position of the ITCZ occurs between about 6.5 and 4.5 ka. In addition, abundance variations of G. sacculifer show century-scale variability throughout most of the Holocene. The GOM record is consistent with records from other areas, suggesting that century-scale variability is a pervasive feature of Holocene climate. The frequency of several cycles in the climate records is similar to cycles identified in proxy records of solar variability, indicating that at least some of the century-scale climate variability during the Holocene is due to external (solar) forcing.

(Table 2) Radiocarbon content and 14C AMS ages of planktonic foraminifera from sediment cores Louis_1900 and Louis_2023

North American freshwater runoff records have been used to support the case that climate flickers were caused by shutdowns of the ocean thermohaline circulation (THC) resulting from reversals of meltwater discharges. Inconsistencies in the documentation of these meltwater switches, however, continue to fuel the debate on the cause/s of the oscillatory nature of the deglacial climate. New oxygen and carbon isotope records from the northern Gulf of Mexico depict in exceptional detail the succession of meltwater floods and pauses through the southern routing during the interval 16 to 8.9 ka (14C years BP; ka, kiloannum). The records underscore the bimodal role played by the Gulf of Mexico as a destination of meltwater discharges from the receding Laurentide Ice Sheet. The evidence indicates that the Gulf of Mexico acted as the principal source of superfloods at 13.4, 12.6, and 11.9 ka that reached the North Atlantic and contributed significantly to density stratification, disruption of ocean ventilation, and cold reversals. Gulf of Mexico lapsed into a "relief valve" position in post-Younger Dryas time, when meltwater discharges were rerouted south at 9.9, 9.7, 9.4, and 9.1 ka, thus temporarily interrupting North Atlantic-bound freshwater discharges from Lake Agassiz. The history of meltwater events in the Gulf of Mexico contradicts the model that meltwater flow via the eastern outlets into the North Atlantic disrupted the ocean THC, causing cooling, while diversions to the Gulf of Mexico via the Mississippi River enhanced THC and warming.

AMS radiocarbon dates on ten monospecific samples of planktonic foraminifer Globigerinoides ruber of sediment core GeoB8509-2 (Table 1)

Aeolian and fluvial sediment transport to the Atlantic Ocean offshore Mauritania were reconstructed based on grain-size distributions of the carbonate-free silt fraction of three marine sediment records of Cap Timiris Canyon to monitor the climatic evolution of present-day arid north-western Africa. During the late Pleistocene, predominantly coarse-grained particles, which are interpreted as windborne dust, characterise glacial dry climate conditions with a low sea level and extended sand seas that reach onto the exposed continental shelf off Mauritania. Subsequent particle fining and the abrupt decrease in terrigenous supply are attributed to humid climate conditions and dune stabilisation on the adjacent African continent with the onset of the Holocene humid period. Indications for an ancient drainage system, which was discharging fluvial mud offshore via Cap Timiris Canyon, are provided by the finest end member for early to mid Holocene times. However, in comparison to the Senegal and Niger River further south, the river system connecting Cap Timiris Canyon with the Mauritanian hinterland was starved during the late Holocene and is non-discharging under present-day arid climate conditions.

(Table 1) AMS-14C ages determined in pairs of spreiten and directly adjacent host sediment of cores M39029-4 and M29039-8

he downward transport of surface sediment deep into the sediment column by the Zoophycos-producing animal leads not only to large age differences between the Zoophycos structure and surrounding host sediment but also to large differences in age between different foraminifer species found inside the trace fossil. In the late Quaternary material from the southwestern Portuguese continental slope examined in this study, age differences of up to 2590 years were observed between the planktic foraminifer species Globigerinoides ruber and Globigerina bulloides. These differences are caused by the mixing of surface and host material with different abundances of the two species. If there are differences in the abundance of the two species at the surface and/or in the host sediment, plenty of relatively young foraminifers may be mixed with few relatively old ones, or vice versa. The age differences between species caused by the combination of deep-reaching bioturbation by the Zoophycos producer and abundance variations may be considerably larger than the age differences caused by the homogenizing bioturbation in the mixed layer.

Analizar y comparar el lenguaje de alto nivel SystemC frente a los de HDL. aplicación al diseño de sistemas de computo

La complejidad de los sistemas actuales de computación ha obligado a los diseñadores de herramientas CAD/CAE a acondicionar lenguajes de alto nivel, tipo C++, para la descripción y automatización de estructuras algorítmicas a sus correspondientes diseños a nivel físico. Los proyectos a realizar se encuadran dentro de una línea de trabajo consistente en estudiar la programación, funcionamiento de los lenguajes SystemC y SystemVerilog, sus herramientas asociadas y analizar cómo se adecuan a las restricciones temporales y físicas de los componentes (librerías, IP's, macro-celdas, etc) para su directa implementación. En una primera fase, y para este TFG, se estudiarán los componentes que conforman el framework elegido que es SystemC y su inclusión en herramientas de diseño arquitectural. Este conocimiento nos ayudará a entender el funcionamiento y capacidad de dicha herramienta y proceder a su correcto manejo. Analizaremos y estudiaremos unos de los lenguajes de alto nivel de los que hace uso dicha herramienta. Una vez entendido el contexto de aplicación, sus restricciones y sus elementos, diseñaremos una estructura hardware. Una vez que se tenga el diseño, se procederá a su implementación haciendo uso, si es necesario, de simuladores. El proyecto finalizará con una definición de un conjunto de pruebas con el fin de verificar y validar la usabilidad y viabilidad de nuestra estructura hardware propuesta.

¿LA GEOGRAFÍA DE LA EXCLUSIÓN SOCIAL COINCIDE CON LA GEOGRAFÍA DE LA POLÍTICA PÚBLICA EN CHILE? CONVERGENCIA DE LOS ESPACIOS DE INTERVENCIÓN PARA LA REGENERACIÓN DE BARRIOS Y DE ESCUELAS CON BAJOS RESULTADOS ACADÉMICOS EN EL ÁREA METROPOLITANA DE SANTIAGO (AMS) DE CHILE

La pobreza urbana se presenta como un problema característico de las metrópolis en Latinoamérica, donde las dinámicas sociales de segmentación del espacio están asociadas a usos y representaciones territoriales que van más allá de lo descrito por las perspectivas de análisis tradicionales sobre pobreza, ingresos o consumo. El presente artículo busca mediante la descripción de los mecanismos de focalización dos políticas públicas con referencia territorial especifica -Programas de mejoramiento de resultados educacionales y Programa de regeneración de barrios-, dar cuenta de la construcción de una geografía de la exclusión social para el caso del Área Metropolitana de Santiago, donde se problematiza la escala espacial de análisis, de diagnóstico y de intervención. Se pone de manifiesto a nivel teórico el concepto de estrategias sociales de segmentación del espacio urbano, como un elemento fundamental para comprender las dinámicas de integración y exclusión de diversos colectivos en la ciudad, las cuales deben ser parte sustancial de las intervenciones a nivel educacional y de barrio-vivienda. Por último, se busca avanzar en la discusión respecto de la variable territorial asociada a procesos complejos de exclusión socio-espacial, al mismo tiempo que se releva la necesidad de un análisis multi-nivel para las políticas públicas con referencia territorial.

EXISTENCE RESULTS FOR ABSTRACT NEUTRAL FUNCTIONAL DIFFERENTIAL EQUATIONS

In this paper we discuss the existence of solutions for a class of abstract partial neutral functional differential equations.

SOLITON SOLUTIONS TO SYSTEMS OF COUPLED SCHRODINGER EQUATIONS OF HAMILTONIAN TYPE

We study the existence of positive solutions of Hamiltonian-type systems of second-order elliptic PDE in the whole space. The systems depend on a small parameter and involve a potential having a global well structure. We use dual variational methods, a mountain-pass type approach and Fourier analysis to prove positive solutions exist for sufficiently small values of the parameter.

FLOWS WITHOUT WANDERING POINTS ON COMPACT CONNECTED SURFACES

Given a compact 2 dimensional manifold M we classify all continuous flows phi without wandering points on M. This classification is performed by finding finitely many pairwise disjoint open phi-invariant subsets {U(1), U(2), ..., U(n)} of M such that U(i=1)(n) (U(i)) over bar = M and each U(i) is either a suspension of an interval exchange transformation, or a maximal open cylinder made up of closed trajectories of phi.