930 resultados para Smid, Stefan


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The melting of spherical nanoparticles is considered from the perspective of heat flow in a pure material and as a moving boundary (Stefan) problem. The dependence of the melting temperature on both the size of the particle and the interfacial tension is described by the Gibbs-Thomson effect, and the resulting two-phase model is solved numerically using a front-fixing method. Results show that interfacial tension increases the speed of the melting process, and furthermore, the temperature distribution within the solid core of the particle exhibits behaviour that is qualitatively different to that predicted by the classical models without interfacial tension.

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We treat two related moving boundary problems. The first is the ill-posed Stefan problem for melting a superheated solid in one Cartesian coordinate. Mathematically, this is the same problem as that for freezing a supercooled liquid, with applications to crystal growth. By applying a front-fixing technique with finite differences, we reproduce existing numerical results in the literature, concentrating on solutions that break down in finite time. This sort of finite-time blow-up is characterised by the speed of the moving boundary becoming unbounded in the blow-up limit. The second problem, which is an extension of the first, is proposed to simulate aspects of a particular two-phase Stefan problem with surface tension. We study this novel moving boundary problem numerically, and provide results that support the hypothesis that it exhibits a similar type of finite-time blow-up as the more complicated two-phase problem. The results are unusual in the sense that it appears the addition of surface tension transforms a well-posed problem into an ill-posed one.

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Under certain conditions, the mathematical models governing the melting of nano-sized particles predict unphysical results, which suggests these models are incomplete. This thesis studies the addition of different physical effects to these models, using analytic and numerical techniques to obtain realistic and meaningful results. In particular, the mathematical "blow-up" of solutions to ill-posed Stefan problems is examined, and the regularisation of this blow-up via kinetic undercooling. Other effects such as surface tension, density change and size-dependent latent heat of fusion are also analysed.

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Se realizó el análisis de ocho artículos y un libro escrito por el profesor Stefan Tengblad desde el 2000 hasta el 2012. Durante 12 años, el autor sueco se ha dado la tarea de analizar no solo los resultados obtenidos por los escritores más importantes sobre la práctica directiva, sino que también se puso en la tarea de comparar sus estudios y resultados. En las reseñas reconstructivas se pueden identificar las variables más importantes y las conclusiones que Tengblad obtuvo después de muchos años de estudio. Nuestro principal objetivo es descubrir, analizar y comprender las investigaciones hechas por el escritor sueco sobre la naturaleza de la práctica directiva hasta el año 2014. De esta manera podremos ver si las diferentes posiciones de los autores han cambiado con los años. Trataremos algunas variables importantes de la práctica directiva como el liderazgo, la fragmentación del trabajo, la comunicación escrita y electrónica, los valores, los objetivos, la toma de decisiones, las normas, la cultura corporativa, la estructura organizacional, las expectativas internas y externas, entre otras. Todo esto nos llevará a identificar a profundidad el discurso del profesor Stefan Tengblad y los aportes que le ha hecho a la comunidad no solo académica sino también laboral.

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Monográfico: Globalización, diversidad cultural y acción socioeducativa. Resumen en inglés y catalán