Tab. 1 Mole % CO2 and 13C values of CO2 at baseline and at the final monitoring event for the eight observation wells

During CO2 storage operations in mature oilfields or saline aquifers it is desirable to trace the movement of injected CO2 for verification and safety purposes. We demonstrate the successful use of carbon isotope abundance ratios for tracing the movement of CO2 injected at the Cardium CO2 Storage Monitoring project in Alberta between 2005 and 2007. Injected CO2 had a d13C value of -4.6±1.1 per mil that was more than 10 per mil higher than the carbon isotope ratios of casing gas CO2 prior to CO2 injection with average d13C values ranging from -15.9 to -23.5 per mil. After commencement of CO2 injection, d13C values of casing gas CO2 increased in all observation wells towards those of the injected CO2 consistent with a two-source end-member mixing model. At four wells located in a NE-SW trend with respect to the injection wells, breakthrough of injected CO2 was registered chemically (>50 mol % CO2) and isotopically 1-6 months after commencement of CO2 injection resulting in cumulative CO2 fluxes exceeding 100000 m**3 during the observation period. At four other wells, casing gas CO2 contents remained below 5 mol % resulting in low cumulative CO2 fluxes (<2000 m**3) throughout the entire observation period, but carbon isotope ratios indicated contributions between <30 and 80% of injected CO2. Therefore, we conclude that monitoring the movement of CO2 in the injection reservoir with geochemical and isotopic techniques is an effective approach to determine plume expansion and to identify potential preferential flow paths provided that the isotopic composition of injected CO2 is constant and distinct from that of baseline CO2.

(Table 1) Chloride concentrations in water obtained from observation wells on Helgoland Dune, North Sea

The hydrogeological conditions are unfavourable for a sufficient supply of drinking-water. The small size of the catchment area, the large hydraulic gradient inside the steep 'Buntsandstein'-cliff and the low geodetic level of the 'Dune Island' and the foreshore at the eastern foot of the cliff do not allow the formation and recharge of a sufficiently exploitable geodetic freshwater dome over the underlying saltwater. This means that until recently the provision of sufficient drinking-water for the island's inhabitants, for its garrison as well as for visiting ships was a problem. This problem has now been solved by the desalination of seawater.

Chemical analysis of water from observation wells in the Edwards and associated limestones, San Antonio area, Texas.

Cover title.

Guide for fabricating and installing shallow ground water observation wells /

"January 2001."

Assessment of flood-related recharge to alluvial aquifers of an irrigated catchment following extended drought conditions using 3D visualisation and environmental tracers, Lockyer Valley, southeast Queensland, Australia.

The Lockyer Valley in southeast Queensland, Australia, hosts an economically significant alluvial aquifer system which has been impacted by prolonged drought conditions (~1997 to ~ 2009). Throughout this time, the system was under continued groundwater extraction, resulting in severe aquifer depletion. By 2008, much of the aquifer was at <30% of storage but some relief occurred with rains in early 2009. However, between December 2010 and January 2011, most of southeast Queensland experienced unprecedented flooding, which generated significant aquifer recharge. In order to understand the spatial and temporal controls of groundwater recharge in the alluvium, a detailed 3D lithological property model of gravels, sands and clays was developed using GOCAD software. The spatial distribution of recharge throughout the catchment was assessed using hydrograph data from about 400 groundwater observation wells screened at the base of the alluvium. Water levels from these bores were integrated into a catchment-wide 3D geological model using the 3D geological modelling software GOCAD; the model highlights the complexity of recharge mechanisms. To support this analysis, groundwater tracers (e.g. major and minor ions, stable isotopes, 3H and 14C) were used as independent verification. The use of these complementary methods has allowed the identification of zones where alluvial recharge primarily occurs from stream water during episodic flood events. However, the study also demonstrates that in some sections of the alluvium, rainfall recharge and discharge from the underlying basement into the alluvium are the primary recharge mechanisms of the alluvium. This is indicated by the absence of any response to the flood, as well as the observed old radiocarbon ages and distinct basement water chemistry signatures at these locations. Within the 3D geological model, integration of water chemistry and time-series displays of water level surfaces before and after the flood suggests that the spatial variations of the flood response in the alluvium are primarily controlled by the valley morphology and lithological variations within the alluvium. The integration of time-series of groundwater level surfaces in the 3D geological model also enables the quantification of the volumetric change of groundwater stored in the unconfined sections of this alluvial aquifer during drought and following flood events. The 3D representation and analysis of hydraulic and recharge information has considerable advantages over the traditional 2D approach. For example, while many studies focus on singular aspects of catchment dynamics and groundwater-surface water interactions, the 3D approach is capable of integrating multiple types of information (topography, geological, hydraulic, water chemistry and spatial) into a single representation which provides valuable insights into the major factors controlling aquifer processes.

Assessment of interactions between alluvial, Great Artesian Basin (GAB) and volcanic aquifers using 3D visualisation and environmental tracers, Lockyer Valley, southeast Queensland, Australia

A detailed 3D lithological model framework was developed using GOCAD software to understand interactions between alluvial, volcanic and GAB aquifers and the spatial and temporal distribution of groundwater recharge to the alluvium of the Lockyer Valley. Groundwater chemistry, isotope data (H20-δ2H and δ18O , 87Sr/86Sr, 3H and 14C) and groundwater level time-series data from approximately 550 observation wells were integrated into the catchment-wide 3D model to assess the recharge processes involved. This approach enabled the identification of zones where recharge to the alluvium primarily occurs from stream water during episodic flood events. Importantly, the study also demonstrates that in some sections of the alluvium recharge is also from storm rainfall and seepage discharge from the underlying GAB aquifers. These other sources of recharge are indicated by (a) the absence of a response of groundwater levels to flooding in some areas, (b) old radiocarbon ages, and (c) distinct bedrock water chemistry and δ2H and δ18O signatures in alluvial groundwater at these locations. Integration of isotopes, water chemistry and time-series displays of groundwater levels before and after the 2010/2011 flood into the 3D model suggest that the spatial variations in the alluvial groundwater response are mostly controlled by valley morphology and lithological (i.e. permeability) variations within the alluvium. Examination of the groundwater level variations in the 3D model also enabled quantification of the volumetric change of groundwater stored in the unconfined alluvial aquifer prior to and post-flood events.

Modelling solute and microorganism transport through a peri-alpine gravel aquifer by considering the aquifer as a dual porosity fractured medium.

Approach:
In-situ passive gradient comparative artificial tracer testing, undertaken using solutes (Uranine and Iodide), Bacteria (E.coli and P.putida) and bacteriophage (H40/1), permitted comparison of the mobility of different sized microorganisms relative to solutes in the sand and gravel aquifer underlying Dornach, Germany.
Tracer breakthrough curves reveal that even though uranine initially arrived at observation wells at the same time as microbiological tracers, maximum relative concentrations were sometimes less than those of microbiological tracers, while solute breakthrough curves proved more disperse.
Monitoring uranine breakthrough with depth suggested tracers arrived in observation wells in discrete 0.5m-1m thick intervals, over the aquifer’s 12m saturated thickness. Nearby exposures of aquifer material suggested that the aquifer consisted of sandy gravels enveloping sequences of open framework (OW) gravel up to 1m thick. Detailed examination of OW units revealed that they contained lenses of silty sand up to 1m long x 30cm thick., while granulometric data suggested that the gravel was two to three orders of magnitude more permeable than the enveloping sandy gravel.
Solute and microorganism tracer responses could not be simulated using conventional advective-dispersive equation solutions employing the same velocity and dispersion terms. By contrast solute tracer responses, modelled using a dual porosity approach for fractured media (DP-1D) corresponded well to observed field data. Simulating microorganism responses using the same transport terms, but no dual porosity term, generated good model fits and explained the higher relative concentration of the bacteria, compared to the non-reactive solute, even with first order removal to account for lower RR. Geologically, model results indicate that the silty units within open framework gravels are accessible to solute tracers, but not to microorganisms.
Importance:
Results highlight the benefits of geological observations developing appropriate conceptual models of solute and micro organism transport and in developing suitable numerical approaches to quantifying microorganism mobility at scales appropriate for the development of groundwater supply (wellhead) protection zones.

Proposta de um sistema automatizado para controle de nível freático em sub-irrigação

Pós-graduação em Agronomia (Irrigação e Drenagem) - FCA

Simulação numérica de fluxo de águas subterrâneas na bacia do Rio Grande (BA)

The Urucuia Aquifer System represents a strategic water source in western Bahia. Its baseflow is responsible for the flow rate of the main tributaries of São Francisco river left bank in the dry season, including the Rio Grande, its main tributary in Bahia state. This river has a hydrological regime heavily affected by groundwater and is located in a region with conflicts about water resources. The aquifers geology is constituted by neocretacious sandstones of Urucuia Group subdivided in Posse Formation and Serra das Araras Formation. The embasement is formed by neoproterozoic rocks of Bambuí Group. This work focuses on an important tool application, the mathematical model, whose function is represent approximately and suitably the reality so that can assist in different scenarios simulations and make predictions. Many studies developed in this basin provided the conceptual model basis including a full free aquifer, lithological and hydraulical homogeneity in entire basin, null flux at plateau borders and aquifer base. The finite element method is the numerical method used and FEFLOW the computational algorithm. The simulated area was discretized in a single layer with 27.357,6 km² (314.432 elements and 320.452 nodes) totaling a 4.249,89 km³ volume. Were utilized 21 observation wells from CERB to calibrate the model. The terrain topography was obtained by SRTM data and the impermeable base was generated by interpolation of descriptive profiles from wells and electric vertical drilling from previous studies. Works in this area obtained mean recharge rates varying approximately from 20% to 25% of average precipitation, thus the values of model recharge zones varying in this range. Were distributed 4 hydraulic conductivity zones: (K1) west zone with K=6x10-5 m/s; (K2) center-east zone with K=3x10-4 m/s; (K3) far east zone with K=5x10-4 m/s; e (K4) east-north zone with K=1x10-5 m/s. Thereby was incorporated to the final conceptual model...

A mathematical view of water table fluctuations in a shallow aquifer in Brazil

Detailed monitoring of the groundwater table can provide important data about both short- and long-term aquifer processes, including information useful for estimating recharge and facilitating groundwater modeling and remediation efforts. In this paper, we presents results of 4 years (2002 to 2005) of monitoring groundwater water levels in the Rio Claro Aquifer using observation wells drilled at the Rio Claro campus of São Paulo State University in Brazil. The data were used to follow natural periodic fluctuations in the water table, specifically those resulting from earth tides and seasonal recharge cycles. Statistical analyses included methods of time-series analysis using Fourier analysis, cross-correlation, and R/S analysis. Relationships could be established between rainfall and well recovery, as well as the persistence and degree of autocorrelation of the water table variations. We further used numerical solutions of the Richards equation to obtain estimates of the recharge rate and seasonable groundwater fluctuations. Seasonable soil moisture transit times through the vadose zone obtained with the numerical solution were very close to those obtained with the cross-correlation analysis. We also employed a little-used deep drainage boundary condition to obtain estimates of seasonable water table fluctuations, which were found to be consistent with observed transient groundwater levels during the period of study.

Salinidad del agua freática en el área regadía del río Mendoza

La provincia de Mendoza tiene la mayor superficie regada de Argentina y cuenta con una vasta infraestructura de riego y drenaje en los cinco ríos aprovechados. Los suelos son de origen aluvial, con perfiles que alternan capas de distintas texturas, observándose la presencia de estratos muy finos -casi impermeables- que impiden el libre drenaje del agua de riego. Esta situación dinámica es más evidente a medida que el río disminuye su pendiente coincidiendo con los sectores bajos de la cuenca. La acumulación de agua produce el ascenso de los niveles freáticos hasta aproximarse a la superficie del suelo, incrementando la salinización del mismo. El área de riego del río Mendoza, con valores de salinidad media del agua en su derivación hacia la red de riego menor de 1 dS.m-1, es una de las más intensamente explotadas del país y presenta dos sectores con problemas de freática cercana a superficie. Los mismos corresponden a una zona central llamada Área de Surgencia AS y a otra llamada Área Lavalle AL. En AS hay una red de 98 pozos de observación (freatímetros) para conocer las profundidades, direcciones de flujos y calidad del agua freática. El AL tiene una red de 100 freatímetros distribuidos en tres subáreas correspondientes a tres colectores de drenajes: Tres de Mayo-Jocolí TMJ, Villa Lavalle VL y Costa de Araujo-Gustavo André CG. El presente trabajo muestra los resultados de la evaluación de la salinidad del agua freática expresada como salinidad total a 25 °C (CE) para las dos áreas de estudio. Las muestras han sido extraídas en 2002 y 2004. Los resultados indican que en los dos momentos de muestreo la mediana es menor que la media correspondiente, lo que evidencia asimetría positiva en las distribuciones. Las medianas obtenidas fueron: 6180 μS cm-1 (2002) y 6195 μS cm-1 (2004). Además se observan cambios en las distribuciones entre los momentos de muestreo y entre las áreas: en 2004 aparecen valores extremos superiores mucho mayores que en 2002, y el área VL acusa frecuencias relativas más uniformes y los mayores incrementos de CE. Se distingue también que en los dos momentos de muestreo el área AS posee los valores de posición de CE más bajos, aunque también es la zona con mayor cantidad de outliers; las áreas TMJ, CG y AS no han sufrido cambios importantes en los valores de CE en dos años, pero sí se advierte un sensible aumento de la CE en VL. Con la base de datos depurados se realizaron isolíneas para diferentes intervalos de la variable analizada (CE) que muestran espacialmente los sectores afectados con los distintos intervalos de salinidad freática.

Observation of quantum-confined Stark shifts in SiGe/Si type-I multiple quantum wells

Quantum-confined Stark shifts in SiGe/Si type-I multiple quantum wells are suggested by the bias dependence of the photocurrent spectra of p-i-n photodiodes. Both Stark redshift and blueshift have been observed for the same sample in the different ranges of electric fields applied to the quantum wells. The turnaround point corresponds to a certain electric field (named "critical" field). This phenomenon was generally predicted by Austin in 1985 [Phys. Rev. B 31, 5569 (1985)] and calculated in detail for SiGe quantum structure by Kim recently [Thin Solid Films 321, 215 (1998)]. The critical electric field obtained from the photocurrent spectra is in reasonable agreement with the theoretical prediction. (C) 2000 American Institute of Physics. [S0021-8979(00)03711-7].

Observation of field-driven blue shift in delta-doped Si n-i-p-i multiple quantum wells

We report the observation of the field-driven blue shift at near absorption edge in the photo-current response spectra of delta-doped Si n-i-p-i multiple quantum wells due to the widening of the effective energy gap. This phenomenon differs from the observed results in GaAs/AlGaAs and GeSi/Si superlattices, because the physical mechanisms of forming energy band in these superlattice samples are different. Our experimental results are interpreted satisfactorily by the theoretical calculation. (C) 1999 Elsevier Science Ltd. All rights reserved.

Mechanism on Effect of Surface Plasmons Coupling with InGaN/GaN Quantum Wells: Enhancement and Suppression of Photoluminescence Intensity

The photoluminescence (PL) intensity enhancement and suppression mechanism on surface plasmons (SPs) coupling with InGaN/GaN quantum wells (QWs) have been systematically studied. The SP-QW coupling behaviors in the areas of GaN cap layer coated with silver thin film were compared at different temperatures and excitation powers. It is found that the internal quantum efficiency (IQE) of the light emitting diodes (LEDs) varies with temperature and excitation power, which in turn results in anomalous emission enhancement and suppression tendency related to SP-QW coupling. The observation is explained by the balance between the extraction efficiency of SPs and the IQE of LEDs

Observation of electric current induced by optically injected spin current

Linearly polarized light at normal incidence injects a spin current into a strip of two-dimensional electron gas with Rashba spin-orbit coupling. The authors report observation of an electric current when such light is shed on the vincinity of the junction in a crossbar-shaped InGaAs/InAlAs quantum well Rashba system. The polarization dependence of this electric current was experimentally observed to be the same as that of the spin current. The authors attribute the observed electric current to the scattering of the optically injected spin current at the crossing. (c) 2007 American Institute of Physics.