Radiocarbon ages and 230Th data of five sediment cores from the Björn and Gardar Drift, North Atlantic

In locations of rapid sediment accumulation receiving substantial amounts of laterally transported material the timescales of transport and accurate quantification of the transported material are at the focus of intense research. Here we present radiocarbon data obtained on co-occurring planktic foraminifera, marine haptophyte biomarkers (alkenones) and total organic carbon (TOC) coupled with excess Thorium-230 (230Thxs) measurements on four sediment cores retrieved in 1649-2879 m water depth from two such high accumulation drift deposits in the Northeast Atlantic, Björn and Gardar Drifts. While 230Thxs inventories imply strong sediment focussing, no age offsets are observed between planktic foraminifera and alkenones, suggesting that redistribution of sediments is rapid and occurs soon after formation of marine organic matter, or that transported material contains negligible amounts of alkenones. An isotopic mass balance calculation based on radiocarbon concentrations of co-occurring sediment components leads us to estimate that transported sediment components contain up to 12% of fossil organic matter that is free of or very poor in alkenones, but nevertheless appears to consist of a mixture of fresh and eroded fossil material. Considering all available constraints to characterize transported material, our results show that although focussing factors calculated from bulk sediment 230Thxs inventories may allow useful approximations of bulk redeposition, they do not provide a unique estimate of the amount of each laterally transported sediment component. Furthermore, our findings provide evidence that the occurrence of lateral sediment redistribution alone does not always hinder the use of multiple proxies but that individual sediment fractions are affected to variable extents by sediment focussing.

Stable isotope record and lithic fragments distribution in sediments of MIS9-14 of the North Atlantic

Stable isotope and ice-rafted debris records from three core sites in the mid-latitude North Atlantic (IODP Site U1313, MD01-2446, MD03-2699) are combined with records of ODP Sites 1056/1058 and 980 to reconstruct hydrographic conditions during the middle Pleistocene spanning Marine Isotope Stages (MIS) 9-14 (300-540 ka). Core MD03-2699 is the first high-resolution mid-Brunhes record from the North Atlantic's eastern boundary upwelling system covering the complete MIS 11c interval and MIS 13. The array of sites reflect western and eastern basin boundary current as well as north to south transect sampling of subpolar and transitional water masses and allow the reconstruction of transport pathways in the upper limb of the North Atlantic's circulation. Hydrographic conditions in the surface and deep ocean during peak interglacial MIS 9 and 11 were similar among all the sites with relative stable conditions and confirm prolonged warmth during MIS 11c also for the mid-latitudes. Sea surface temperature (SST) reconstructions further reveal that in the mid-latitude North Atlantic MIS 11c is associated with two plateaus, the younger one of which is slightly warmer. Enhanced subsurface northward heat transport in the eastern boundary current system, especially during early MIS 11c, is denoted by the presence of tropical planktic foraminifer species and raises the question how strongly it impacted the Portuguese upwelling system. Deep water ventilation at the onset of MIS 11c significantly preceded surface water ventilation. Although MIS 13 was generally colder and more variable than the younger interglacials the surface water circulation scheme was the same. The greatest differences between the sites existed during the glacial inceptions and glacials. Then a north - south trending hydrographic front separated the nearshore and offshore waters off Portugal. While offshore waters originated from the North Atlantic Current as indicated by the similarities between the records of IODP Site U1313, ODP Site 980 and MD01-2446, nearshore waters as recorded in core MD03-2699 derived from the Azores Current and thus the subtropical gyre. Except for MIS 12, Azores Current influence seems to be related to eastern boundary system dynamics and not to changes in the Atlantic overturning circulation.

Revised age models and foraminiferal records obtained for the Last Interglacial period in six marine sediment cores

The dataset contains the revised age models and foraminiferal records obtained for the Last Interglacial period in six marine sediment cores: - the Southern Ocean core MD02-2488 (age model, sea surface temperatures, benthic d18O and d13C for the period 136-108 ka), - the North Atlantic core MD95-2042 (age model, planktic d18O, benthic d18O and d13C for the period 135-110 ka), - the North Atlantic core ODP 980 (age model, planktic d18O, sea surface temperatures, seawater d18O, benthic d18O and d13C, ice-rafted detritus for the period 135-110 ka), - the North Atlantic core CH69-K09 (age model, planktic d18O, sea surface temperatures, seawater d18O, benthic d18O and d13C, ice-rafted detritus for the period 135-110 ka), - the Norwegian Sea core MD95-2010 (age model, percentage of Neogloboquadrina pachyderma sinistral, sea surface temperatures, benthic d18O, ice-rafted detritus for the period 134-110 ka), - the Labrador Sea core EW9302-JPC2 (age model, percentage of Neogloboquadrina pachyderma sinistral, sea surface temperatures, benthic d18O for the period 134-110 ka).

Concentrations and isotopic ratios of thorium and uranium in pelagic sediments

The predictable in situ production of 230Th from the decay of uranium in seawater, and its subsequent removal by scavenging onto falling particles, provides a valuable tool for normalizing fluxes to the seafloor. We describe a new application, determination of the 232Th that dissolves in the water column and is removed to the seafloor. 232Th is supplied to the ocean in continental minerals, dissolution of which leads to a measurable standing stock in the water column. Sedimentary adsorbed 232Th/230Th ratios have the potential to provide a proxy for estimating the amount of dissolved material that enters the ocean, both today and in the past. Ten core top samples were treated with up to eight different leaching techniques in order to determine the best method for the separating adsorbed from lattice bound thorium. In addition, separate components of the sediments were analyzed to test whether clay dissolution was an important contribution to the final measurement. There was no systematic correlation between the strength of acid used in the leach and the measured 232Th/230Th ratios. In all cases clean foraminifera produced the same ratio as leaches on bulk sediment. In three out of five samples leaches performed on non-carbonate detritus in the <63 µm size fraction were also identical. Without additional water column data it is not yet clear whether there is a simple one to one correlation between the expected deep-water 232Th/230Th and that produced by leaching, especially in carbonate-rich sediments. However, higher ratios, and associated high 232Th adsorbed fluxes, were observed in areas with high expected detrital inputs. The adsorbed fraction was ~35-50% of the total 232Th in seven out of ten samples. Our 230Th normalized 232Th fluxes are reasonable by comparison to global estimates of detrital inputs to the ocean. In nine cases out of ten, the total 230Th-normalized 232Th flux is greater than predicted from the annual dust fall at each specific location, but lower than the average global detrital input from all sources.

Sea surface temperature reconstruction of ODP Site 175-1087

Successful application of the alkenone palaeothermometer, the UK'37 index, relies upon the assumption that fossil alkenone synthesisers responded to growth-temperature changes in a similar manner to the modern producers, chiefly the coccolithophores Emiliania huxleyi and Gephyrocapsa oceanica. We compare coccolith and UK'37 data from ODP Site 1087 in the south-east Atlantic between 1500 and 500 ka, and show that evolutionary events and changes in species dominance within the coccolithophore populations had little impact on the UK'37 record. The relative abundances of the C37 and C38 alkenones also closely resembled those found in modern populations, and suggest a similar temperature sensitivity of UK'37 during the early and mid-Pleistocene to that found at present. These results support the application of the UK'37 index to reconstruct sea-surface temperatures (SSTs) throughout the Quaternary. The UK'37 record at ODP Site 1087 contains an SST signal that documents the emergence of the 100-kyr cycles that characterise the late Quaternary ice volume records. This is preceded by significant cooling at ODP Site 1087, marked by a negative shift in SSTs and a positive shift in the planktonic delta18O some 250-kyr earlier, at ca 1150-1000 ka. This results in a permanent fall in average SSTs of around 1.5 °C. The predicted increase in aridity onshore as a result of this cooling can be identified in a number of published records from southern Africa, and may have played a role in some important evolutionary events of the mid-Pleistocene.

Sediment composition and stable isotopic ratio of Neogloboquadrina pachyderma from DSDP Site 94-609_Site, North Altlantic

Digitized records of optical desnity in many North Atlantic cores exihibt rapid changes from lighter to darker extrems, typically within less than 200 years, at the 5d/5e, 5b/5c and 4/5 boundaries. In cores from DSDP site 609 the changes from lighter to darker color coincide with increasing in relative abundance of Neogloboquadrina pachyderma (l.c.), with increases in abundances of lithic grains and with decreasing in carbonate content. The rapid changes to dark color, therefore, are climate-driven and correspond to a lowering of seas surface temperatures and to increases in amounts of ice rafted debris relative to biogenic carbonate. At the 5d&4c boundary, delta18O in N. pachyderma (l.c.) increases abruptly with the change to darker sediments as expected for cooler sea surface temperatures. At the 4/5 boundary, however, delta18O decreases with the change to darker sediment and cooler sea surface temperatures, suggesting that a layer of fresh surface water was present in the North Atlantic at that time.

Planktonic foraminifera and stable isotope record of ODP Site 162-980

Detailed faunal, isotopic, and lithic marine records provide new insight into the stability and climate progression of the last interglacial period, Marine Isotope Stage (MIS) 5, which peaked approximately 125,000 years ago. In the eastern subpolar North Atlantic, at the latitude of Ireland, interglacial warmth of the ice volume minimum of substage 5e (MIS 5e) lasted ~10,000 years (10 ka) and its demise occurred in two cooling steps. The first cooling step marked the end of the climatic optimum, which was 2-3 ka long. Minor ice rafting accompanied each cooling step; the second, larger, step encompassing cold events C26 and C25 was previously identified in the northwestern Atlantic. Approximately 4 °C of cooling occurred between peak interglacial warmth and C25, and the region experienced an additional temporary cooling of at least 1-2 °C during C24, a cooling event associated with widespread ice rafting in the North Atlantic. Beginning with C24, MIS 5 was characterized by oscillations of at least 1-2 °C superimposed on a generally cool baseline. The results of this study imply that the marine climatic optimum of the last interglacial was shorter than previously thought. The finding that the eastern subpolar North Atlantic cooled significantly before C24 reconciles terrestrial evidence for progressive climate deterioration at similar and lower latitudes with marine conditions. Our results also demonstrate a close association between modest ice rafting, cooling, and deep ocean circulation even during the peak of MIS 5e and in the earliest stages of ice growth.

Age determination and stable isotope record of ODP Hole 162-980B

The conversion of surface water to deep water in the North Atlantic results in the release of heat from the ocean to the atmosphere, which may have amplified millennial-scale climate variability during glacial times (Broecker et al., 1990, doi:10.1029/PA005i004p00469) and could even have contributed to the past 11,700 years of relatively mild climate (known as the Holocene epoch) (Bond et al., 2001, doi:10.1126/science.1065680; Alley et al., 1997, doi:10.1130/0091-7613(1997)025<0483:HCIAPW>2.3.CO;2; Keigwin and Boyle, 2000, doi:10.1073/pnas.97.4.1343). Here we investigate changes in the carbon-isotope composition of benthic foraminifera throughout the Holocene and find that deep-water production varied on a centennial-millennial timescale. These variations may be linked to surface and atmospheric events that hint at a contribution to climate change over this period.

Aprubt climate change events in the Northeastern Atlantic Ocean

The western Iberian margin has been one of the key locations to study abrupt glacial climate change and associated interhemispheric linkages. The regional variability in the response to those events is being studied by combining a multitude of published and new records. Looking at the trend from Marine Isotope Stage (MIS) 10 to 2, the planktic foraminifer data, conform with the alkenone record of Martrat et al. [2007], shows that abrupt climate change events, especially the Heinrich events, became more frequent and their impacts in general stronger during the last glacial cycle. However, there were two older periods with strong impacts on the Atlantic meridional overturning circulation (AMOC): the Heinrich-type event associated with Termination (T) IV and the one occurring during MIS 8 (269 to 265 ka). During the Heinrich stadials of the last glacial cycle, the polar front reached the northern Iberian margin (ca. 41°N), while the arctic front was located in the vicinity of 39°N. During all the glacial periods studied, there existed a boundary at the latter latitude, either the arctic front during extreme cold events or the subarctic front during less strong coolings or warmer glacials. Along with these fronts sea surface temperatures (SST) increased southward by about 1°C per one degree of latitude leading to steep temperature gradients in the eastern North Atlantic and pointing to a close vicinity between subpolar and subtropical waters. The southern Iberian margin was always bathed by subtropical water masses - surface and/ or subsurface ones -, but there were periods when these waters also penetrated northward to 40.6°N. Glacial hydrographic conditions were similar during MIS 2 and 4, but much different during MIS 6. MIS 6 was a warmer glacial with the polar front being located further to the north allowing the subtropical surface and subsurface waters to reach at minimum as far north as 40.6°N and resulting in relative stable conditions on the southern margin. In the vertical structure, the Greenland-type climate oscillations during the last glacial cycle were recorded down to 2465 m during the Heinrich stadials, i.e. slightly deeper than in the western basin. This deeper boundary is related to the admixing of Mediterranean Outflow Water, which also explains the better ventilation of the intermediate-depth water column on the Iberian margin. This compilation revealed that latitudinal, longitudinal and vertical gradients existed in the waters along the Iberian margin, i.e. in a relative restricted area, but sufficient paleo-data exists now to validate regional climate models for abrupt climate change events in the northeastern North Atlantic Ocean.