Carbonate mineralogical and isotopic analyses of TV-guided grab samples and TV-guided box corer samples from the Shumagin area

Methane seepage leads to Mg-calcite and aragonite precipitation at a depth of 4,850 m on the Aleutian accretionary margin. Stromatolitic and oncoid growth structures imply encrustation of microorganisms (microbial mats) in the host sediment with a unique growth direction downward into the sediment, forming crust-shaped lithologies. Biomarker investigations of the residue after carbonate dissolution show strong enrichments in crocetane and archaeol, which contain extremely low d13C values. This indicates the presence of methane-consuming archaea, and d13C values of -42 to -51 per mill PDB indicate that methane is the carbon source for the carbonate crusts. Thus, it appears that stromatolitic encrustations of methanotrophic anaerobic archaea probably occurs in a consortium with sulphate-reducing bacteria and that carbonate precipitation proceeds downward into the sediment, where ascending cold fluids provide a methane source. Strontium and oxygen isotope analyses as well as 14C ages of the carbonates suggest that the fluids come from deep within the sediment and that carbonate precipitation began about 3,000 years ago.

(Table 1) Luminescence age determination of sediments from the Arkhangelsk area

The Arkhangelsk area lies in the region that was reached by the northeastern flank of the Scandinavian ice sheet during the last glaciation. Investigations of Late Pleistocene sediments show interglacial terrestrial and marine conditions with sea level up to 52 m above the present level. An unconformity in the stratigraphy suggests a hiatus representing the Early Valdaian (Weichselian) and the beginning of the Middle Valdaian. This unconformity could be related to a low base level and isostatic depression of the area north of Arkhangelsk, either caused by ice masses advancing from the Kara and Barents ice sheets and/or to Scandinavian ice over the Kola Peninsula. During Middle Valdaian, from c. 66 ka BP, until the advance of the Late Valdaian glacier, c. 17-16 ka BP, peat formation, and northward fluvial sedimentation occurred coexisting with permafrost conditions in a later phase. Before the glacier advance, the base level rose and thick vertical accumulations of fluvial sediments were formed. Associated with this glacier advance from the north-northwest, ice damming occurred. Fluvial drainage was opposite to the present drainage pattern and deposition appeared in glaciolacustrine ponds in the area outside the limit of the glaciation. After the deglaciation that started c. 15 ka BP, permafrost conditions and downwasting of buried stagnant glacier ice prevailed until at least 10.7 ka BP.

Methane and hydrogen sulfide in porewater of sediment cores from the upwelling area off Namibia

Porewater concentrations of sulfate, methane, and other relevant constituents were determined on four sediment cores from the high productivity upwelling area off Namibia which were recovered from the continental slope at water depths of 1300 and 2000 m. At all four stations a distinct sulfate-methane transition zone was observed several meters below the seafloor in which both sulfate and methane are consumed. Nutrient porewater concentration profiles do not show gradient slope changes at the depths of the transition zones. Flux calculations carried out on the basis of the determined porewater profiles revealed that anaerobic methane oxidation accounts for 100% of deep sulfate reduction within the sulfate-methane transition zone and consumes the total net diffusive sulfate flux. A significant contribution of organic carbon oxidation to the reduction of sulfate at these depths could, therefore, be excluded. We state that porewater profiles of sulfate with constant gradients above the transition zones are indicative for anaerobic methane oxidation controlling sulfate reduction.

Composition of Upper Quaternary bottom sediments from the Syrian area of the Mediterranean Sea

Results of a lithological study of bottom sediments in the Syrian region of the Mediterranean Sea during Cruise 27 of R/V Vityaz (1993) are reported. Suspended sediment discharge of the Nile River are of the greatest importance for terrigenous sedimentation in the SE part of the Mediterranean Sea, especially in deep-sea areas. Suspended load entering from the Syrian catchment area plays an important role in formation of recent shelf and slope deposits. Supply of aerosols from Syrian and Arabian deserts was distinguished by the patchiness of surface distribution of quartz. During Late Quaternary accumulation of terrigenous material supplied from both the Syrian and the Nile drainage areas was irregular. Sedimentation was remarkably enhanced during sapropel formation 7000-9000 years BP.

Average compositions and analyses range for clinopyroxene, olivines, orthopyroxene, and spinel from the MARK area at DSDP Site 45-395A, and ODP Site 153-920

Mineral compositions of residual peridotites collected at various locations in the Mid-Atlantic Ridge south of the Kane transform (MARK area) are consistent with generally smaller degrees of melting in the mantle near the large offset Kane transform than near the other, small offset, axial discontinuities in the area. We propose that this transform fault effect is due to along-axis variations in the final depth of melting in the subaxial mantle, reflecting the colder thermal regime of the ridge near the Kane transform. Calculations made with a passive mantle flow regime suggest that these along-axis variations in the final depth of melting would not produce the full range of crustal thickness variations observed in the MARK area seismic record. It is therefore likely that the transform fault effect in the MARK area is combined with other mechanisms capable of producing crustal thickness variations, such as along-axis melt migration, the trapping of part of the magma in a cold mantle root beneath the ridge, or active mantle upwelling.