Physical, geochemical and magnetic properties of several ODP Leg 192 sites, Ontong Java Plateau

In this manuscript, we present the results of a physical properties investigation carried out on basaltic cores recovered from the four Leg 192 basement sites, focusing on the relationship between physical properties and alteration in basalts. Variations in physical properties in the Leg 192 basement sites closely resemble each other and reflect the amount of alteration and vein formation in the basement basalts. P-wave velocities, magnetic susceptibilities, and densities for the dense massive basalts are higher than those of more altered and heavily veined basalts. Porosity-dependent alteration is observed at Leg 192 basement sites: P-wave velocity displays a general decrease with increasing loss on ignition and potassium content. These trends are consistent with trends documented for typical alteration of oceanic crust and suggest that basalt alteration is largely responsible for the variation of the physical properties exhibited by rocks at Leg 192 basement sites. Our physical property data support the conclusion that only low-temperature seawater-mediated alteration occurred in the lava flows of the Ontong Java Plateau (OJP). This lack of higher-temperature hydrothermal alteration is consistent with the idea that the OJP basement sites are far from their eruptive vents.

Geochemistry of Ontong Java Plateau basalts

Basement rocks from the Ontong Java Plateau are tholeiitic basalts that appear to record very high degrees of partial melting, much like those found today in the vicinity of Iceland. They display a limited range of incompatible element and isotopic variation, but small differences are apparent between sampled sites and between upper and lower groups of flows at Ocean Drilling Program Site 807.40Ar-39Ar ages of lavas from Site 807 and Deep Sea Drilling Project Site 289 are indistinguishable about an early Aptian mean of 122 Ma (as are preliminary data for the island of Malaita at the southern edge of the plateau), indicating that plateau-building eruptions ended more or less simultaneously at widely separated locations. Pb-Nd-Sr isotopes for lavas from Sites 289, 803, and 807, as well as southern Malaita, reflect a hotspot-like source with epsilon-Nd(T) = +4.0 to +6.3, (87Sr/86Sr)T = 0.70423-0.70339, and 206Pb/204Pb = 18.245-18.709 and possessing consistently greater 208Pb/204Pb for a given 206Pb/204Pb than Pacific MORB. The combination of hotspot-like mantle source, very high degrees of melting, and lack of a discernible age progression is best explained if the bulk of the plateau was constructed rapidly above a surfacing plume head, possibly that of the Louisville hotspot. Basalt and feldspar separates indicate a substantially younger age of ~90 Ma for basement at Site 803; in addition, volcaniclastic layers of mid-Cenomanian through Coniacian age occur at DSDP Site 288, and beds of late Aptian-Albian age are found at Site 289. Therefore, at least some volcanism continued on the plateau for 30 m.y. or more. The basalts at Site 803 are chemically and isotopically very similar to those at the ~122 Ma sites, suggesting that hot plume-type mantle was present beneath the plateau for an extended period or at two different times. Surviving seamounts of the Louisville Ridge formed between 70 and 0 Ma have much higher 206Pb/204Pb than any of the plateau basalts. Thus, assuming the Louisville hotspot was the source of the plateau lavas, a change in the hotspot's isotopic composition may have occurred between roughly 70 and 90 Ma; such a change may have accompanied the plume-head to plume-tail transition. Similar shifts from early, lower 206Pb/204Pb to subsequently higher 206Pb/204Pb values are found in several other oceanic plateau-hotspot and continental flood basalt-hotspot systems, and could reflect either a reduction in the supply of low 206Pb/204Pb mantle or an inability of some off-ridge plume-tails to melt refractory low 206Pb/204Pb material.

Multi-year weather data in the remote semi-arid to arid mountain region of the Saharan flank of the Atlas Mountains

In 2001, a weather and climate monitoring network was established along the temperature and aridity gradient between the sub-humid Moroccan High Atlas Mountains and the former end lake of the Middle Drâa in a pre-Saharan environment. The highest Automated Weather Stations (AWS) was installed just below the M'Goun summit at 3850 m, the lowest station Lac Iriki was at 450 m. This network of 13 AWS stations was funded and maintained by the German IMPETUS (BMBF Grant 01LW06001A, North Rhine-Westphalia Grant 313-21200200) project and since 2011 five stations were further maintained by the GERMAN DFG Fennec project (FI 786/3-1), this way some stations of the AWS network provided data for almost 12 years from 2001-2012. Standard meteorological variables such as temperature, humidity, and wind were measured at an altitude of 2 m above ground. Other meteorological variables comprise precipitation, station pressure, solar irradiance, soil temperature at different depths and for high mountain station snow water equivalent. The stations produced data summaries for 5-minute-precipitation-data, 10- or 15-minute-data and a daily summary of all other variables. This network is a unique resource of multi-year weather data in the remote semi-arid to arid mountain region of the Saharan flank of the Atlas Mountains. The network is described in Schulz et al. (2010) and its further continuation until 2012 is briefly discussed in Redl et al. (2015, doi:10.1175/MWR-D-15-0223.1) and Redl et al. (2016, doi:10.1002/2015JD024443).

Habitat map of Danajon Bank, Philippines, derived from a high-spatial-resolution multi-spectral satellite image and georeferenced point intercept transect and spot-check survey field data, using an object-based image classification method

A mosaic of two WorldView-2 high resolution multispectral images (Acquisition dates: October 2010 and April 2012), in conjunction with field survey data, was used to create a habitat map of the Danajon Bank, Philippines (10°15'0'' N, 124°08'0'' E) using an object-based approach. To create the habitat map, we conducted benthic cover (seafloor) field surveys using two methods. Firstly, we undertook georeferenced point intercept transects (English et al., 1997). For ten sites we recorded habitat cover types at 1 m intervals on 10 m long transects (n= 2,070 points). Second, we conducted geo-referenced spot check surveys, by placing a viewing bucket in the water to estimate the percent cover benthic cover types (n = 2,357 points). Survey locations were chosen to cover a diverse and representative subset of habitats found in the Danajon Bank. The combination of methods was a compromise between the higher accuracy of point intercept transects and the larger sample area achievable through spot check surveys (Roelfsema and Phinn, 2008, doi:10.1117/12.804806). Object-based image analysis, using the field data as calibration data, was used to classify the image mosaic at each of the reef, geomorphic and benthic community levels. The benthic community level segregated the image into a total of 17 pure and mixed benthic classes.

Downwelling spectral irradiance as measured in different depths, remote sensing reflectance and phytoplankton pigment concentration during POLARSTERN cruises ANT-XXIV/1, ANT-XXIV/4, ANT-XXVI/4 and Maria S. Merian cruise MSM18/3

The composition and abundance of algal pigments provide information on phytoplankton community characteristics such as photoacclimation, overall biomass and taxonomic composition. In particular, pigments play a major role in photoprotection and in the light-driven part of photosynthesis. Most phytoplankton pigments can be measured by high-performance liquid chromatography (HPLC) techniques applied to filtered water samples. This method, as well as other laboratory analyses, is time consuming and therefore limits the number of samples that can be processed in a given time. In order to receive information on phytoplankton pigment composition with a higher temporal and spatial resolution, we have developed a method to assess pigment concentrations from continuous optical measurements. The method applies an empirical orthogonal function (EOF) analysis to remote-sensing reflectance data derived from ship-based hyperspectral underwater radiometry and from multispectral satellite data (using the Medium Resolution Imaging Spectrometer - MERIS - Polymer product developed by Steinmetz et al., 2011, doi:10.1364/OE.19.009783) measured in the Atlantic Ocean. Subsequently we developed multiple linear regression models with measured (collocated) pigment concentrations as the response variable and EOF loadings as predictor variables. The model results show that surface concentrations of a suite of pigments and pigment groups can be well predicted from the ship-based reflectance measurements, even when only a multispectral resolution is chosen (i.e., eight bands, similar to those used by MERIS). Based on the MERIS reflectance data, concentrations of total and monovinyl chlorophyll a and the groups of photoprotective and photosynthetic carotenoids can be predicted with high quality. As a demonstration of the utility of the approach, the fitted model based on satellite reflectance data as input was applied to 1 month of MERIS Polymer data to predict the concentration of those pigment groups for the whole eastern tropical Atlantic area. Bootstrapping explorations of cross-validation error indicate that the method can produce reliable predictions with relatively small data sets (e.g., < 50 collocated values of reflectance and pigment concentration). The method allows for the derivation of time series from continuous reflectance data of various pigment groups at various regions, which can be used to study variability and change of phytoplankton composition and photophysiology.

Calcite saturation and dissolution index of core-top sediment samples from the Ontong Java Plateau, Mid-Atlantic Ridge, the Caribbean and the Ceara Rise, the Indian Ocean, the Ninety-East Ridge and from the east of Madagascar

X-ray computed tomography (CT) provides an insight into the progression of dissolution in the tests of planktonic foraminifera. Four species of foraminifera (G. ruber [white], G. sacculifer, N. dutertrei and P. obliquiloculata) from Pacific, Atlantic and Indian Ocean core-top samples were examined by CT and SEM. Inner chamber walls began to dissolve at Delta[CO3**2-] values of 12-14 µmol/kg. Close to the calcite saturation horizon, dissolution and precipitation of calcite may occur simultaneously. Inner calcite of G. sacculifer, N. dutertrei and P. obliquiloculata from such sites appeared altered or replaced, whereas outer crust calcite was dense with no pores. Unlike the other species, there was no distinction between inner and outer calcite in CT scans of G. ruber. Empty calcite crusts of N. dutertrei and P. obliquiloculata were most resistant to dissolution and were present in samples where Delta[CO3**2-] ~ -20 µmol/kg. Five stages of preservation were identified in CT scans, and an empirical dissolution index, XDX, was established. XDX appears to be insensitive to initial test mass. Mass loss in response to dissolution was similar between species and sites at ~ 0.4 µg/µmol/kg. We provide calibrations to estimate Delta[CO3**2-] and initial test mass from XDX.