Petrology, mineralogy, and chemistry of basaltic rocks at DSDP Leg 81 Holes

We detail the petrography and mineralogy of 145 basaltic rocks from the top, middle, and base of flow units identified on shipboard along with associated pyroclastic samples. Our account includes representative electron microprobe analyses of primary and secondary minerals; 28 whole-rock major-oxide analyses; 135 whole-rock analyses each for 21 trace elements; 7 whole-rock rare-earth analyses; and 77 whole-rock X-ray-diffraction analyses. These data show generally similar petrography, mineralogy, and chemistry for the basalts from all four sites; they are typically subalkaline and consanguineous with limited evolution along the tholeiite trend. Limited fractionation is indicated by immobile trace elements; some xenocrystic incorporation from more basic material also occurred. Secondary alteration products indicate early subaerial weathering followed by prolonged interaction with seawater, most likely below 150°C at Holes 552, 553A, and 554A. At Hole 555, greenschist alteration affected the deepest rocks (olivine-dolerite) penetrated, at 250-300°C.

Concentration of the rare-earth elements in metalliferous sediments from DSDP Leg 92 holes

DSDP Leg 92 drilled at four sites along an east-west transect at 19°S on the western flank of the East Pacific Rise (EPR), in an area where sediments are essentially a mixture of hydrothermal and biogenic components, with only a minimal contribution of clastic material. Rare-earth element (REE) data on the metalliferous (non-carbonate) fraction of samples ranging in age from ~2 to ~27 Ma indicate the existence of two distinct groups of patterns corresponding to two broad age groups, one <=8 Ma, the other >=10 Ma. Within each group, REE patterns have characteristics which are near-uniform, despite large variations in total REE abundances. Sediments of the younger group are enriched in light REE (LREE) relative to deep bottom waters influenced by the hydrothermal plume extending west from the EPR at 19°S. Sediments of the older groups show further relative LREE enrichment and/or heavy REE (HREE) depletion. Surficial sediments deposited beneath the lysocline have high Sum REE concentrations resulting from slow accumulation rates, and patterns resembling older sediments due to early diagenetic effects. A correlation between the mass accumulation rates (MAR) of Sum REE and Fe + Mn suggests that ferromanganese particulate matter supplied by the hydrothermal plume scavenges REE; during this process the LREE are preferentially removed from plume seawater. The MAR of Fe + Mn shows a general decrease with age above basement, whereas Sum REE concentrations in the metalliferous component increase with age above basement. This supports the Ruhlin and Owen model wherein limited scavenging of REE, due to rapid burial of sediment near the palaeo-axis, leads to low concentrations (but high MAR-values) for the REE. Following deposition and burial of the hydrothermal component, further relative flattening of the REE pattern takes place, probably the result of diagenetic reactions over several million years. Phase partitioning data indicate that the proportion of REE residing in more poorly crystalline phases tends to increase with age (from ~45% to 90% of Sum REE). This suggests that as initial ferromanganese precipitates undergo diagenetic recrystallization, REE are transferred to the poorly crystalline phases, and/or are scavenged from pore waters by these phases. Because of the various modifications to REE patterns apparently produced both in the water column and post-depositional settings, the REE patterns of metalliferous sediments will not reflect fine-scale REE variations in associated oceanic water masses.

Eocene benthic foraminiferal community DSDP of Holes 95-612, 95-613 and 11-108

Benthic foraminiferal biofacies may vary independently of water depth and water mass; however, calibration of biofacies and stratigraphic ranges with independent paleodepth estimates allows reconstruction of age-depth patterns applicable throughout the deep Atlantic (Tjalsma and Lohmann, 1983). We have attempted to test these faunal calibrations in a continental margin setting, reconstructing Eocene benthic foraminiferal distributions along a dip section afforded by the New Jersey Transect (DSDP Sites 612, 108, 613). The following independent estimates of Eocene depths for the transect were obtained by "backtracking," "backstripping," and by assuming increasing depth downdip ("paleoslope"): Site 612, near the middle/lower bathyal boundary (about 1000 m); Site 108, in the middle bathyal zone (about 1600 m); and Site 613, near the lower bathyal/upper abyssal boundary (about 2000 m). Within uncertainties of backtracking (hundreds of meters), these estimates agree with estimates of paleodepth based on comparison of the New Jersey margin biofacies with other backtracked faunas. The stratigraphic ranges of many benthic taxa correspond to those found at other Atlantic DSDP sites. The major biofacies patterns show: (1) a depth dichotomy between an early to middle Eocene Nuttallides truempyidominated biofacies (greater than 2000 m) and a Lenticulina-Osangularia-Alabamina cf. dissonata biofacies (1000- 2000 m); and (2) a difference between a middle and a late Eocene biofacies at Site 612. The faunal boundary at about 2000 m, between bathyal and abyssal zones, occurs not only on the margin, but also throughout the deep Atlantic. The faunal change between the middle and late Eocene at Site 612 was due to a decrease of Lenticulina spp., the local disappearance of N. truempyi, and establishment of a Bulimina alazanensis-Gyroidinoides spp. biofacies. Although this change could be attributed to local paleoceanographic or water-depth changes, we argue that it is the bathyal expression of a global deep-sea benthic foraminiferal change which occurred across the middle/late Eocene boundary.

Uranium and thorium isotopes and sedimentation rates in metalliferous sediments from the western flank of the East Pacific Rise at 21°-22°S

Isotopic compositions of uranium (234U and 238U) and thorium (230Th and 232Th) were measured in metalliferous sediments from the western flank of the East Pacific Rise at 21°-22°S, in the area of hydrothermal activity and massive sulfide accumulation at the axis of the EPR. Concentration of 232Th (on the carbonate-free base) is consistent with composition of mafic extrusive rocks; isotope ratios 232Th/238U and 234U/238U indicate that about 70% of uranium passes into sediments from sea water with hydrothermal iron hydroxide. Mean sedimentation rates are calculated for seven cores by the nonequilibrium 230Th method with use of the constant concentration model. Flux of 230Th to bottom sediments is calculated and its mean value is used to determine sedimentation rate in four other cores. The constant flux model is used to calculate change of sedimentation rate with depth for seven cores over time interval of 100-300 ky. Sedimentation rates varied not much (0.3-0.6 cm/ky). The greatest changes occurred in two cores: one located near massive sulfide structures, and another near the spreading axis. Determinations of mean rates by the radiocarbon method and the nonequilibrium thorium method are in good agreement.