Sedimentology of ODP Leg 104 holes

The long-term record of glacial/interglacial cycles indicates three major paleoceanographic regimes in the Norwegian Sea. The period since the first major glaciation over Scandinavia at 2.56 Ma is characterized by high-frequency, low-amplitude oscillations of ice-rafted debris inputs, a lowered salinity, and decreased carbonate shell production in surface waters as well as overall strong carbonate dissolution at the sea floor. These conditions indicate a more zonal circulation pattern in the Northern Hemisphere and a relative isolation of surface and bottom waters in the Norwegian Sea. The generally temperate glacial climate was only interrupted by episodic weak intrusions of warm Atlantic waters. These intrusions have been detected in considerable magnitude only at Site 644, and thus are restricted to areas much closer to the Norwegian shelf than during earlier periods. The interval from 1.2 to 0.6 Ma is characterized by an increase in carbonate shell production and a better preservation, as well as a change in frequency patterns of ice-rafted debris inputs. This pattern reflects increasing meridionality in circulation-strengthening contrasts in the Norwegian Sea between strong glaciations and warm interglacials. The past 0.6 Ma reveal high-amplitude oscillations in carbonate records that are dominated by the 100-k.y. frequency pattern. Glacial/interglacial sedimentary cycles in the ODP Leg 104 drill sites reveal a variety of specific dark lithofacies. These dark diamictons reflect intense iceberg rafting in surface waters fed by surges along the front of marine-based parts of the continental ice sheets in the southeastern sector of the Norwegian Sea and are associated with resuspension of reworked fossil organic carbon and strong dissolution at the sea floor. Piling up of huge iceberg barriers along the Iceland-Faeroe-Scotland Ridge might have partially blocked off surface water connections with the North Atlantic during these periods

Siliceous phytoplankton in Late Quaternary sediments of ODP Site 175-1077

Late Quaternary fluctuations in the intensity of Congo River freshwater load were reconstructed using three different proxies (marine and freshwater diatoms, and the delta18O record of Globigerinoides ruber) preserved in the sediments of Ocean Drilling Program (ODP) Site 1077, located at the northern rim of the Congo River fan (5°10'S, 10°26'E). An abrupt change in the diatom assemblage is evident at Termination II: a two- to four-fold increase in (a) the relative abundance of a marine planktonic diatom tolerant of low salinity conditions (Cyclotella litoralis), and (b) in the concentration of freshwater diatoms. The microfossil data suggest a change in the environmental conditions surrounding Site 1077 from predominantly marine to mixed marine/brackish/fresh. The delta18O record of the planktic foraminifera G. ruber (pink) revealed negative deviations from the global oxygen isotope signal since Termination II which occurred during warm stage 1 and substages 3.2, 5.1, 5.3, and 5.5. Comparison of the isotopic signal of ODP Site 1077 with the record from a pelagic location (core GeoB1041 at 3°48'S, 7°05'W) confirms these results. The construction of an artificial delta18O curve using alkenone-derived sea surface temperature (SST) data from a nearby core (GeoB1008 at 6°S, 10°E) allowed us to estimate salinity and temperature effects on the ODP Site 1077 isotopic signal. Although increased SSTs may account for lighter delta18O values during warmer periods, they do not explain the extremely light values documented in the sediments of Site 1077. We used the oxygen isotope difference (Delta delta18O) between our site and GeoB1041 as a proxy for freshwater input. A general trend in the Delta delta18O was observed, with more negative values since Termination II. In addition, conspicuous Delta delta18O negative pulses coincided with periods of northern hemisphere summer insolation maxima over the African continent, suggesting an increase in the freshwater discharge from the Congo River due to enhanced precipitation on the hinterland. Here we propose that the abrupt change in environmental conditions at Site 1077 since Termination II is a consequence of a major reorganization in the depositional environment of the Congo River delta. This reorganization involved sustained equatorward displacement of the Angola-Benguela Front causing a northward deflection of the Congo River plume thus moving plume waters further north than normal and over Site 1077.

Pliocene and Pleistocene eastern equatorial Pacific Mg/Ca subsurface temperature

During the early Pliocene warm period (~4.6-4.2 Ma) in the Eastern Equatorial Pacific upwelling region, sea surface temperatures were warm in comparison to modern conditions. Warm upwelling regions have global effects on the heat budget and atmospheric circulation, and are argued to have contributed to Pliocene warmth. Though warm upwelling regions could be explained by weak winds and/or a deep thermocline, the temporal and spatial evolution of the equatorial thermocline is poorly understood. Here we reconstruct temporal and spatial changes in subsurface temperature to monitor thermocline depth and show the thermocline was deeper during the early Pliocene warm period than it is today. We measured subsurface temperature records from Eastern Equatorial Pacific ODP transect Sites 848, 849, and 853 using Mg/Ca records from Globorotalia tumida, which has a depth habitat of ~50-100 m. In the early Pliocene, subsurface temperatures were ~4-5°C warmer than modern temperatures, indicating the thermocline was relatively deep. Subsurface temperatures steeply cooled ~2-3°C from 4.8 to 4.0 Ma and continued to cool an additional 2-3°C from 4.0 Ma to present. Compared to records from other regions, the data suggests the pronounced subsurface cooling between 4.8 and 4.0 Ma was a regional signal related to restriction of the Isthmus of Panama, while continued cooling from 4.0 Ma to present was likely related to global processes that changed global thermocline structure. Additionally, the spatial evolution of the equatorial thermocline along a N-S transect across ODP Sites 853, 849 and 848 suggests an intensification of the southeast trades from the Pliocene to present. Large-scale atmospheric and oceanographic circulation processes link high and low latitude climate through their influence on equatorial thermocline source water regions and consequently the equatorial thermocline. Through these low latitude/high latitude linkages, changes in the equatorial thermocline and thermocline source water played an important role in the transition from the warm Pliocene to the cold Pleistocene.

Paleogene and early Neogene stable isotope record of foraminifera from ODP Leg 119 samples

Oxygen and carbon isotopic records of monogeneric and monospecific benthic and planktonic foraminifer samples from Sites 744 and 738 drilled on the southern end of the Kerguelen Plateau during ODP Leg 119 reveal the evolution of polar Indian Ocean water masses from the early Paleocene to the middle Miocene. Results from Site 738 are from sediments of early Paleocene to late Eocene age and those from Site 744 are late Eocene to middle Miocene. They suggest that intermediate waters at this location did not originate in the high latitudes during the early Eocene. Surface and near-surface waters cooled gradually after the maximum warming at 56 Ma, when surface waters were about 18°C. Intermediate waters cooled after 52 Ma. The highest temperatures (lowest d18O values) of the Cenozoic occurred from 56 to 52 Ma. The records of equatorial Pacific Site 577 and Weddell Sea Site 690 resemble that of the polar Indian Ocean in this interval. The well-documented d13C excursions toward positive values in the late Paleocene and negative values in the early Eocene are represented by foraminifers increases of 1.5 per mil and following decreases of about 3 per mil. Most of the cooling in the Paleogene occurred in the middle and late Eocene. A 2°C decrease of surface water at about 38.4 Ma heralded the beginning of extensive glacial conditions in Antarctica in the early Oligocene. At Site 744, the global d18O shift just above the Eocene/Oligocene boundary is 1.15 per mil, and occurred gradually in sediments dated at 36.5-35.9 Ma. Ice-rafted debris was deposited beginning at 36.1 Ma for about the next 2 m.y. This simultaneous occurrence of the global d18O shift with ice-rafted debris is evidence for early Oligocene glaciation in East Antarctica. Moreover, early and late Oligocene Cibicidoides d18O values between 2 and 2.2 per mil indicate intermediate water cooling and a small ice-volume effect. Production of cold dense bottom water in Antarctica was intensified with continental cooling and glaciation in the early Oligocene. Comparison of Oligocene and early Miocene isotopic data from high-latitude and low-latitude deepsea sites indicates that there were probably at least two sources of bottom waters at this time.

Calcareous nannofossils of ODP Leg 103 holes

Ocean Drilling Program Leg 103 occupied five sites on the Galicia margin, northwest of the Iberian Peninsula. Two holes (Holes 637A and 638B) yielded significant Cenozoic sedimentary sections ranging from late Miocene to late Pleistocene in age. From the nannofossil stratigraphy, one hiatus is recognized in Hole 637A (2.35-2.4 Ma), whereas two hiatuses (one at 1.9-2.6 Ma and another at 3.5-3.7 Ma) are recognized in Hole 638B. Sediment-accumulation rates for the Cenozoic portions of these two holes have been calculated based on the nannofossil datums. The abundance ratios of Coccolithus pelagicus to Discoaster brouweri for Hole 637A show relatively low values and small fluctuations from 2.5 to 6.5 Ma but sharply increase and then widely fluctuate beginning at about 2.5 Ma. This may indicate relatively warmer, more stable surface-water temperatures from 2.5 to 6.5 Ma and cooler, variable surface-water temperatures after 2.5 Ma at Site 637. C. pelagicus/D. brouweri ratios from Hole 638B also show a trend of increasing values with time from late Miocene to late Pliocene, but with more fluctuations and a different pattern from that of Hole 637A.

Heat-flow studies in the Peru Trench subduction zone

New heat-flow values were obtained in the central Peru Trench area during site surveys and drilling of Ocean Drilling Program (ODP) Leg 112 by measuring temperatures with ordinary surface heat-flow probes and in the drill holes and by estimating from bottom-simulating reflectors resulting from gas hydrates. The values determined by these methods are consistent with each other within the limits of error. When combined with existing data, heat-flow distribution from the trench to the coast was delineated. Heat flow is lower than 40 mW/m**2 at the bottom of the trench and 40 to 50 mW/m**2 on the landward slope. The low heat flow at the trench bottom can be explained partly by a high sedimentation rate. Heat flow is variable about where the Mendana Fracture Zone meets the trench. This low heat flow might result from hydrothermal circulation in the fracture zone, which some scientists believe is a new propagating rift. On the landward slope, no significant difference in heat flow is recognized between the northern side and the southern side of the fracture zone, in spite of differences in the age of the subducting plate and the tectonic history. Heat flow on the landward slope may be slightly higher than that in most other subduction zones.

Age determination of sediment cores from the Skagerrak

Paleoceanographic and paleoenvironmental interpretations based on foraminifera, sedimentary data, radiocarbon dates, and stable isotope measurements were derived from two sections in the Skagerrak: a 115-m-thick Holocene marine section drilled onshore at Skagen near the northernmost tip of Jutland, Denmark, and a 9-m piston core from the Skagerrak, north of Skagen. The foraminiferal data show that arctic-subarctic environments in the deep Skagerrak-Kattegat area were succeeded by boreal conditions at 9.6 ka. This was a result of northward migration of the Atlantic polar front and inflow of warm Atlantic water into the area through the Norwegian Channel. A gradual warming of the water masses after 9.6 ka is indicated by the data. Rare foraminifera and high sedimentation rates are found between approximately 8.6 ka and 7.6 ka at both core locations. The modern foraminiferal assemblages of the area were fully established at 7.6 ka indicating that the modern circulation pattern in the Skagerrak-Kattegat after the opening of the English Channel and the Danish Straits was not established before this date. At 5.5 ka a sudden change to coarser sediments (higher-energy environments) and the appearance of the foraminifer Eoeponidella laesoeensis is recorded in the Skagen core. This indicates a rapid change in the hydrography reflecting altered meteorological and hydrographic conditions in the Skagerrak-Kattegat, including a strengthening of the Jutland Current and increased inflow of North Sea water into the Kattegat. The event is interpreted as a response to cooling at the end of the Holocene climatic optimum in late Atlantic time and possibly reflects a rapid cooling event of North Atlantic surface water masses.

Late Cretaceous planktonic foraminiferal assemblages from the Exmouth Plateau, ODP Sites 122-762 and 122-763, eastern Indian Ocean

The evolution of planktonic foraminifera during the Late Cretaceous is marked in the Santonian by the disappearance of complex morphotypes (the marginotruncanids), and the contemporary increasing importance and diversification of another group of complex taxa, the globotruncanids. Upper Turonian to lower Campanian planktonic foraminiferal assemblages from Holes 762C and 763B (Ocean Drilling Program, Leg 122, Exmouth Plateau, 47°S palaeolatitude) were studied in detail to evaluate the compositional variations at the genus and species level based on the assumption that, in the Cretaceous oceans as in the modern, any faunal change was associated with changes in the characteristics and the degree of stability of the oceanic surface waters. Three major groups were recognised based on gross morphology, and following the assumption that Cretaceous planktonic foraminifera, although extinct, had life-history strategies comparable to those of modern planktonics: 1 - r-selected opportunists; 2 - k-selected specialists; 3 - r/k intermediate morphotypes which include all genera that display a range of trophic strategies in-between opportunist and specialist taxa. Although planktonic foraminiferal assemblages are characterised by a progressive appearance of complex taxa, this trend is discontinuous. Variation in number of species and specimens within genera has allowed recognition of five discrete intervals each of them reflecting different oceanic conditions based on fluctuations in diversity and abundance of the major morphotypes. Planktonic forms show cyclical fluctuations in diversity and abundance of cold (r-strategists) and warm taxa (k-strategists), perhaps representing alternating phases of unstable conditions (suggesting a weakly stratified upper water column in a mesotrophic environment), and well-stratified surface and near-surface waters (indicating a more oligotrophic environment). Interval 1, middle Turonian to early Coniacian in age, is dominated by the r/k intermediate morphotypes which alternate with r-strategists. These cyclical alternations are used to identify three additional subintervals. Interval 2, aged middle to late Coniacian, is characterised by the increasing number of species and relative abundance of k-strategists. After this maximum diversification the k-strategists show a progressive decrease reaching a minimum value in Interval 3 (early to late Santonian), which corresponds to the extinction of the genus Marginotruncana. In the Interval 4, latest Santonian in age, the k-strategists, represented mainly by the genera Globotruncana, increase again in diversity and abundance. The last Interval 5 (early Campanian) is dominated by juvenile globotruncanids and r-strategists which fluctuate in opposite phase. The positive peak (Interval 2) related to the maximum diversification of warm taxa (k-strategists) in the Coniacian seems to correspond to a warmer episode. It is followed by a marked decrease in the relative abundance of warm taxa (k-strategists crisis) with a minimum in the late Santonian (Interval 3), reflecting a decrease in temperature. Detailed analysis of faunal variations allows the Santonian faunal turnover to be ascribed to a cooling event strong enough to cause the extinction of the marginotruncanids.

Uranium contents and isotope ratios of uranium and strontium in sediments, leachates and pore fluids from ODP Hole 162-984A

Bulk dissolution rates for sediment from ODP Site 984A in the North Atlantic are determined using the 234U/238U activity ratios of pore water, bulk sediment, and leachates. Site 984A is one of only several sites where closely spaced pore water samples were obtained from the upper 60 meters of the core; the sedimentation rate is high (11-15 cm/ka), hence the sediments in the upper 60 meters are less than 500 ka old. The sediment is clayey silt and composed mostly of detritus derived from Iceland with a significant component of biogenic carbonate (up to 30%). The pore water 234U/238U activity ratios are higher than seawater values, in the range of 1.2 to 1.6, while the bulk sediment 234U/238U activity ratios are close to 1.0. The 234U/238U of the pore water reflects a balance between the mineral dissolution rate and the supply rate of excess 234U to the pore fluid by a-recoil injection of 234Th. The fraction of 238U decays that result in a-recoil injection of 234U to pore fluid is estimated to be 0.10 to 0.20 based on the 234U/238U of insoluble residue fractions. The calculated bulk dissolution rates, in units of g/g/yr are in the range of 0.0000004 to 0.000002 1/yr. There is significant down-hole variability in pore water 234U/238U activity ratios (and hence dissolution rates) on a scale of ca. 10 m. The inferred bulk dissolution rate constants are 100 to 1000 times slower than laboratory-determined rates, 100 times faster than rates inferred for older sediments based on Sr isotopes, and similar to weathering rates determined for terrestrial soils of similar age. The results of this study suggest that U isotopes can be used to measure in situ dissolution rates in fine-grained clastic materials. The rate estimates for sediments from ODP Site 984 confirm the strong dependence of reactivity on the age of the solid material: the bulk dissolution rate (R_d) of soils and deep-sea sediments can be approximately described by the expression R_d ~ 0.1 1/age for ages spanning 1000 to 500,000,000 yr. The age of the material, which encompasses the grain size, surface area, and other chemical factors that contribute to the rate of dissolution, appears to be a much stronger determinant of dissolution rate than any single physical or chemical property of the system.

Stable isotope ratios of foraminifera from ODP Hole 171B-1051B sediments

The primary aim of the this investigation was to examine the stability of subtropical sea-surface temperatures and reconstruct the surface-to-benthos thermal gradient. High-resolution stable isotopic analyses (18O and 13C) were conducted on late middle Eocene planktonic and benthic foraminifers recovered from Hole 1051B, Blake Nose, western North Atlantic. The sequence comprises a siliceous nannofossil and foraminifer ooze, with well-preserved calcareous microfossils. Isotopic examination was conducted on the mixed-layer dweller Morozovella spinulosa and the benthic foraminifer Nuttalides truempyi at this subtropical site.

Contents, partition, and isotopic composition of sulphur in sediments from ODP Sites 680 and 686

We have determined (1) the abundance and isotopic composition of pyrite, monosulphide, elemental sulphur, organically bound sulphur, and dissolved sulphide; (2) the partition of ferric and ferrous iron; (3) the organic carbon contents of sediments recovered at two sites drilled on the Peru Margin during Leg 112 of the Ocean Drilling Program. Sediments at both sites are characterised by high levels of organically bound sulphur (OBS). OBS comprises up to 50% of total sedimentary sulphur and up to 1% of bulk sediment. The weight ratio of S to C in organic matter varies from 0.03 to 0.15 (mean = 0.10). Such ratios are like those measured in lithologically similar, but more deeply buried petroleum source rocks of the Monterey and Sisquoc formations in California. The sulphur content of organic matter is not limited by the availability of porewater sulphide. Isotopic data suggest that sulphur is incorporated into organic matter within a metre of the sediment surface, at least partly by reaction with polysulphides. Most inorganic Sulphur occurs as pyrite. Pyrite formation occurred within surface sediments and was limited by the availability of reactive iron. But despite highly reducing sulphidic conditions, only 35-65% of the total iron was converted to sulphide; 10-30% of the total iron still occurs as Fe(III). In surface sediments, the isotopic composition of pyrite is similar to that of both iron monosulphide and dissolved sulphide. Either pyrite, like monosulphide, formed by direct reaction between dissolved sulphide and detrital iron, and/or the sulphur species responsible for converting FeS to FeS2 is isotopically similar to dissolved sulphide. Likely stoichiometries for the reaction between ferric iron and excess sulphide imply a maximum resulting FeS2:FeS ratio of 1:1. Where pyrite dominates the pool of iron sulphides, at least some pyrite must have formed by reaction between monosulphide and elemental sulphur and/or polysulphide. Elemental sulphur (S°) is most abundant in surface sediments and probably formed by oxidation of sulphide diffusing across the sediment-water interface. In surface sediments, S° is isotopically heavier than dissolved sulphide, FeS and FeS2 and is unlikely to have been involved in the conversion of FeS to FeS2. Polysulphides are thus implicated as the link between FeS and FeS2.

Biomarker and x-ray diffraction data from Site U1313 (MIS 16 - 9)

A reconstruction of Milankovitch to millennial-scale variability of sea-surface temperature (SST) and sea-surface productivity in the Pleistocene mid-latitude North Atlantic Ocean (MIS 16-9) and its relationship to ice sheet instability was carried out on sediments from IODP Site U1313. This reconstruction is based on alkenone and n-alkane concentrations, Uk37' index, total organic carbon (TOC) and carbonate contents, X-Ray diffraction (XRD) data, magnetic susceptibility, and accumulation rates. Increased input of ice-rafted debris (IRD) occurred during MIS 16, 12, and 10, characterized by high concentrations of dolomite, quartz, and feldspars and elevated accumulation rates of terrigenous matter. Minimum input values of terrigenous matter, on the other hand, were determined for MIS 13 and 11. Peak values of dolomite, coinciding with quartz, plagioclase, and kalifeldspar peaks and maxima in long-chain n-alkanes indicative for land plants, are interpreted as Heinrich-like Events related to sudden instability of the Laurentide Ice Sheet during early and late (deglacial) phases of the glacials. The coincidence of increased TOC values with elevated absolute concentrations of alkenones suggest increased glacial productivity, probably due to a more southern position of the Polar Front. Alkenone-based SST reached absolute maxima of about 19°C during MIS 11.3 and absolute minima of <10°C during MIS 12 and 10. Within MIS 11, prominent cooling events (MIS 11.22 and 11.24) occurred. The absolute SST minima recorded directly before and after the glacial maxima MIS 10.2 and 12.2, are related to Heinrich-like Event meltwater pulses, as supported by the coincidence of SST minima and maxima in C37:4 alkenones and dolomite. These sudden meltwater pulses - especially during Terminations IV and V - probably caused a collapse of phytoplankton productivity as indicated by the distinct drop in alkenone concentrations. Ice-sheet disintegration and subsequent surges and outbursts of icebergs and meltwater discharge may have been triggered by increased insolation in the Northern High Latitudes.

Rock magnetism and paleomagnetism of basalts at DSDP Leg 65 Holes

We investigated the magnetic and paleomagnetic properties of 77 basalt samples from Holes 482, 482C, 482D, 483, 483B, 485, and 485A in order to study the structure and development of the ocean's crust. During the course of this study, we measured the natural remanent magnetization, Jn, and its stability in an alternating magnetic field; the magnetic susceptibility, x; the saturation magnetization, Js; the saturation remanent magnetization, Jrs; the coercivity of maximum remanence, HCR; and the median destructive fields MDFn (for Jn) and MDFs for Jrs. A thermomagnetic analysis for Js and Jrs was also performed; these latter measurements were made on the same samples.

Paleomagnetic and rock magnetic characterization of ODP Leg 210 cores

We conducted an integrated paleomagnetic and rock magnetic study on cores recovered from Ocean Drilling Program Sites 1276 and 1277 of the Newfoundland Basin. Stable components of magnetization are determined from Cretaceous-aged sedimentary and basement cores after detailed thermal and alternating-field demagnetization. Results from a series of rock magnetic measurements corroborate the demagnetization behavior and show that titanomagnetites are the main magnetic carrier. In view of the normal polarity of magnetization and radiometric dates for the sills at Site 1276 (~98 and ~105 Ma, both within the Cretaceous Normal Superchron) and for a gabbro intrusion in peridotite at Site 1277 (~126 Ma, Chron M1), our results suggest that the primary magnetization of the Cretaceous rocks is likely retained in these rocks. The overall magnetic inclination of lithologic Unit 2 in Hole 1277A between 143 and 180 meters below seafloor is 38°, implying significant (~35° counterclockwise, viewed to the north) rotation of the basement around a horizontal axis parallel to the rift axis (010°). The paleomagnetic rotational estimates should help refine models for the tectonic evolution of the basement. The mean inclinations for Sites 1276 and 1277 rocks imply paleolatitudes of 30.3° ± 5.1° and 22.9° ± 12.0°, respectively, with the latter presumably influenced by tectonic rotation. These values are consistent with those inferred from the mid-Cretaceous reference poles for North America, suggesting that the inclination determinations are reliable and consistent with a drill site on a location in the North America plate since at least the mid-Cretaceous. The combined paleolatitude results from Leg 210 sites indicate that the Newfoundland Basin was some 1800 km south of its current position in the mid-Cretaceous. Assuming a constant rate of motion, the paleolatitude data would suggest a rate of 12.1 mm/yr for the interval from ~130 Ma (Site 1276 age) to present, and 19.6 mm/yr for the interval from 126 Ma (Site 1277 age) to recent. The paleolatitude and rotational data from this study are consistent with the possibility that Site 1276 may have passed over the Canary and Madeira hotspots that formed the Newfoundland Seamounts in the mid-Cretaceous.