Grain size distribution and percentiles of the sand component from sediments obtained in the southern Great Belt, Baltic Sea

Im Sedimentationsraum der südwestlichen Ostsee verdient der nordöstliche Teil der Kieler Bucht besonderes Interesse. Dort öffnet sich die wichtigste Verbindung zwischen Ostsee und Nordsee. Von den Austauschvorgängen, durch welche diese Meeresräume aufeinander Einfluß nehmen, ist gerade jenes Gebiet entscheidend betroffen. Die Beobachtung der Dynamik des Austausches, die Beobachtung der Transportlast, welche von den Wassermassen bewegt wird, und schließlich auch die Beobachtung der Beziehungen, welche sich zwischen dem Zusammentreffen von Wassermassen unterschiedlicher physikalischer Eigenschaften und der Sedimentbildung ergeben, läßt deshalb vor allem dort wesentliche Hinweise zum Verständnis der Sedimentationsvorgänge in der südlichen Ostsee erhoffen. In der vorliegenden Arbeit wurden an 49 Durchschnittsproben die Korngrößenverteilungen und Schwermineralgehalte von Sedimenten aus dem Südausgang des Großen Beltes untersucht. 1. Es wurden sechs in sich morphologisch etwa gleichwertige Gebiete ausgegliedert, die jeweils durch Sedimente mit ähnlichen Korngrößenverteilungen ausgezeichnet sind. Nach Lage, Typ und genetischer Ausdeutbarkeit fügen sich diese Gebiete dem von O. PRATJE (1939, 1948) gegebenen Modell der Sedimentationszonen gut ein. 2. Innerhalb dieser Gebiete ergibt sich für Sande in mehr als 20 m Wassertiefe südwärts gerichteter Transport. Oberhalb dieser Tiefe läßt sich stellenweise nordwärts gerichteter Transport nachweisen. 3. Der Schwermineralgehalt der Sedimente bleibt immer unter zwei Prozent. Die höchsten Anteile (1,7 bzw. 1,9%) werden in den Sedimenten der Tiefen Rinne und der ufernahen Bereiche des Großen Beltes angetroffen. 4. Die Korngrößenverteilungen der Sedimente werden nach der Lage der Modi in bis zu drei (Kies-, Sand-, Silt-) Komponenten zerlegt. Die Beteiligung der Silt-Komponente wird entscheidend von der Salzgehaltssprungschicht beeinflußt. 5. Es bestehen offensichtlich Zusammenhänge zwischen der Schlicksedimentation und der Salzgehaltsschichtung auch in der weiteren südlichen Ostsee.

Secchi depth maps for the Baltic Sea, 2003-2012, with links to GeoTIFs

Secchi depth is a measure of water transparency. In the Baltic Sea region, Secchi depth maps are used to assess eutrophication and as input for habitat models. Due to their spatial and temporal coverage, satellite data would be the most suitable data source for such maps. But the Baltic Sea's optical properties are so different from the open ocean that globally calibrated standard models suffer from large errors. Regional predictive models that take the Baltic Sea's special optical properties into account are thus needed. This paper tests how accurately generalized linear models (GLMs) and generalized additive models (GAMs) with MODIS/Aqua and auxiliary data as inputs can predict Secchi depth at a regional scale. It uses cross-validation to test the prediction accuracy of hundreds of GAMs and GLMs with up to 5 input variables. A GAM with 3 input variables (chlorophyll a, remote sensing reflectance at 678 nm, and long-term mean salinity) made the most accurate predictions. Tested against field observations not used for model selection and calibration, the best model's mean absolute error (MAE) for daily predictions was 1.07 m (22%), more than 50% lower than for other publicly available Baltic Sea Secchi depth maps. The MAE for predicting monthly averages was 0.86 m (15%). Thus, the proposed model selection process was able to find a regional model with good prediction accuracy. It could be useful to find predictive models for environmental variables other than Secchi depth, using data from other satellite sensors, and for other regions where non-standard remote sensing models are needed for prediction and mapping. Annual and monthly mean Secchi depth maps for 2003-2012 come with this paper as Supplementary materials.

137Cs concentrations in the southeastern Baltic Sea in 1997-2000

Variations of 137Cs concentration in the southeastern Baltic Sea were investigated over the period 1997-2000, i.e. in 11-14 years after the Chernobyl Nuclear Power Plant accident. Rate of "self-cleaning" proved to be very slow. Some results obtained in 1999 were almost the same as those measured after the accident, in 1986. Calculated results showed that "Chernobyl" caesium-137 would be "cleaned" in the Baltic Sea by 2020-2022. In 2000 average concentration had to be about 50-60 Bq/m**3. Sometimes mentioned concentrations were observed. In some cases higher concentrations averaging from 67 to 80 Bq/m**3 were registered in the southeastern Baltic Sea in 1999; and in some samples 137Cs concentrations were very high. They varied from 110 to 212 Bq/m**3. No steady correlation was observed between 137Cs concentration, salinity and temperature in surface water of the area. Distribution of radionuclide concentration sometimes depends on direction of water mass transport. Abnormally high concentrations of 137Cs in the southeastern Baltic Sea may result from additional radioactive waste discharge.

Secchi disk data collection for the North Sea and Baltic Sea

This paper presents the results of a Secchi depth data mining study for the North Sea - Baltic Sea region. 40,829 measurements of Secchi depth were compiled from the area as a result of this study. 4.3% of the observations were found in the international data centers [ICES Oceanographic Data Center in Denmark and the World Ocean Data Center A (WDC-A) in the USA], while 95.7% of the data was provided by individuals and ocean research institutions from the surrounding North Sea and Baltic Sea countries. Inquiries made at the World Ocean Data Center B (WDC-B) in Russia suggested that there could be significant additional holdings in that archive but, unfortunately, no data could be made available. The earliest Secchi depth measurement retrieved in this study dates back to 1902 for the Baltic Sea, while the bulk of the measurements were gathered after 1970. The spatial distribution of Secchi depth measurements in the North Sea is very uneven with surprisingly large sampling gaps in the Western North Sea. Quarterly and annual Secchi depth maps with a 0.5° x 0.5° spatial resolution are provided for the transition area between the North Sea and the Baltic Sea (4°E-16°E, 53°N-60°N).

Mesozooplankton investigations in Bornholm Basin, Baltic Sea

Mesozooplankton production was estimated by using a new sampling technique and two alternative calculation methods. In essence, production estimates are based on significantly higher abundances. The contribution of juvenile stages to copepod and fish dynamics was generally low, so that the omission of juvenile stages in budgets will result in a small error. The situations reported in this study present a unique food web szenario, which in detail, however, was strongly dependent on methodology. Furthermore relations between trophic levels were considered with respect to vertical distribution.

X-ray fotos of 10 sediment cores from the Baltic Sea

Various types of trace fossils have been studied on radiographs of sediment cores from the Western Baltic since the early nineteen sixties. lnvestigations on the endo- und epifauna including their habitats and population densities carried out independently by biologists helped to identify the processes of their formation and classify the structures. Biogenic traces are ubiquitous in both sandy and muddy sediments of the Great Belt, where the bottom waters are weil oxygenated through inflows from the North Sea (through Kattegat-Skagerrak). Almost all types of bioturbation structures encountered in the Kiel Bay are also observed in a variety of shapes and forms, and can be considered as representative for the Western Baltic area. Polychaetes, bivalves and echinoderms were recorded at the sediment surface of the cores, and also in living positions in the sediment. The different types of burrows having distint outlines ('trace fossis'), and those having indistinct outlines ('biodeformational strctures'), and their varying abundance encountered in the area have been linked, wherever possible, to the sediment type, and to the macro-benthos.

Geochemistry of Baltic Sea sediments

The Baltic Sea has experienced three major intervals of bottom water hypoxia following the intrusion of seawater ca. 8 kyrs ago. These intervals occurred during the Holocene Thermal Maximum (HTM), Medieval Climate Anomaly (MCA) and during recent decades. Here, we show that sequestration of both Fe and Mn in Baltic Sea sediments generally increases with water depth, and we attribute this to shelf-to-basin transfer ("shuttling") of Fe and Mn. Burial of Mn in slope and basin sediments was enhanced following the lake-brackish/marine transition at the beginning of the hypoxic interval during the HTM. During hypoxic intervals, shelf-to-basin transfer of Fe was generally enhanced but that of Mn was reduced. However, intensification of hypoxia within hypoxic intervals led to decreased burial of both Mn and Fe in deep basin sediments. This implies a non-linearity in shelf Fe release upon expanding hypoxia with initial enhanced Fe release relative to oxic conditions followed by increased retention in shelf sediments, likely in the form of iron sulfide minerals. For Mn, extended hypoxia leads to more limited sequestration as Mn carbonate in deep basin sediments, presumably because of more rapid reduction of Mn oxides formed after inflows and subsequent escape of dissolved Mn to the overlying water. Our Fe records suggest that modern Baltic Sea hypoxia is more widespread than in the past. Furthermore, hypoxia-driven variations in shelf-to-basin transfer of Fe may have impacted the dynamics of P and sulfide in the Baltic Sea thus providing potential feedbacks on the further development of hypoxia.

Maps and acoustic profiles of free gas distribution, Western Baltic Sea and Kattgat-Skagerrak area

A shallow gas depth-contour map covering the Skagerrak-western Baltic Sea region has been constructed using a relatively dense grid of existing shallow seismic lines. The digital map is stored as an ESRI shape file in order to facilitate comparison with other data from the region. Free gas usually occurs in mud and sandy mud but is observed only when sediment thickness exceeds a certain threshold value, depending on the water depth of the area in question. Gassy sediments exist at all water depths from approx. 20 m in the coastal waters of the Kattegat to 360 m in the Skagerrak. In spite of the large difference in water depths, the depth of free gas below seabed varies only little within the region, indicating a relatively fast movement of methane in the gas phase towards the seabed compared to the rate of diffusion of dissolved methane. Seeps of old microbial methane occur in the northern Kattegat where a relatively thin cover of sandy sediments exists over shallow, glacially deformed Pleistocene marine sediments. Previous estimates of total methane escape from the area may be correct but the extrapolation of local methane seepage rate data to much larger areas on the continental shelf is probably not justified. Preliminary data on porewater chemistry were compared with the free gas depth contours in the Aarhus Bay area, which occasionally suffers from oxygen deficiency, in order to examine if acoustic gas mapping may be used for monitoring the condition of the bay.

Composition of organic matter in suspended matter and bottom sediments of the southeastern Baltic Sea

Data on contents and compositions of hydrocarbons (HCs)-aliphatic (AHCs) and polycyclic aromatic (PAHs) are provided in comparison with contents of total organic carbon (Corg), lipids in suspended matter, and Corg in bottom sediments. Particular attention is paid to distribution of HCs in the area of the Kravtsov oil field. It is established that concentrations of AHCs in water are governed by concentrations of suspended matter and elevated AHC concentrations are confined to coastal areas. In the area of D-6 platform sandy bottom sediments are notable for great variability of HC concentrations, both laterally and from year to year. In summer of 2010 average content of AHCs was 40 ppm (19% of Corg) and that of PAHs was 0.023 ppm. Natural seepage from sediment mass is considered to be a source of HCs along with oil contamination.

Chemical composition of bottom sediments from the Baltic Sea

According to geochemical analyses carbonaceous sediments from deep basins of the Baltic Sea containing 3-5% of organic carbon are enriched in some metals such as Cu, Mo, Ni, Pb, Zn, V, and U relative to shallow-water facies of the Bay of Finland. These metals also enrich (relative to background values in clayey rocks) ancient carbonaceous shales, where the average Cu and V contents are slightly higher and that of Mo, Pb, and Zn lower than in deep-sea carbonaceous sediments of the Baltic Sea. In addition, the deep-sea carbonaceous sediments of the Baltic Sea are enriched (but less notably than ancient shales) in Ag, As, Bi, and Cd. These data confirm previous assumptions that carbonaceous sediments accumulating now in seas and oceans can be considered as recent analogs of ancient metalliferous shales.