Late Paleocene to Eocene stable isotope record od ODP Site 143-865

An expanded and largely complete upper Paleocene to upper Eocene section was recovered from the pelagic cap overlying Allison Guyot, Mid-Pacific Mountains at Ocean Drilling Program (ODP) Site 865 (18°26'N, 179°33'W; paleodepth 1300-1500 m). Reconstructions show that the site was within a few degrees of the equator during the Paleogene. Because no other Paleogene sections have been recovered in the Pacific Ocean at such a low latitude, Site 865 provides a unique record of equatorial Pacific paleoceanography. Detailed stable isotopic investigations were conducted on three planktonic foraminiferal taxa (species of Acarinina, Morozovella, and Subbotina). We studied benthic foraminiferal isotopes at much lower resolution on species of Cibicidoides and Lenticulina, Nuttallides truempyi and Gavelinella beccariiformis, because of their exceptional rarity. The d18O and d13C stratigraphies from Site 865 are generally similar to those derived from other Paleocene and Eocene sections. The planktonic foraminiferal records at Site 865, however, include significantly less short-term, single-sample variability than those from higher-latitude sites, indicating that this tropical, oligotrophic location had a comparatively stable water column structure with a deep mixed layer and less seasonal variability. Low-amplitude (0.1-0.8 per mil) oscillations on timescales of 250,000 to 300,000 years correlate between the d13C records of all planktonic taxa and may represent fluctuations in the mixing intensity of surface waters. Peak sea surface temperatures of 24°-25°C occurred in the earliest Eocene, followed by a rapid cooling of 3-6°C in the late early Eocene. Temperatures remained cool and stable through the middle Eocene. In the late Eocene, surface water temperatures decreased further. Vertical temperature gradients decreased dramatically in the late Paleocene and were relatively constant through much of the Eocene but increased markedly in the late Eocene. Intermediate waters warmed through the late Paleocene, reaching a maximum temperature of 10°C in the early Eocene. Cooling in the middle and late Eocene paralleled that of surface waters, with latest Eocene temperatures below 5°C. Extinction patterns of benthic foraminifera in the latest Paleocene were similar to those observed at other Pacific sites and were coeval with a short-term, very rapid negative excursion in d13C values in planktonic and benthic taxa as at other sites. During this excursion, benthic foraminiferal d18O values decreased markedly, indicating warming of 4 to 6°C for tropical intermediate waters, while planktonic taxa show slight warming (1°C) followed by 2°C of cooling. Convergence of d18O values of planktonic and benthic foraminifera suggests that thermal gradients in the water column in this tropical location collapsed during the excursion. These data are consistent with the hypothesis that equatorial Pacific surface waters were a potential source of warm, higher salinity waters which filled portions of the deep ocean in the latest Paleocene. Oxygen isotopic data indicate that equator to high southern latitude sea surface thermal gradients decreased to as little as 4°C at the peak of the excursion, suggesting some fundamental change in global heat transport.

Dinoflagellate cyst counts and age model from sediment samples of ODP Hole 175-1085A

Sediment samples from ODP Site 1085 were investigated in order to obtain more information on the initiation and development of the Benguela upwelling system during the middle and upper Miocene. In particular, our intent was to establish the causes of the upwelling as well as the response of the upwelling regime to the development of the Antarctic Circumpolar Current. Based on changes in the calcareous dinoflagellate cyst association, we found an initial increase of the dinoflagellate cyst productivity, probably related to the initiation of upwelling about 11.8 Ma ago. Two distinct increases in cyst productivity in conjunction with temperature decreases of the upper water masses reflect upwelling pulses off Namibia and occur at the end of the Miocene cooling events Mi5 (about 11.5 Ma) and Mi6 (about 10.5 Ma). Both cooling events are associated with an ice volume increase in Antarctica and are thought to have led to an increase in southeasterly winds, possibly causing these two upwelling pulses. We demonstrate a decrease in dinoflagellate cyst productivity and enhanced terrigenous input via the Orange River after the Mi5 event. At about 11.1 Ma, the dinoflagellate cyst productivity increases again. The polar cyst species Caracomia arctica occurs here for the first time. This implies an influence of subantarctic mode water and therefore a change in the quality of the upwelling water which allowed the Benguela upwelling to develop into modern conditions. From about 10.4 Ma, C. arctica forms a permanent part of the association, pointing to an establishment of the upwelling regime.

Carbon and oxygen isotopic compositions of Cibicidoides spp. and fine fraction separates (<10 µm) from ODP Holes 113-689B, 119-738B, and 120-748B

A prominent middle Eocene warming event is identified in Southern Ocean deep-sea cores, indicating that long-term cooling through the middle and late Eocene was not monotonic. At sites on Maud Rise and the Kerguelen Plateau, a distinct negative shift in d18O values (~1.0 per mil) is observed ca. 41.5 Ma. This excursion is interpreted as primarily a temperature signal, with a transient warming of 4°C over 600 k.y. affecting both surface and middle-bathyal deep waters in the Indian-Atlantic region of the Southern Ocean. This isotopic event is designated as the middle Eocene climatic optimum, and is interpreted to represent a significant climatic reversal in the midst of middle to late Eocene deep-sea cooling. The lack of a significant negative carbon isotope excursion, as observed during the Paleocene-Eocene thermal maximum, and the gradual rate of high-latitude warming suggest that this event was not triggered by methane hydrate dissociation. Rather, a transient rise in pCO2 levels is suspected, possibly as a result of metamorphic decarbonation in the Himalayan orogen or increased ridge/arc volcanism during the late middle Eocene.

Organic carbon in waters, suspended matter, and upper layer bottom sediments of the Kara Sea and Obskay Guba

Along three sections in the Kara Sea and Obskaya Guba concentrations of dissolved and particulate organic carbon (DOC and POC, respectively) in waters , as well as of organic carbon in bottom sediments (Corg) in September-October 2007 were determined. DOC varied from 6.3 to 2400 µg/l, POC - from 0.84 to 12.2 mg/l. For all samples the average DOC was 200 µg/l (n = 78; sigma = 368), the average POC - 2.7 mg/l (n = 92; sigma = 2.7). Concentrations of Corg in dried samples of upper layer bottom sediments varied from 0.13 to 2.10% (aver. = 0.9%; n = 21; sigma = 0.49%). It is shown that distribution of different forms of organic matter (OM) is an indicator of supply and scattering of particulate matter in the Kara Sea and that DOC and POC of the Kara Sea are formed under impact of runoff of the Ob and Yenisei Rivers. It is found that distribution of OM in bottom sediments is closely related to their grain size composition and to the structure of currents in the area. Variations in Corg concentration in bottom sediment cores from the zone of riverine and sea water mixing represent variability of OM burial.

Eocene-Oligocene planktonic foraminifera of ODP Hole 135-841B

A middle Eocene to lower Oligocene sedimentary sequence was drilled at Site 841 in the Tonga forearc region during Ocean Drilling Program Leg 135. A 56-m-thick sequence of volcanic sandstone, spanning from Cores 135-841B-4IR to -47R (549.1 to 605 mbsf), unconformably overlies rhyolitic volcanic basement. The middle Eocene planktonic foraminifer assemblages (P Zone?), which occur in association with larger benthic foraminifers, include spinose species of Acarinina, Morozovella, and Truncorotaloides, but their abundance is low. Late Eocene and early Oligocene faunas are abundant and show the highest diversity of the Paleogene sequence drilled at this site. They have been assigned to Zones P15-16 and P18, respectively. The Eocene/Oligocene boundary was not recognized because of a hiatus in which Zone P17 (37.2-36.6 Ma) was missing. Another hiatus is recorded in the interval between the middle and late Eocene, spanning at least 1.8 Ma. Paleogene assemblages of Site 841 contain equal numbers of warm- and cool-water species, an attribute of the warm middle-latitude Paleogene fauna of the Atlantic Ocean. In particular, common to high abundances of cool-water taxa, such as Globorotaloides, Catapsydrax, Tenuitella, and small globigerinids, may be related to the opening of a shallow seaway south of Tasmania permitting the influx of cool Indian Ocean waters into the South Pacific before the late Eocene (approximately 37 Ma).

Geochemistry at DSDP Hole 76-534A

At Site 534 in the Blake-Bahama Basin, western North Atlantic, an interval of 68 m of Maestrichtian (Upper Cretaceous) and upper middle to upper Eocene sediments consists of terrigenous siltstones, mudstones, and varicolored zeolitic claystones; minor recovery of micritic limestones, porcellanites, and quartzitic chert was made at this site as well. Comparisons with other Deep Sea Drilling Project (DSDP) sites in the western North Atlantic suggest that the following formations are present in this interval: Hatteras (Maestrichtian), Plantagenet (Maestrichtian and upper Eocene), Bermuda Rise (upper middle to upper Eocene), and the basal Blake Ridge Formation (upper middle to upper Eocene). Recognition of a Tertiary interval of the Plantagenet allows that formation to be divided into lower and upper informal units. Condensation makes this formal lithostratigraphic subdivision difficult. Together the formations record marked net condensed sedimentation (average rate ca. 2.5 m/m.y.) in strongly oxidizing bottom waters. From sedimentary structures and petrography, it is inferred that the terrigenous siltstones and micritic limestones were redeposited from the continental margin by turbidity currents. Chemical data plus petrography confirm relatively high plankton productivity during the upper Eocene. Much of the nonrecovered Eocene interval may represent chert and porcellanite. Fragments recovered were formed by replacement of relatively porous calciturbidites by opal-CT and quartz. Radiolarians in interbedded claystones rich in clinoptilolite show extensive dissolution. Relative to typical hemipelagic sediments, the claystones are enriched in many metals (Cu, Ni, Zn, Pb), particularly within manganese micronodules. The metal accumulation is related to a 30-m.y. period of slow net sediment accumulation, rather than to hydrothermal enrichment or to upward mobilization of metals from the underlying reduced Hatteras black shale facies. Elsewhere in the Blake-Bahama Basin, at Site 391, 22 km to the northwest, upper Eocene facies are missing, reportedly due to deep seafloor erosion of up to 800 m of the sedimentary succession. By contrast, the discovery that this interval is preserved at nearby Site 534 points to much less extensive seafloor erosion, possibly mostly in the Oligocene, which is missing at both DSDP Sites.

Datum events and their estimated magnetochronology at DSDP Site 72-516

Calcareous plankton biostratigraphy (foraminifers and nannoplankton) and magnetostratigraphy of the upper Oligocene to Pleistocene have been studied in hydraulic piston Cores 516-1 to 516-44, 516A-5 to 516A-11, and 516F-1 to 516F-11, Rio Grande Rise (water depth 1313 m). Some 80 biostratigraphic datum events have been correlated to the magnetic polarity stratigraphy over an interval representing the Matuyama to Chron 5, and Chrons 16 to 23. Coring disturbance and biostratigraphic evidence of a condensed section preclude unambiguous identification of polarity or biostratigraphic events over an approximately 30-m interval in the middle and upper Miocene. Sedimentation rates varied considerably during the Neogene, but an abnormally thick upper Oligocene and lower Miocene section allows a high degree of magnetobiochronologic resolution. A new planktonic foraminiferal zonation for the Miocene completes the midlatitude Neogene zonation of the South Atlantic. Important magnetobiostratigraphic correlations at Site 516 and their estimated magnetochronology include: (1) Oligocene/ Miocene boundary = first appearance datum (FAD) Globorotalia kugleri = last appearance datum (LAD) Reticulofenestra bisecta = mid-Anomaly 6C (Chron 23) = 23.7 Ma; (2) Aquitanian/Burdigalian boundary = LAD G. kugleri = between base Anomaly 6A and top of unnumbered anomaly between 6A and 6B (Chron 21) = 21.8 Ma; (3) Zone N6/N7 boundary = LAD Catapsydrax dissimilis (= FAD G. pseudomiozea and G. zealandica) = Chron 16/17 boundary = 17.6 Ma; (4) early/middle Miocene (= Burdigalian/Langhian) boundary = FAD Praeorbulina sicana = midpart of Anomaly 5C (Chron 16) = 16.6 Ma or FAD P. glomerosa = just above Anomaly 5C (inferred) = 16.3 Ma; (5) Zone N8/N9 boundary = FAD Orbulina suturalis above Anomaly 5C (later part Chron 16, inferred); (6) Miocene/ Pliocene boundary = LAD Globoquadrina dehiscens LAD Globorotalia lenguaensis = basal Gilbert Chron = 5.3 Ma.

Composition and age of volcanic rocks from the Sinii Utes Depression, Southern Primoye

New data are reported on structure of sections, chemical composition, and age of volcano-sedimentary and volcanic rocks from the Sinii Utes Depression in the Southern Primorye region. The Sinii Utes Depression is filled with two sequences: the lower sequence composed of sedimentary-volcanogenic coaliferous rocks (the stratotype of the Sinii Utes Formation) and the upper sequence consisting of tephroid with overlying basalts. This work considers chemical composition and problems of K-Ar dating of basalts. The uppermost basaltic flow has K-Ar age 22.0±1.0 Ma. The dates obtained for the middle and upper parts of lava flows are underestimated. It is explained by their heating due to combustion of brown coals of the Sinii Utes Formation underlying the lava flow. Calculations show that argon could only partly have been removed from the basalts owing to conductive heat transfer and was lost largely due to infiltration of hot gases in heterogeneous fissured medium. Basaltic volcanism on continental margins of the southern Primorye region and the adjacent Korean and Chinese areas at the Oligocene-Miocene boundary preceded Early-Middle Miocene spreading and formation of the Sea of Japan basin. Undifferentiated moderately alkaline basalts of intraplate affinity developed in the Amba Depression and some other structures of the southern Primorye region and intraplate alkali basalts of the Phohang Graben in the Korean Peninsula serve as indicators of incipient spreading regime in the Sea of Japan. Potassic basalt-trachybasalt eruptions occurred locally in riftogenic depressions and shield volcanoes. In some structures this volcanism was terminated by eruptions of intermediate and acid lavas. Such evolution of volcanism is explained by selective contamination of basaltic melts during their interaction with crustal acid material and generation of acid anatectic melts.

An integrated biostratigraphy (conodonts and foraminifers) and chronostratigraphy (paleomagnetic reversals, magnetic susceptibility, elemental chemistry, carbon isotopes and geochronology) for the Permian-Triassic strata of Guandao section

The chronostratigraphy of Guandao section has served as the foundation for numerous studies of the end-Permian extinction and biotic recovery in south China. Guandao section is continuous from the Permian-Triassic boundary to the Upper Triassic.Conodonts enable broad delineation of stage and substage boundaries and calibration of foraminifer biostratigraphy as follows. Changhsingian- Griesbachian: first Hindeodus parvus, and first appearance of foraminifers Postcladella kalhori and Earlandia sp. Griesbachian-Dienerian: first Neospathodus dieneri, and last appearance of foraminifer P. grandis. Dienerian-Smithian: first Novispathodus waageni and late Dienerian first appearance of foraminifer Hoyenella ex gr. sinensis. Smithian-Spathian: first Nv? crassatus and last appearance of foraminifers Arenovidalina n. sp. and Glomospirella cf. vulgaris. Spathian-Aegean: first Chiosella timorensis and first appearance of foraminifer Meandrospira dinarica. Aegean-Bithynian: first Nicoraella germanica and first appearance of foraminifer Pilammina densa. Bithynian-Pelsonian: after last Neogondolella regalis, prior to first Paragondolella bulgarica and first appearance of foraminifer Aulotortus eotriasicus. Pelsonian-Illyrian: first Pg. excelsa and last appearance of foraminifers Meandrospira ? deformata and Pilamminella grandis. Illyrian-Fassanian: first Budurovignathus truempyi, and first appearance of foraminifers Abriolina mediterranea and Paleolituonella meridionalis. Fassanian-Longobardian: first Bv. mungoensis and last appearance of foraminifer A. mediterranea. Longobardian-Cordevolian: first Quadralella polygnathiformis and last appearance of foraminifers Turriglomina mesotriasica and Endotriadella wirzi. The section contains primary magnetic signature with frequent reversals occurring around the Permian-Triassic, Olenekian-Anisian, and Anisian-Ladinian boundaries. Predominantly normal polarity occurs in the lower Smithian, Bithynian, and Longobardian-Cordevolian. Predominantly reversed polarity occurs in the upper Griesbachian, Induan-Olenekian, Pelsonian and lower Illyrian. Reversals match well with the GPTS. Large amplitude carbon isotope excursions, attaining values as low as -2.9 per mil d13C and high as +5.7 per mil d13C, characterize the Lower Triassic and basal Anisian. Values stabilize around +2 per mil d13C through the Anisian to Carnian. Similar signatures have been reported globally. Magnetic susceptibility and synthetic gamma ray logs show large fluctuations in the Lower Triassic and an overall decline in magnitude of fluctuation through the Middle and Upper Triassic. The largest spikes in magnetic susceptibility and gamma ray, indicating greater terrestrial lithogenic flux, correspond to positive d13C excursions. Several volcanic ash horizons occur in the Lower Triassic and Olenekian-Anisian boundary. High resolution U-Pb analysis of zircons provide a robust age of 247.2 Ma for the Olenekian-Anisian boundary.

Chemistry of siliciclastic and volcanoclastic sediments of DSDP Site 47-397

The Lower Cretaceous and Miocene sequences of the NW African passive continental margin consist of siliciclastic, volcaniclastic and hybrid sediments. These sediments contain a variety of diagenetic carbonates associated with zeolites, smectite clays and pyrite, reflecting the detrital mineralogical composition and conditions which prevailed during opening of the North Atlantic. In the Lower Cretaceous siliciclastic sediments, siderite (-6 per mil to +0.7per mil d18O PDB, -19.6 per mil to +0.6 per mil d13C PDB) was precipitated as thin layers and nodules from modified marine porewaters with input of dissolved carbon from the alteration of organic matter. Microcrystalline dolomite layers, lenses, nodules and disseminated crystals (-3.0 per mil to +2.5 per mil d18O PDB, -7.2 per mil to +4.9 per mil d13C PDB) predominate in slump and debris-flow deposits within the Lower Miocene sequence. During the opening of the Atlantic, volcanic activity in the Canary Islands area resulted in input of volcaniclastic sediments to the Middle and Upper Miocene sequences. Calcite is the dominant diagenetic carbonate in the siliciclastic-bioclastic-volcaniclastic hybrid and in the volcaniclastic sediments, which commonly contain pore-rimming smectite. Diagenetic calcite (-22 per mil to +1.6 per mil d18O PDB, -35.7 per mil to +0.8 per mil d13C PDB) was precipitated due to the interaction of volcaniclastic and bioclastic grains with marine porewaters. Phillipsite is confined to the alteration of volcaniclastic sediments, whereas clinoptilolite is widely disseminated, occurring essentially within foraminiferal chambers, and formed due to the dissolution of biogenic silica.

Neogene planktonic foraminifera of DSDP Leg 41 holes

During Leg 41 Neogene sediments were recovered from five sites off northwest Africa. On the Sierra Leone Rise (Site 366), Neogene sediments consist of nanno oozes, nanno chalk, and calcareous clays 230 meters thick, resting conformably on the late Oligocene sediments. The common succession of zones occurs with two hiatuses. The lower gap corresponds to an interval around the lower/middle Miocene boundary (the Praeorbulina glomerosa and Orbulina suturalis-Globorotalia peri-pheroronda zones are absent) and the upper gap coincides with an interval around the middle/upper Miocene boundary (the Sphaeroidinellopsis sub-dehiscens-GIobigerina druryi, Globigerina nepenthes-Globorotalia siakensis and Globorotalia conlinuosa zones are missing). In the Cape Verde Basin (Site 367) deep-water Neogene turbidites (about 200-250 m thick) contain poor fauna of redeposited and sorted Cretaceous, Eocene, Oligocene, and Neogene species. On the Cape Verde Rise (Site 368) the Neogene section starts with slightly calcareous and non-calcareous clays with poor planktonic foraminifers of the lower Miocene. Later on this area was uplifted and clayey sediments have been replaced upsection in order by more shallow-water clayey nanno and nanno-foraminifer oozes and marls and pure calcareous oozes. In the middle Miocene, planktonic foraminifers are still not diverse, but since the level of the Globigerina nepenthes-Globorotalia siakensis Zone, almost all Neogene zones have been traced. The minimum thickness of the Neogene sediments is about 230 meters. On the continental slope off Spanish Sahara (Site 369) monotonous calcareous pelagic sediments of Neogene age (164 m thick) overlie the late Oligocene comformably, or with a small time gap. A set of zones beginning from the Globigerinoides primordis-Globorotaiia kugleri Zone up to the Globorotalia fohsi fohsi Zone has been revealed with a gap corresponding to the Globigerinita stainforthi and the Globigerinatella insueta-Globigerinoides irilobus zones. Above that follow sediments with heterogeneous microfauna which result from redeposition or mixing of sediments during drilling. The section ends with sediments of the late Miocene and lower Pliocene with abundant planktonic foraminifers. The latter are unconformably overlain by the Quaternary ooze. In the Morocco basin (Site 370) deep-water marls and calcareous clays of the lower Miocene contain poor assemblages of planktonic foraminifers. The middle and upper Miocene are represented by turbidites (alternation of nanno oozes, clays, siltstones, and sands) with heterogeneous microfauna. Total thickness of Neogene is up to 200 meters. In general the Neogene foraminifer microfauna of the area studied includes the majority of species which developed within the tropical-subtropical belt. The entire succession of the Miocene and Pliocene foraminifer zones occurs. The only exclusion is the Sphaeroidinellopsis subdehiscens-Globigerina druryi Zone of the middle Miocene. The distribution of species is shown on three tables. Comments are given for 47 species and subspecies of foraminifers (stratigraphic ranges, peculiarities of morphology, and ultrastructure of the shell wall).

Stratigraphic occurrence of selected marine palynomorph species recorder in the Paleogene of ODP Hole 105-647A (Table 3)

Dinoflagellate cysts were recovered throughout the Paleogene succession of Hole 647A, which contains an almost complete deep-water record of early Eocene through early late Oligocene sedimentation in the Labrador Sea. Dinoflagellate cyst biostratigraphy is in general accord with that provided by other microfossil groups and is consistent with a lower Eocene age, as determined by nannofossils, for basal sediments in Hole 647A. These sediments overlie oceanic crust of Chron 24 age. Dinocyst assemblages indicate outer neritic to oceanic conditions throughout, although the persistent occurrence of Wetzeliellaceae specimens in the lower Eocene suggests a greater influence from shelf environments during this time. Lower Eocene dinocyst assemblages are similar to coeval assemblages from the Rockall Plateau, but those from the middle to upper Eocene have mixed affinities and may be related to the intensification of the proto-Gulf Stream from middle Eocene time. Oligocene dinocyst assemblages suggest the influence of both arctic and North Atlantic wate rmasses at this site. The presence of protoperidineacean species in the upper Eocene and Oligocene may indicate increased availability of nutrients, perhaps related to increased upwelling or the effects of water-mass mixing. Productive samples are dominated by dinocysts and acritarchs, while sporomorphs are represented mainly by bisaccate pollen. Preservational differences within samples may reflect mixing of penecontemporaneous dinocyst populations during the Eocene, and all samples examined may have a considerable allochthonous component. Variability in relative abundance of many species during the Eocene may be related to fluctuating water-mass properties. A total 175 dinocyst and acritarch taxa were recorded from 53 productive samples from the Paleogene. Only one Paleogene sample was barren of palynomorphs. Of three Miocene samples processed, all were barren.