Thallium isotope composition in pyrites

This paper presents the first study of Tl isotopes in early diagenetic pyrite. Measurements from two sections deposited during the Toarcian Ocean Anoxic Event (T-OAE, ~183 Ma) are compared with data from Late Neogene (<10 Ma) pyrite samples from ODP legs 165 and 167 that were deposited in relatively oxic marine environments. The Tl isotope compositions of Late Neogene pyrites are all significantly heavier than seawater, which most likely indicates that Tl in diagenetic pyrite is partially sourced from ferromanganese oxy-hydroxides that are known to display relatively heavy Tl isotope signatures. One of the T-OAE sections from Peniche in Portugal displays pyrite thallium isotope compositions indistinguishable from Late Neogene samples, whereas samples from Yorkshire in the UK are depleted in the heavy isotope of Tl. These lighter compositions are best explained by the lack of ferromanganese precipitation at the sediment-water interface due to the sulfidic (euxinic) conditions thought to be prevalent in the Cleveland Basin where the Yorkshire section was deposited. The heavier signatures in the Peniche samples appear to result from an oxic water column that enabled precipitation of ferromanganese oxy-hydroxides at the sediment-water interface. The Tl isotope profile from Yorkshire is also compared with previously published molybdenum isotope ratios determined on the same sedimentary succession. There is a suggestion of an anti-correlation between these two isotope systems, which is consistent with the expected isotope shifts that occur in seawater when marine oxic (ferromanganese minerals) fluxes fluctuate. The results outlined here represent the first evidence that Tl isotopes in early diagenetic pyrite have potential to reveal variations in past ocean oxygenation on a local scale and potentially also for global oceans. However, much more information about Tl isotopes in different marine environments, especially in anoxic/euxinic basins, is needed before Tl isotopes can be confidently utilized as a paleo-redox tracer.

Diatom biostratigraphy and datum levels of sediments from ODP Leg 167 sites

Ocean Drilling Program Leg 167 represents the first time since 1978 that the North American Pacific margin was drilled to study ocean history. More than 7500 m of Quaternary to middle Miocene (14 Ma) sediments were recovered from 13 sites, representing the most complete stratigraphic sequence on the California margin. Diatoms are found in most samples in variable abundance and in a moderately well-preserved state throughout the sequence, and they are often dominated by robust, dissolution-resistant species. The Neogene North Pacific diatom zonation of Yanagisawa and Akiba (1998, doi:10.5575/geosoc.104.395) best divides the Miocene to Quaternary sequences, and updated ages of diatom biohorizons estimated based on the geomagnetic polarity time scale of Cande and Kent (1995, doi:10.1029/94JB03098) are slightly revised to adjust the differences between the other zonations. Most of the early middle Miocene through Pleistocene diatom datum levels that have been proven to be of stratigraphic utility in the North Pacific appear to be nearly isochronous within the level of resolution constrained by sample spacing. The assemblages are characterized by species typical of middle-to-high latitudes and regions of high surface-water productivity, predominantly by Coscinodiscus marginatus, Stephanopyxis species, Proboscia barboi, and Thalassiothrix longissima. Latest Miocene through Pliocene assemblages in the region of the California Current, however, are intermediate between those of subarctic and subtropical areas. As a result, neither the existing tropical nor the subarctic (high latitude) zonal schemes were applicable for this region. An interval of pronounced diatom dissolution detected throughout the Pliocene sequence apparently correspond to a relatively warmer paleoceanographic condition resulting in a slackening of the southward flow of the California Current.

Distribution of abundance of planktic foraminifera and calcareous nannofossils at DSDP Sites 17-167 and 62-463

New paleomagnetic and paleontologic data from Pacific DSDP Sites 463 and 167 define the magnetic reversals that predate the Cretaceous Normal Polarity Superchron (K-N). Data from Mid-Pacific Mountain Site 463 provide the first definition of polarity chron M0 in the Pacific deep-sea sedimentary record. Foraminiferal biostratigraphy suggests that polarity chron M0 is contained entirely within the lower Aptian Hedbergella similis Zone, in agreement with foraminiferal data from the Italian Southern Alps and Atlantic Ocean. Nannofossil assemblages also suggest an early Aptian age for polarity chron M0, contrary to results from the Italian Umbrian Apennines and Southern Alps, which place polarity chron M0 on the Barremian-Aptian boundary. Biostratigraphic dating discrepancies caused by the time-transgressive, preservational, or provincial nature of paleontological species might be reconciled by the use of magnetostratigraphy, specifically polarity chron M0 which lies close to the Barremian-Aptian boundary. At Magellan Rise Site 167, five reversed polarity zones are recorded in Hauterivian to Aptian sediments. Correlation with M-anomalies is complicated by synsedimentary and postsedimentary sliding about 25 m.y. after basement formation, producing gaps in, and duplications of, the stratigraphic sequence. The magnitude and timing of such sliding must be addressed when evaluating the stratigraphy of these oceanic-rise environments.

Carbonate record of ODP Leg 167 sites

One of the expected scientific results of Ocean Drilling Program Leg 167 was to reconstruct the Neogene history of biogenic calcium carbonate accumulation in the northeastern Pacific along the California margin (Lyle, Koizumi, Richter, et al., 1997). This aims to constrain inorganic carbon burial rates, deep-water hydrography in the North Pacific, and linkages between deep Atlantic and Pacific circulation and carbonate accumulation or dissolution patterns. Data are presented for four sites. Two of them are located in the California bight-East Cortez Basin (Site 1012: 32°16.970?N 118°23.024?W, 1773 m) and San Nicholas Basin (Site 1013: 32°48.040??, 118°53.992?W, 1564 m). The others are the dedicated Hole 1017E at Site 1017 (34°32.099?N, 121°6.430?W, 955 m) and Site 1019 in the Eel River Basin (41¢X40.972?N, 124°55.975?W, 977 m). Reconstruction of paleo-sea-surface temperatures (SST) by determining the alkenone unsaturation index of the extractable organic matter is an independent technique and helps to verify oxygen-isotope-based estimates. Results from the uppermost 600 cm of the dedicated Hole 1017E are expected to reveal the local temperature history of the last 30 k.y.

Oxygen isotope composition of benthic and planktonic foraminifera from ODP Holes 146-893A and 167-1017B

The detailed structure and timing of the penultimate deglaciation are insufficiently defined yet critical for understanding mechanisms responsible for abrupt climate change. Here we present oxygen isotope records (from planktonic and benthic foraminifera) at unprecedented resolution encompassing late marine oxygen isotope stage (MIS) 6 and Termination II (ca. 150-120 ka) from the Santa Barbara Basin, supported by additional southern California margin records, a region highly sensitive to millennial-scale climate oscillations during the last deglaciation. These records reveal millennial- and centennial-scale climate variability throughout the interval, including an interstadial immediately preceding the deglaciation, a brief warm event near the beginning of Termination II, and a Bølling-Allerød-Younger Dryas-like climate oscillation midway through the deglaciation. Recognition of these events in an oxygen isotope record from a 230Th-dated stalagmite allows the adoption of this radiometric chronology for the California margin records. This chronology supports the Milankovitch theory of deglaciation. The suborbital history of climate variability during Termination II may account for records of early deglaciation.