Relative contents of heavy minerals in 0.100-0.010 mm grain size fraction from bottom sediments of the southwest Barents Sea

Structure and composition of sub-surface bottom sediments from the southwest Barents Sea have been under study. The study has revealed heterogeneity of sediment structure resulted from temporal irregularity and variability of sedimentation processes. The study of the heavy minerals from 0.1-0.01 mm grain size fraction has shown prevalence of green hornblende, epidote, garnet, and ilmenite in all types of sediments; these minerals are the basis of terrigenous-mineralogical province. At the same time in different areas local terrigenous-mineralogical associations have been identified. Clay mineral composition of in the sediments was quite uniform: biotite, chlorite, hydromica, smectite. Despite this, a number of features indicating initial stages of clay mineral transformation has been identified. Differences in material composition and structure of the studied sediments are associated with rapid change in paleogeographic situation on the land - ice cover melting on the Kola Peninsula and subsequent Holocene climatic situation.

Carbon geochemistry of sediments from the Amazon deep sea fan

Sediment cores from the Amazon deep sea fan recovered during R/V Meteor cruise 16-2 show in detail the modern areal distribution of sedimentary organic carbon, stable organic carbon isotopes of the organic matter (OM), as well as variations in the depositional processes. In addition, we studied up to 300 m long drilled sediment records recovered during ODP Leg 155 which allow evaluation of temporal variations on the Amazon fan. Our results reveal new evidence for a very rapid change of fan depositional processes and organic carbon source at times of sea-level change over the middle and lower Amazon fan. To estimate the amount of terrestrial organic carbon stored in sediments from the last glacial in the Amazon fan we used stable organic carbon isotopes of the OM (delta13Corg), organic carbon content (Corg), and age models based on oxygen isotopes, faunal data, and magnetic excursions. Following our results, the organic carbon accumulation on the Amazon deep sea fan is controlled by glacio-eustatic sea-level oscillations. Interglacial sea-level high stand sediments are dominated by marine OM whereas during glacial sea-level low stands terrestrial organic carbon is transported beyond the continental shelf through the Amazon canyon and deposited directly onto the Amazon deep sea fan. Glacial sediments of the Amazon fan stored approximately 73*10**15 g terrestrial Corg in 20,000 years or 3.7*10**12 g terrestrial Corg/yr (equivalent to 7-12% of the riverine organic carbon discharge; assuming constant paleo discharge), which is about the same amount of terrestrial organic carbon as deposited on the Amazon shelf today (3.1*10**12 g terrestrial Corg/yr or 6-10% of the modern riverine organic carbon discharge).

Mineral and foraminifer composition of sediments across the Paleocene/Eocene Thermal Maximum from ODP Leg 198 sites

The Paleocene/Eocene Thermal Maximum (PETM) was a transient interval of global warming ~55 m.y. ago associated with transformation of ecosystems and changes in carbon cycling. The event was caused by the input of massive amounts of CO2 or CH4 to the ocean-atmosphere system. Rapid shoaling of the lysocline and calcite compensation depth (CCD) is a predicted response of CO2 or CH4 input; however, the extent of this shoaling is poorly constrained. Investigation of Ocean Drilling Program (ODP) Sites 1209-1212 at Shatsky Rise, which lies along a depth transect, suggests a minimum lysocline shoaling of ~500 m in the tropical Pacific Ocean during the PETM. The sites also show evidence of CaCO3 dissolution within the sediment column, carbonate "burn-down" below the level of the carbon isotope excursion, and a predicted response to a rapid change in deepwater carbonate saturation. Close examination of several foraminiferal preservation proxies (i.e., fragmentation, benthic/planktonic foraminiferal ratios, coarse fraction, and CaCO3 content) and observations of foraminifers reveal that increased fragmentation levels most reliably predict intervals with visually impoverished foraminiferal preservation as a result of dissolution. Low CaCO3 content and high benthic/planktonic ratios also mirror intervals of poorest preservation.

(Table 1) Organic carbon and radiogenic isotopes analysis of DSDP Hole 22-218 sediments

Modern erosion of the Himalaya, the world's largest mountain range, transfers huge dissolved and particulate loads to the ocean. It plays an important role in the long-term global carbon cycle, mostly through enhanced organic carbon burial in the Bengal Fan. To understand the role of past Himalayan erosion, the influence of changing climate and tectonic on erosion must be determined. Here we use a 12 Myr sedimentary record from the distal Bengal Fan (Deep Sea Drilling Project Site 218) to reconstruct the Mio-Pliocene history of Himalayan erosion. We use carbon stable isotopes (d13C) of bulk organic matter as paleo-environmental proxy and stratigraphic tool. Multi-isotopic - Sr, Nd and Os - data are used as proxies for the source of the sediments deposited in the Bengal Fan over time. d13C values of bulk organic matter shift dramatically towards less depleted values, revealing the widespread Late Miocene (ca. 7.4 Ma) expansion of C4 plants in the basin. Sr, Nd and Os isotopic compositions indicate a rather stable erosion pattern in the Himalaya range during the past 12 Myr. This supports the existence of a strong connection between the southern Tibetan plateau and the Bengal Fan. The tectonic evolution of the Himalaya range and Southern Tibet seems to have been unable to produce large re-organisation of the drainage system. Moreover, our data do not suggest a rapid change of the altitude of the southern Tibetan plateau during the past 12 Myr. Variations in Sr and Nd isotopic compositions around the late Miocene expansion of C4 plants are suggestive of a relative increase in the erosion of High Himalaya Crystalline rock (i.e. a simultaneous reduction of both Transhimalayan batholiths and Lesser Himalaya relative contributions). This could be related to an increase in aridity as suggested by the ecological and sedimentological changes at that time. A reversed trend in Sr and Nd isotopic compositions is observed at the Plio-Pleistocene transition that is likely related to higher precipitation and the development of glaciers in the Himalaya. These almost synchronous moderate changes in erosion pattern and climate changes during the late Miocene and at the Plio-Pleistocene transition support the notion of a dominant control of climate on Himalayan erosion during this time period. However, stable erosion regime during the Pleistocene is suggestive of a limited influence of the glacier development on Himalayan erosion.

Neodymium isotopic ratios and clay mineral composition from ODP Hole 1147A and Site 184-1148

Ocean Drilling Program sampling of the distal passive margin of South China at Sites 1147 and 1148 has yielded clay-rich hemipelagic sediments dating to 32 Ma (Oligocene), just prior to the onset of seafloor spreading in the South China Sea. The location of the drill sites offshore the Pearl River suggests that this river, or its predecessor, may have been the source of the sediment in the basin, which accounts for only not, vert, similar ~1.8% of the total Neogene sediment in the Asian marginal seas. A mean erosion depth of not, vert, similar ~1 km over the current Pearl River drainage basin is sufficient to account for the sediment volume on the margin. Two-dimensional backstripping of across-margin seismic profiles shows that sedimentation rates peaked during the middle Miocene (11-16 Ma) and the Pleistocene (since 1.8 Ma). Nd isotopic analysis of clays yielded epsilonNd values of -7.7 to -11.0, consistent with the South China Block being the major source of sediment. More positive epsilonNd values during and shortly after rifting compared to later sedimentation reflect preferential erosion at that time of more juvenile continental arc rocks exposed along the margin. As the drainage basin developed and erosion shifted from within the rift to the continental interior epsilonNd values became more negative. A rapid change in the clay mineralogy from smectite-dominated to illite dominated at not, vert, similar 15.5 Ma, synchronous with middle Miocene rapid sedimentation, mostly reflects a change to a wetter, more erosive climate. Evidence that the elevation of the Tibetan Plateau and erosion in the western Himalaya both peaked close to this time supports the suggestion that the Asian monsoon became much more intense at that time, much earlier than the 8.5 Ma age commonly accepted.

Alkenone stable carbon isotopes, carbonate stable carbon and oxygen isotopes, planktic foraminifera boron isotopes and atmospheric CO2 calculations and box model results from Ras il-Pellegrin section, Malta

The development of a permanent, stable ice sheet in East Antarctica happened during the middle Miocene, about 14 million years (Myr) ago. The middle Miocene therefore represents one of the distinct phases of rapid change in the transition from the "greenhouse" of the early Eocene to the "icehouse" of the present day. Carbonate carbon isotope records of the period immediately following the main stage of ice sheet development reveal a major perturbation in the carbon system, represented by the positive d13C excursion known as carbon maximum 6 ("M6"), which has traditionally been interpreted as reflecting increased burial of organic matter and atmospheric pCO2 drawdown. More recently, it has been suggested that the d13C excursion records a negative feedback resulting from the reduction of silicate weathering and an increase in atmospheric pCO2. Here we present high-resolution multi-proxy (alkenone carbon and foraminiferal boron isotope) records of atmospheric carbon dioxide and sea surface temperature across CM6. Similar to previously published records spanning this interval, our records document a world of generally low (~300 ppm) atmospheric pCO2 at a time generally accepted to be much warmer than today. Crucially, they also reveal a pCO2 decrease with associated cooling, which demonstrates that the carbon burial hypothesis for CM6 is feasible and could have acted as a positive feedback on global cooling.

Aprubt climate change events in the Northeastern Atlantic Ocean

The western Iberian margin has been one of the key locations to study abrupt glacial climate change and associated interhemispheric linkages. The regional variability in the response to those events is being studied by combining a multitude of published and new records. Looking at the trend from Marine Isotope Stage (MIS) 10 to 2, the planktic foraminifer data, conform with the alkenone record of Martrat et al. [2007], shows that abrupt climate change events, especially the Heinrich events, became more frequent and their impacts in general stronger during the last glacial cycle. However, there were two older periods with strong impacts on the Atlantic meridional overturning circulation (AMOC): the Heinrich-type event associated with Termination (T) IV and the one occurring during MIS 8 (269 to 265 ka). During the Heinrich stadials of the last glacial cycle, the polar front reached the northern Iberian margin (ca. 41°N), while the arctic front was located in the vicinity of 39°N. During all the glacial periods studied, there existed a boundary at the latter latitude, either the arctic front during extreme cold events or the subarctic front during less strong coolings or warmer glacials. Along with these fronts sea surface temperatures (SST) increased southward by about 1°C per one degree of latitude leading to steep temperature gradients in the eastern North Atlantic and pointing to a close vicinity between subpolar and subtropical waters. The southern Iberian margin was always bathed by subtropical water masses - surface and/ or subsurface ones -, but there were periods when these waters also penetrated northward to 40.6°N. Glacial hydrographic conditions were similar during MIS 2 and 4, but much different during MIS 6. MIS 6 was a warmer glacial with the polar front being located further to the north allowing the subtropical surface and subsurface waters to reach at minimum as far north as 40.6°N and resulting in relative stable conditions on the southern margin. In the vertical structure, the Greenland-type climate oscillations during the last glacial cycle were recorded down to 2465 m during the Heinrich stadials, i.e. slightly deeper than in the western basin. This deeper boundary is related to the admixing of Mediterranean Outflow Water, which also explains the better ventilation of the intermediate-depth water column on the Iberian margin. This compilation revealed that latitudinal, longitudinal and vertical gradients existed in the waters along the Iberian margin, i.e. in a relative restricted area, but sufficient paleo-data exists now to validate regional climate models for abrupt climate change events in the northeastern North Atlantic Ocean.

Age determination and model of sediment core RAPiD-15-4P

Greenland ice core records indicate that the last deglaciation (~7-21 ka) was punctuated by numerous abrupt climate reversals involving temperature changes of up to 5°C-10°C within decades. However, the cause behind many of these events is uncertain. A likely candidate may have been the input of deglacial meltwater, from the Laurentide ice sheet (LIS), to the high-latitude North Atlantic, which disrupted ocean circulation and triggered cooling. Yet the direct evidence of meltwater input for many of these events has so far remained undetected. In this study, we use the geochemistry (paired Mg/Ca-d18O) of planktonic foraminifera from a sediment core south of Iceland to reconstruct the input of freshwater to the northern North Atlantic during abrupt deglacial climate change. Our record can be placed on the same timescale as ice cores and therefore provides a direct comparison between the timing of freshwater input and climate variability. Meltwater events coincide with the onset of numerous cold intervals, including the Older Dryas (14.0 ka), two events during the Allerød (at ~13.1 and 13.6 ka), the Younger Dryas (12.9 ka), and the 8.2 ka event, supporting a causal link between these abrupt climate changes and meltwater input. During the Bølling-Allerød warm interval, we find that periods of warming are associated with an increased meltwater flux to the northern North Atlantic, which in turn induces abrupt cooling, a cessation in meltwater input, and eventual climate recovery. This implies that feedback between climate and meltwater input produced a highly variable climate. A comparison to published data sets suggests that this feedback likely included fluctuations in the southern margin of the LIS causing rerouting of LIS meltwater between southern and eastern drainage outlets, as proposed by Clark et al. (2001, doi:10.1126/science.1062517).